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In this work, we conducted molecular dynamics simulations to study the fracture mechanism of ice crystals in a bulk phase and at ice-ice interfaces at the atomistic scale. We show that there exists a narrow disordered interfacial layer…

Chemical Physics · Physics 2019-07-23 A. Afshar , J. Zhong , D. S. Thompson , D. Meng

The paper presents an analytical theory and numerical simulations of the dipolar response of hydrated proteins. The effective dielectric constant of the solvated protein, representing the average dipole moment induced at the protein by a…

Biological Physics · Physics 2015-05-30 Dmitry V. Matyushov

Dipolar susceptibility of interfacial water and the corresponding interface dielectric constant were calculated from numerical molecular dynamics simulations for neutral and charged states of buckminsterfullerene C$_{60}$. Dielectric…

Liquid water exhibits several important anomalous properties in the vicinity of the melting temperature ($T_{\mathrm{m}}$) of ice Ih, including a higher density than ice and a density maximum at 4~$^{\circ}$C. Experimentally, an isotope…

Chemical Physics · Physics 2026-01-01 Yifan Li , Bingjia Yang , Chunyi Zhang , Axel Gomez , Pinchen Xie , Yixiao Chen , Pablo M. Piaggi , Roberto Car

The structural dynamics of ice in the freezing - thawing process has been studied in the context of the concept of two-phase water. It was previously shown that water is a two-phase system consisting of free and bound (liquid crystal)…

Soft Condensed Matter · Physics 2018-11-21 T. Yakhno , V. Yakhno

The morphology of water ice in the interstellar medium is still an open question. Although accretion of gaseous water could not be the only possible origin of the observed icy mantles covering dust grains in cold molecular clouds, it is…

The static dielectric properties of dense ionic fluids, e.g., room temperature ionic liquids (RTILs) and inorganic fused salts, are investigated on different length scales by means of grandcanonical Monte Carlo simulations. A generally…

Soft Condensed Matter · Physics 2015-05-14 Grigory Zarubin , Markus Bier

It is well known that the dielectric constant of two-dimensional (2D) electron system goes negative at low electron densities. A consequence of the negative dielectric constant could be the formation of the droplet state. The droplet state…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Junren Shi , Song He , X. C. Xie

In this paper, a review on dielectric mixtures and the importance of the numerical simulations of dielectric mixtures are presented. It stresses on the interfacial polarization observed in mixtures. It is shown that this polarization can…

Materials Science · Physics 2016-11-18 Enis Tuncer , Yuriy V. Serdyuk , Stanislaw M. Gubanski

Using classical density functional theory (DFT) in a modified mean-field approximation we investigate the fluid phase behavior of quasi-two dimensional dipolar fluids confined to a plane. The particles carry three-dimensional dipole moments…

Statistical Mechanics · Physics 2013-06-18 R. Geiger , S. H. Klapp

The strengths and short-comings of the point-dipole model for polar fluids of spherical molecules are illustrated by considering the physically more relevant case of extended dipoles formed by two opposite charges $\pm q$ separated by a…

Statistical Mechanics · Physics 2009-11-10 V. Ballenegger , J. P. Hansen

We introduce a novel approach to sample the canonical ensemble at constant temperature and applied electric potential. Our approach can be straightforwardly implemented into any density-functional theory code. Using thermopotentiostat…

Materials Science · Physics 2021-04-07 F. Deißenbeck , C. Freysoldt , M. Todorova , J. Neugebauer , S. Wippermann

The surface of a polar liquid presents a special environment for the solvation and organization of charged solutes, which differ from bulk behaviors in important ways. These differences have motivated many attempts to understand…

Soft Condensed Matter · Physics 2022-06-07 Stephen J. Cox , Phillip L. Geissler

Higher superconducting critical temperature and large-area epsilon-near-zero interfaces are two long-standing goals of Condensed Matter Physics and Optics. Motivated by the recent advancements of experimental interests on metallic…

Previous calculations of the dielectric and optical properties of 2D materials often overlooked or circumvented the influence of vacuum spacing introduced in periodic calculations, which gave rise to mispredictions of the intrinsic…

Materials Science · Physics 2021-10-26 Guang Yang , Shang-Peng Gao

Out-of-plane and in-plane electric polarization, which rarely coexist in a two-dimensional (2D) ferroelectric material, offer different advantages in ferroelectricity-based devices. Here, we report the coexistence of in-plane and…

Materials Science · Physics 2026-03-24 A. D. Molchanova , L. H. Yin , L. P. Gao , W. H. Song , Y. P. Sun , K. R. Allahverdiyev , M. N. Popova

The static dielectric constant of liquid water is computed using classical force field based molecular dynamics simulation at fixed electric displacement D. The method to constrain the electric displacement is the finite temperature…

Chemical Physics · Physics 2016-04-07 Chao Zhang , Michiel Sprik

Structural and thermodynamic properties of high-density amorphous (HDA) ice have been studied by path-integral molecular dynamics simulations in the isothermal-isobaric ensemble. Interatomic interactions were modeled by using the effective…

Chemical Physics · Physics 2012-09-20 Carlos P. Herrero , Rafael Ramirez

In this work we present the dielectric behavior of water with a novel flexible model that improved all three sites water models Different concentrations of the ionic liquid 1- butyl-3-methylimidazolium [bmim]…

We study a system of ultra cold dipolar Bose gas atoms confined in a two-dimensional (2D) harmonic trap with a dipolar impurity implanted at the center of the trap. Due to recent experimental progress in dipolar condensates, we focused on…

Quantum Gases · Physics 2025-04-10 Neelam Shukla , Jeremy R Armstrong