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The density functional theory (DFT) is used to investigate the mechanical properties of pure, fully hydrogenated, semi-hydrogenated, fully fluorinated, and semi-fluorinated germanene sheets, including Young's and bulk moduli, and plastic…

Materials Science · Physics 2021-04-07 M. Goli , S. M. Mozvashi , P. Aghdasi , Sh. Yousefi , R. Ansari

The semiconductor Bloch equations (SBEs) are routinely used for simulations of strong-field laser-matter interactions in condensed matter. In systems without inversion or time-reversal symmetries, the Berry connections and transition dipole…

Atomic Physics · Physics 2020-05-13 Lun Yue , Mette B. Gaarde

Electronic structure calculation of atoms and molecules, in the past few decades has largely been dominated by density functional methods. This is primarily due to the fact that this can account for electron correlation effects in a…

Chemical Physics · Physics 2013-07-12 Amlan K. Roy

Using a computationally inexpensive frozen phonon approach we have developed a technique which can be used to screen large unit cell materials and systems for enhanced superconducting critical temperatures. The method requires only density…

Superconductivity · Physics 2024-05-07 Oliver A. Dicks , Kateryna Foyevtsova , Ilya Elfimov , Rohit Prasankumar , George Sawatzky

Quantum chemistry and condensed matter physics are among the most promising applications of quantum computers. Further, estimating properties of a material is crucial to evaluate its industrial applications. To investigate charge…

Quantum Physics · Physics 2026-02-19 Erik Schultheis , Alexander Rehn , Gabriel Breuil

The accuracy of bulk property predictions in density functional theory (DFT) calculations depends on the choice of exchange-correlation functional. While the Perdew-Burke-Ernzerhof (PBE) functional systematically overestimates lattice…

We present a critical analysis of the popular fragment-orbital density-functional theory (FO-DFT) scheme for the calculation of electronic coupling values. We discuss the characteristics of different possible formulations or 'flavors' of…

Materials Science · Physics 2016-02-17 Christoph Schober , Karsten Reuter , Harald Oberhofer

Detailed physisorption data from experiment for the H_2 molecule on low-index Cu surfaces challenge theory. Recently, density-functional theory (DFT) has been developed to account for nonlocal correlation effects, including van der Waals…

Density Functional Tight-Binding (DFTB), an approximative approach derived from Density Functional Theory (DFT), has the potential to pave the way for simulations of large periodic or non-periodic systems. We have specifically tailored DFTB…

In crystalline solids, disorder breaks translational symmetry and obscures k-resolved Bloch states, limiting an accurate description of wavefunction-based observables. In this work, we present a method that unfolds not only the band…

Materials Science · Physics 2026-03-03 T. Thuy Hoang , Kunihiro Yananose , Sungjong Woo , Seongjin Ahn , Dong Han , Xian-Bin Li , Junhyeok Bang

We present a unified theory for wave-packet dynamics of electrons in crystals subject to perturbations varying slowly in space and time. We derive the wave-packet energy up to the first order gradient correction and obtain all kinds of…

Condensed Matter · Physics 2009-10-31 Ganesh Sundaram , Qian Niu

The knowledge of effective masses is a key ingredient to analyze numerous properties of semiconductors, like carrier mobilities, (magneto-)transport properties, or band extrema characteristics yielding carrier densities and density of…

Classical density functional theory (DFT) is the primary method for investigations of inhomogeneous fluids in external fields. It requires the excess Helmholtz free energy functional as input to an Euler-Lagrange equation for the one-body…

Soft Condensed Matter · Physics 2026-02-05 S. M. Tschopp , H. Vahid , J. M. Brader

While standard computational protocols for density functional theory (DFT) have universal applicability, differences exist in code implementations. Specific applications require manual parameter optimization, whereas high-throughput…

Materials Science · Physics 2025-08-12 Chenxi Lu , Musen Li , Jeffrey R. Reimers

We present the TRIQS/DFTTools package, an application based on the TRIQS library that connects this toolbox to realistic materials calculations based on density functional theory (DFT). In particular, TRIQS/DFTTools together with TRIQS…

The non-trivial geometry encoded in the Quantum Mechanical wavefunctions has important consequences for its single-particle as well as many-body dynamics. Yet, our understanding of how the geometry of the single-particle eigenstates are…

Superconductivity · Physics 2020-05-27 Sina Zeytinoğlu , Atac İmamoğlu , Sebastian Huber

We present two modules that expand functionalities of the all-electron full-potential density functional theory package WIEN2k for computation of the Chern and $Z_2$ topological invariants. Characterization of topological properties relies…

Computational Physics · Physics 2023-08-28 Andres F. Gomez-Bastidas , Oleg Rubel

We study Density Functional Theory models for systems which are translationally invariant in some directions, such as a homogeneous 2-d slab in the 3-d space. We show how the different terms of the energy are modified and we derive reduced…

Mathematical Physics · Physics 2021-12-24 David Gontier , Salma Lahbabi , Abdallah Maichine

Density-functional theory (DFT) has revolutionized computational prediction of atomic-scale properties from first principles in physics, chemistry and materials science. Continuing development of new methods is necessary for accurate…

We derive a generalized gradient approximation to the exchange energy to be used in density functional theory calculations of two-dimensional systems. This class of approximations has a long and successful history, but it has not yet been…

Strongly Correlated Electrons · Physics 2009-01-07 S. Pittalis , E. Rasanen , J. G. Vilhena , M. A. L. Marques