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We study the spontaneous charging and the crystallization of spherical micron-sized water-droplets dispersed in oil by numerically solving, within a Poisson-Boltzmann theory in the geometry of a spherical cell, for the density profiles of…

Soft Condensed Matter · Physics 2013-06-06 Joost de Graaf , Jos Zwanikken , Markus Bier , Arjen Baarsma , Yasha Oloumi , Mischa Spelt , Rene van Roij

We introduce a new experimental approach to study the structural transitions of large numbers of nanoparticle-coated droplets as their volume is reduced. We use an emulsion system where the dispersed phase is slightly soluble in the…

Soft Condensed Matter · Physics 2012-09-28 Sujit S. Datta , Ho Cheung Shum , David A. Weitz

Self-assembly processes allow us to design and create complex nanostructures using molecules as building blocks and surfaces as scaffolds. This autonomous driven construction is possible due to a complex thermodynamic balance of…

Mesoscale and Nanoscale Physics · Physics 2017-09-06 Sabrina Simoncelli , Yi Li , Emiliano Cortés , Stefan A. Maier

Emulsion fuels have the potential to reduce both particulate matter and NOx emissions and can potentially improve the efficiency of combustion engines. However, their limited stability remains a critical barrier to practical use as an…

We study water-in-oil emulsion droplets, running the Belousov-Zhabotinsky reaction, that form a new type of active matter unit. These droplets, stabilised by surfactants dispersed in the oil medium, are capable of internal chemical…

Soft Condensed Matter · Physics 2012-06-14 Shashi Thutupalli , Stephan Herminghaus

Ordering nanoparticles into a desired super-structure is often crucial for their technological applications. We use molecular dynamics simulations to study the assembly of nanoparticles in a polymer brush randomly grafted to a planar…

Soft Condensed Matter · Physics 2017-12-11 Shengfeng Cheng , Mark J. Stevens , Gary S. Grest

We report a study of reversible adsorption of DNA-coated colloids on complementary functionalized oil droplets. We show that it is possible to control the surface coverage of oil droplets by colloidal particles, by exploiting the fact that…

We outline a concept of self-assembled soft matter devices based on micro-fluidics, which use surfactant bilayer membranes as their main building blocks, arrested in geometric structures provided by top-down lithography. Membranes form…

Soft Condensed Matter · Physics 2011-03-29 Shashi Thutupalli , Stephan Herminghaus , Ralf Seemann

Structural colors are produced by wavelength-dependent scattering of light from nanostructures. While living organisms often exploit phase separation to directly assemble structurally colored materials from macromolecules, synthetic…

Designable media can control properties of nanocomposite materials by spatially organizing nanoparticles. Here we theoretically study particle organization by ultrathin polymer films of grafted chains (``brushes''). Polymer-soluble…

Soft Condensed Matter · Physics 2009-11-07 Jaeup U. Kim , Ben O'Shaughnessy

The directed self-assembly of colloidal nanoparticles (NPs) using external fields guides the formation of sophisticated hierarchical materials but becomes less effective with decreasing particle size. As an alternative, electron-beam-driven…

Soft Condensed Matter · Physics 2024-09-13 Jonathan G. Raybin , Ethan J. Dunsworth , Veronica Guo , Naomi S. Ginsberg

Oils and fragrances can be encapsulated by using composite shells of silica nanoparticles, polymer and surfactant (potassium oleate). The template for the creation of the core-shell structure is a particle stabilized (Pickering) emulsion.…

Soft Condensed Matter · Physics 2020-09-11 T. G. Slavova , G. M. Radulova , P. A. Kralchevsky , K. D. Danov

Physical properties of composite materials can be pre-engineered by controlling their structure and composition at the mesoscale. Yet, approaches for achieving this are limited and rarely scalable. We introduce a new breed of self-assembled…

Soft Condensed Matter · Physics 2018-01-09 Qingkun Liu , Ivan I. Smalyukh

We have developed Norland Optical Adhesive (NOA) flow focusing devices, making use of the excellent solvent compatibility and surface properties of NOA to generate micron scale oil-in-water emulsions with polydispersities as low as 5%.…

Soft Condensed Matter · Physics 2017-02-08 Max Meissner , Jun Dong , Jens Eggers , Annela M. Seddon , C. Patrick Royall

Binary mixtures of water with lower alcohols display non-linear phase behaviour upon mixing which are attributed to potential cluster formation at molecular level. Unravelling such elusive structures requires the investigation of…

Soft Condensed Matter · Physics 2023-10-09 Riccardo Morbidini , Robert M. Edkins , Mark Devonport , Gøran Nilsen , Tilo Seydel , Katharina Edkins

Several oil-water separation techniques have been proposed to improve the capacity of cleaning water. With the technological possibility of producing materials with antagonist wetting behavior, as for example a substrate that repeal water…

Soft Condensed Matter · Physics 2024-06-14 Cristina Gavazzoni , Marion Silvestrini , Carolina Brito

Paint marbling refers to techniques for creating intricate designs in colored paints floating on a liquid surface. If the marbling motions are executed slowly, then this layer of paints can be modeled as a two-dimensional incompressible…

Fluid Dynamics · Physics 2018-10-05 Aubrey Jaffer

Particles that can be trapped in optical tweezers range from tens of microns down to tens of nanometres in size. Interestingly, this size range includes large macromolecules. We show experimentally, in agreement with theoretical…

Optics · Physics 2007-05-23 W. Singer , T. A. Nieminen , N. R. Heckenberg , H. Rubinsztein-Dunlop

Electrochemical etching of semiconductors, apart from many technical applications, provides an interesting experimental setup for self-organized structure formation capable e.g. of regular, diameter-modulated, and branching pores. The…

Pattern formation induced by wrinkling is a very common phenomenon exhibited in soft-matter substrates. In all these systems wrinkles develop in presence of compressively stressed thin films lying on compliant substrates. Here we…

Mesoscale and Nanoscale Physics · Physics 2019-03-26 Maria Caterina Giordano , Francesco Buatier de Mongeot