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Quasi-equilibrium approximation is a widely used closure approximation approach for model reduction with applications in complex fluids, materials science, etc. It is based on the maximum entropy principle and leads to thermodynamically…

Numerical Analysis · Mathematics 2021-10-19 Shan Jiang , Haijun Yu

The phase diagram of water harbours many mysteries: some of the phase boundaries are fuzzy, and the set of known stable phases may not be complete. Starting from liquid water and a comprehensive set of 50 ice structures, we compute the…

Statistical Mechanics · Physics 2021-01-27 Aleks Reinhardt , Bingqing Cheng

We test a method to reduce unwanted sample variance when predicting Lyman-$\alpha$ (ly$\alpha$) forest power spectra from cosmological hydrodynamical simulations. Sample variance arises due to sparse sampling of modes on large scales and…

Cosmology and Nongalactic Astrophysics · Physics 2018-11-16 Lauren Anderson , Andrew Pontzen , Andreu Font-Ribera , Francisco Villaescusa-Navarro , Keir K. Rogers , Shy Genel

This paper generalises the hybrid power spectrum estimator developed in Efstathiou (2004a) to the estimation of polarization power spectra of the cosmic microwave background radiation. The hybrid power spectrum estimator is unbiased and we…

Astrophysics · Physics 2009-11-11 G. Efstathiou

This work expands on our recently introduced low Mach enthalpy method [1] for simulating the melting and solidification of a phase change material (PCM) alongside (or without) an ambient gas phase. The method captures PCM's volume change…

Fluid Dynamics · Physics 2025-03-11 Ramakrishnan Thirumalaisamy , Amneet Pal Singh Bhalla

First-principles particle-in-cell (PIC) simulation is a powerful tool for understanding plasma behavior, but this power often comes at great computational expense. Artificially reducing the ion/electron mass ratio is a time-honored practice…

Plasma Physics · Physics 2022-01-14 Gregory R. Werner , Scott Robertson , Thomas G. Jenkins , Andrew M. Chap , John R. Cary

Accurate low dimension chemical kinetic models for methane are an essential component in the design of efficient gas turbine combustors. Kinetic models coupled to computational fluid dynamics (CFD) provide quick and efficient ways to test…

Chemical Physics · Physics 2022-06-10 Mark Kelly , Gilles Bourque , Stephen Dooley

The shift in chemical equilibria due to isotope substitution is often exploited to gain insight into a wide variety of chemical and physical processes. It is a purely quantum mechanical effect, which can be computed exactly using…

Statistical Mechanics · Physics 2014-07-04 Michele Ceriotti , Thomas E. Markland

A common approach to model complex chemistry in numerical simulations is via post-processing of existing magneto-hydrodynamic simulations, relying on computing the evolution of chemistry over the dynamic history of a subset of particles…

Solar and Stellar Astrophysics · Physics 2021-07-07 Simón Ferrada-Chamorro , Alessandro Lupi , Stefano Bovino

We present a novel technique by which highly-segmented electrostatic configurations can be solved. The Robin Hood method is a matrix-inversion algorithm optimized for solving high density boundary element method (BEM) problems. We…

Computational Physics · Physics 2011-11-23 J. A. Formaggio , P. Lazic , T. J. Corona , H. Stefancic , H. Abraham , F. Gluck

We present an application of Wertheim's Thermodynamic Perturbation Theory (TPT1) to a simple coarse grained model made of flexibly bonded Lennard-Jones monomers. We use both the Reference Hyper-Netted-Chain (RHNC) and Mean Spherical…

Statistical Mechanics · Physics 2016-08-15 L. González MacDowell , M. Mueller , C. Vega , K. Binder

Modern advances in generating ultrabright electron beams have unlocked unprecedented experimental advances based on synchrotron radiation. Current challenges lie in improving the quality of electron sources with novel photocathode materials…

Materials Science · Physics 2024-02-27 Julia Santana-Andreo , Holger-Dietrich Saßnick , Caterina Cocchi

High-throughput density-functional calculations of solids are extremely time consuming. As an alternative, we here propose a machine learning approach for the fast prediction of solid-state properties. To achieve this, LSDA calculations are…

Materials Science · Physics 2014-05-23 K. T. Schütt , H. Glawe , F. Brockherde , A. Sanna , K. R. Müller , E. K. U. Gross

The athermal quasistatic deformation method provides an elegant solution to overcome the limitation of short time spans in molecular simulations. It provides overdamped conditions, allowing for the extraction of purely structural responses…

Computational Physics · Physics 2026-04-30 Maximilian Reihn , Franz Bamer , Benjamin Stamm

Structural and thermodynamic consistency of coarse-graining models across multiple length scales is essential for the predictive role of multi-scale modeling and molecular dynamic simulations that use mesoscale descriptions. Our approach is…

Soft Condensed Matter · Physics 2014-07-04 J. McCarty , A. J. Clark , J. Copperman , M. G. Guenza

Smoothed Dissipative Particle Dynamics (SDPD) is a mesoscopic method which allows to select the level of resolution at which a fluid is simulated. In this work, we study the consistency of the resulting thermodynamic properties as a…

Statistical Mechanics · Physics 2016-10-19 G. Faure , J. Roussel , J. -B. Maillet , G. Stoltz

We have developed and implemented a new quantum molecular dynamics approximation that allows fast and accurate simulations of dense plasmas from cold to hot conditions. The method is based on a carefully designed orbital-free implementation…

Plasma Physics · Physics 2015-06-22 Travis Sjostrom , Jerome Daligault

Exploiting Chemical Short-Range Order (CSRO) is a promising avenue for manipulating the properties of alloys. However, existing modeling frameworks are not sufficient to predict CSRO in multicomponent alloys (>3 components) in an efficient…

Materials Science · Physics 2024-02-16 Chu-Liang Fu , Rajendra Prasad Gorrey , Bi-Cheng Zhou

Analytic expressions for the energy eigenvalues and eigenfunctions of a one-dimensional harmonic crystal are obtained. The average energy and density profiles are obtained numerically as a function of temperature. A surprisingly large…

Quantum Physics · Physics 2021-08-30 Phil Attard

We propose a new method to compute the free energy or enthalpy of fluids or disordered solids by computer simulation . The main idea is to construct a reference system by freezing one representative configuration, and then carry out a…

Computational Physics · Physics 2011-03-16 Friederike Schmid , Tanja Schilling