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Strong-field ionization by counter-rotating two-color laser fields produces quantum interference between photoelectrons emitted on the leading and trailing edges of the laser field oscillations. We show that in chiral molecules, this…

Chiral light-matter interactions have been investigated for two centuries, leading to the discovery of many chiroptical processes used for discrimination of enantiomers. Whereas most chiroptical effects result from a response of bound…

Controlling the polarization state of electromagnetic radiation enables the investigation of fundamental symmetry properties of matter through chiroptical processes. Many strategies have been developed to reveal structural or dynamical…

Angular distribution of photoelectrons released by the ionization of randomly-oriented molecules with two laser fields of carrier frequencies $\omega$ and $2\omega$, which are linearly polarized in two mutually-orthogonal directions, is…

Quantum Physics · Physics 2019-06-11 Philipp V. Demekhin

Strong field ionization by circularly polarized laser fields from initial states with internal orbital momentum has interesting propensity rule: electrons counter-rotating with respect to the laser field can be liberated more easily than…

Atomic Physics · Physics 2015-12-16 Jivesh Kaushal , Felipe Morales , Olga Smirnova

Chiral molecules exhibit enantiosensitive light-matter interactions, with photoelectron circular dichroism (PECD) serving as a sensitive probe of molecular chirality through the asymmetry in the photoelectron wavepacket amplitude. Here, we…

Atomic Physics · Physics 2025-05-07 Zheming Zhou , Yang Li , Xu Zhang , Yueming Zhou , Peixiang Lu

Chirality causes symmetry breaks in a large variety of natural phenomena ranging from particle physics to biochemistry. We investigate one of the simplest conceivable chiral systems, a laser-excited, oriented, effective one-electron Li…

A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

Chemical Physics · Physics 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

Many chirality-sensitive light-matter interactions are governed by chiral electron dynamics. Therefore, the development of advanced technologies harnessing chiral phenomena would critically benefit from measuring and controlling chiral…

Chirality is ubiquitous in nature and of fundamental importance in science. The present work focuses on understanding the conditions required to modify the chirality during ultrafast electronic motion by bringing enantiomers…

Chemical Physics · Physics 2021-01-04 Sucharita Giri , Alexandra Maxi Dudzinski , Jean Christophe Tremblay , Gopal Dixit

We demonstrate a left-right asymmetry control of the photo\-electron angular distribution in multi\-photon ionization of Li atoms by a bichromatic laser field. By delaying the fundamental (780 nm) and its second harmonic relative to each…

Atomic Physics · Physics 2024-05-20 Silva Mezinska , Alexander Dorn , Thomas Pfeifer , Klaus Bartschat

Chiral systems exhibit unique properties traditionally linked to their asymmetric spatial arrangement. Recently, multiple laser pulses were shown to induce purely electronic chiral states without altering the nuclear configuration. Here, we…

Chemical Physics · Physics 2025-07-24 Torsha Moitra , Lukas Konecny , Marius Kadek , Ofer Neufeld , Angel Rubio , Michal Repisky

The interaction of strong laser fields with matter intrinsically provides powerful tools to image transient dynamics with an extremely high spatiotemporal resolution. Here, we study strong-field ionisation of laser-aligned molecules and…

The development of attosecond technology has enabled the real-time observation of coherent electron motion in atoms, molecules and condensed phases. Experimentally, it is now possible to generate laser pulses of durations of only a few tens…

Chemical Physics · Physics 2017-05-18 David Ayuso

Chiroptical effects using circularly polarized light produce signals that change sign when switching either molecular handedness (enantiosensitivity) or the light helicity (circular dichroism). Here, we break this…

In the semiclassical picture of photoionization process in intense laser fields, the ionization rate solely depends on the amplitude of the electric field and the final photoelectron momentum corresponds to the instant of ionization of the…

Atomic Physics · Physics 2019-05-09 Li Guo , Shilin Hu , Mingqing Liu , Zheng Shu , Xiwang Liu , Jie Li , Weifeng Yang , Ronghua Lu , Shensheng Han , Jing Chen

Electronic processes within atoms and molecules reside on the timescale of attoseconds. Recent advances in the laser-based pump-probe interrogation techniques have made possible the temporal resolution of ultrafast electronic processes on…

Atomic Physics · Physics 2024-02-16 Yongzhe Ma , Hongcheng Ni , Jian Wu

Chiral molecules interact and react differently with other chiral objects, depending on their handedness. Therefore, it is essential to understand and ultimately control the evolution of molecular chirality during chemical reactions.…

Chirality is ubiquitous in nature and fundamental in science, from particle physics to metamaterials.The most established technique of chiral discrimination - photoabsorption circular dichroism - relies on the magnetic properties of a…

Ultrafast imaging of molecular chirality is a key step towards the dream of imaging and interpreting electronic dynamics in complex and biologically relevant molecules. Here, we propose a new ultrafast chiral phenomenon exploiting recent…

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