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We revisit quantum phase estimation algorithms for the purpose of obtaining the energy levels of many-body Hamiltonians and pay particular attention to the statistical analysis of their outputs. We introduce the mean phase direction of the…

Quantum Physics · Physics 2020-08-20 P. M. Q. Cruz , G. Catarina , R. Gautier , J. Fernández-Rossier

The calculation of excited state energies of electronic structure Hamiltonians has many important applications, such as the calculation of optical spectra and reaction rates. While low-depth quantum algorithms, such as the variational…

Quantum Physics · Physics 2019-07-03 Oscar Higgott , Daochen Wang , Stephen Brierley

The eigenvalue density of a matrix plays an important role in various types of scientific computing such as electronic-structure calculations. In this paper, we propose a quantum algorithm for computing the eigenvalue density in a given…

Quantum Physics · Physics 2021-12-13 Yasunori Futamura , Xiucai Ye , Tetsuya Sakurai

We derive out a complete series expression of Hamiltonian eigenvalues without any approximation and cut in the general quantum systems based on Wang's formal framework \cite{wang1}. In particular, we then propose a calculating approach of…

Quantum Physics · Physics 2009-11-12 Zhou Li , An Min Wang

We introduce two kinds of quantum algorithms to explore microcanonical and canonical properties of many-body systems. The first one is a hybrid quantum algorithm that, given an efficiently preparable state, computes expectation values in a…

Quantum Physics · Physics 2021-05-19 Sirui Lu , Mari Carmen Bañuls , J. Ignacio Cirac

We report the first electronic structure calculation performed on a quantum computer without exponentially costly precompilation. We use a programmable array of superconducting qubits to compute the energy surface of molecular hydrogen…

We consider performing phase estimation under the following conditions: we are given only one copy of the input state, the input state does not have to be an eigenstate of the unitary, and the state must not be measured. Most quantum…

Quantum Physics · Physics 2022-12-13 Patrick Rall

We present a quantum algorithm that provides a general approach for obtaining the energy spectrum of a physical system without making a guess on its eigenstates. In this algorithm, a probe qubit is coupled to a quantum register $R$ which…

Quantum Physics · Physics 2014-07-14 Hefeng Wang

A powerful method for calculating the eigenvalues of a Hamiltonian operator consists of converting the energy eigenvalue equation into a matrix equation by means of an appropriate basis set of functions. The convergence of the method can be…

Quantum Physics · Physics 2007-05-23 Paolo Amore , Alfredo Aranda , Francisco Fernandez , Hugh Jones

Determining the energy gap in a quantum many-body system is critical to understanding its behavior and is important in quantum chemistry and condensed matter physics. The challenge of determining the energy gap requires identifying both the…

Quantum Physics · Physics 2026-03-04 Mengzhen Ren , Yu-Cheng Chen , Ching-Jui Lai , Min-Hsiu Hsieh , Alice Hu

Accurate computation of multiple eigenvalues of quantum Hamiltonians is essential in quantum chemistry, materials science, and molecular spectroscopy. Estimating excited-state energies is challenging for classical algorithms due to…

Quantum Physics · Physics 2026-05-22 Grzegorz Rajchel-Mieldzioć , Szymon Pliś , Emil Zak

Expectation value estimation is ubiquitous in quantum algorithms. The expectation value of a Hamiltonian, which is essential in various practical applications, is often estimated by measuring a large number of Pauli strings on quantum…

In projective measurements of energy, a target system is projected to an eigenstate of the system Hamiltonian, and the measurement outcomes provide the information of corresponding eigen-energies. Recently, it has been shown that such a…

Quantum Physics · Physics 2017-06-14 Yuichiro Matsuzaki , Shojun Nakayama , Akihito Soeda , Mio Murao , Shiro Saito

The well-known algorithm for quantum phase estimation requires that the considered unitary is available as a conditional transformation depending on the quantum state of an ancilla register. We present an algorithm converting an unknown…

Quantum Physics · Physics 2007-05-23 Dominik Janzing

The preparation of Hamiltonian eigenstates is essential for many applications in quantum computing; the efficiency with which this can be done is of key interest. A canonical approach exploits the quantum phase estimation (QPE) algorithm.…

Quantum Physics · Physics 2022-12-05 Richard Meister , Simon C. Benjamin

Phase estimation is a quantum algorithm for measuring the eigenvalues of a Hamiltonian. We propose and rigorously analyse a randomized phase estimation algorithm with two distinctive features. First, our algorithm has complexity independent…

Quantum Physics · Physics 2022-08-09 Kianna Wan , Mario Berta , Earl T. Campbell

An approximation-free, numerically efficient algorithm is presented for the Hamiltonian eigen-states of the Stark-Hydrogen problem describing a quantum particle exposed to the central Coulomb force and a homogeneous external field. As an…

Atomic Physics · Physics 2022-03-17 Seyedmohammad Yusofsani , Mroslav Kolesik

Quantum simulation of complex quantum systems and their properties often requires the ability to prepare initial states in an eigenstate of the Hamiltonian to be simulated. In addition, to compute the eigenvalues of a Hamiltonian is in…

Quantum Physics · Physics 2020-05-21 Jing-Ning Zhang , Iñigo Arrazola , Jorge Casanova , Lucas Lamata , Kihwan Kim , Enrique Solano

We propose a quantum algorithm to compute low-energy expectation values of a quantum Hamiltonian by sampling a partition function associated with the average energy of that Hamiltonian. For any given quantum circuit-Hamiltonian pair, there…

Quantum Physics · Physics 2022-03-14 Judah F. Unmuth-Yockey

Estimating the eigenvalues of non-normal matrices is a foundational problem with far-reaching implications, from modeling non-Hermitian quantum systems to analyzing complex fluid dynamics. Yet, this task remains beyond the reach of standard…

Quantum Physics · Physics 2025-10-23 Yukun Zhang , Yusen Wu , Xiao Yuan