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We study non-classical pathways and quantum interference in enhanced ionisation of diatomic molecules in strong laser fields using machine learning techniques. Quantum interference provides a bridge, which facilitates intramolecular…

A new formalism for the optimal control of quantum mechanical physical observables is presented. This approach is based on an analogous classical control technique reported previously[J. Botina, H. Rabitz and N. Rahman, J. chem. Phys. Vol.…

Chemical Physics · Physics 2009-10-30 Jair Botina , Herschel Rabitz , Naseem Rahman

Properly designed control has been shown to be particularly advantageous for improving AQC accuracy and time complexity scaling. Here, an \emph{in situ} quantum control optimization protocol is developed to indirectly optimize state…

Quantum Physics · Physics 2019-06-12 Gregory Quiroz

The methods of mathematical control theory are widely used in the modern physics, but still they are less popular in quantum science. We will discuss the aspects of control theory, which are the most useful in applications to the real…

Optics · Physics 2008-02-22 Saifullah , Sergei Borisenok

A quantum system subject to external fields is said to be controllable if these fields can be adjusted to guide the state vector to a desired destination in the state space of the system. Fundamental results on controllability are reviewed…

Nuclear Theory · Physics 2008-11-26 John W. Clark , Dennis G. Lucarelli , Tzyh-Jong Tarn

A gradient ascent method for optimal quantum control synthesis is presented that employs a gradient derived with respect to the coefficients of a functional basis expansion of the control. Restricting the space of allowable controls to…

Quantum Physics · Physics 2018-07-04 Dennis Lucarelli

We propose in this paper a gradient-type dynamical system to solve the problem of maximizing quantum observables for finite dimensional closed quantum ensembles governed by the controlled Liouville-von Neumann equation. The asymptotic…

Optimization and Control · Mathematics 2011-10-03 Ruixing Long , Herschel Rabitz

The successful application of Quantum Optimal Control (QOC) over the past decades unlocked the possibility of directing the dynamics of quantum systems. Nevertheless, solutions obtained from QOC algorithms are usually highly irregular,…

Quantum Physics · Physics 2020-02-26 Martin Larocca , Esteban A. Calzetta , Diego A. Wisniacki

Ultra-cold atomic gases are unique in terms of the degree of controllability, both for internal and external degrees of freedom. This makes it possible to use them for the study of complex quantum many-body phenomena. However in many…

Quantum Physics · Physics 2020-09-30 Rick Mukherjee , Frederic Sauvage , Harry Xie , Robert Löw , Florian Mintert

A class of optimal control problems governed by linear fractional diffusion equation with control constraint is considered. We first establish some results on the existence of strong solution to the state equation and the existence of…

Optimization and Control · Mathematics 2022-11-24 Bui Trong Kien , Bui Ngoc Muoi , Ching-Feng Wen , Jen-Chih Yao

A broad class of hybrid quantum-classical algorithms known as "variational algorithms" have been proposed in the context of quantum simulation, machine learning, and combinatorial optimization as a means of potentially achieving a quantum…

Quantum Physics · Physics 2021-04-09 Aram Harrow , John Napp

A quantum fluid dynamic control formulation is presented for optimally manipulating atomic and molecular systems. In quantum fluid dynamic the control quantum system is expressed in terms of the probability density and the quantum current.…

Chemical Physics · Physics 2009-11-06 Bijoy K. Dey , Herschel Rabitz , Attila Askar

The ability to engineer high-fidelity gates on quantum processors in the presence of systematic errors remains the primary barrier to achieving quantum advantage. Quantum optimal control methods have proven effective in experimentally…

Quantum Physics · Physics 2021-03-30 Thomas Propson , Brian E. Jackson , Jens Koch , Zachary Manchester , David I. Schuster

Genetic learning algorithms are widely used to control ultrafast optical pulse shapes for photo-induced quantum control of atoms and molecules. An unresolved issue is how to use the solutions found by these algorithms to learn about the…

Quantum Physics · Physics 2009-11-10 J. L. White , B. J. Pearson , P. H. Bucksbaum

Different ways of modelling quantum control systems, formulating control problems and solving the resulting problems are considered and compared. In particular, we compare the performance of geometric and optimal control, as well as…

Quantum Physics · Physics 2008-01-08 Sonia G Schirmer , Peter J Pemberton-Ross , Xiaoting Wang

A central aspect for operating future quantum computers is quantum circuit optimization, i.e., the search for efficient realizations of quantum algorithms given the device capabilities. In recent years, powerful approaches have been…

Quantum Physics · Physics 2021-03-16 Thomas Fösel , Murphy Yuezhen Niu , Florian Marquardt , Li Li

Quantum optimal control problems are typically solved by gradient-based algorithms such as GRAPE, which suffer from exponential growth in storage with increasing number of qubits and linear growth in memory requirements with increasing…

Quantum Physics · Physics 2022-10-18 Xian Wang , Paul Kairys , Sri Hari Krishna Narayanan , Jan Hückelheim , Paul Hovland

Higher-dimensional quantum systems, such as qudits, offer architectural and algorithmic advantages over qubits, but their increased spectral crowding and limited controllability render high-fidelity quantum gates particularly challenging.…

Quantum Physics · Physics 2026-04-23 Amine Jaouadi , Sahel Ashhab

Quantum optimization, a key application of quantum computing, has traditionally been stymied by the linearly increasing complexity of gradient calculations with an increasing number of parameters. This work bridges the gap between Koopman…

Quantum Physics · Physics 2024-05-07 Di Luo , Jiayu Shen , Rumen Dangovski , Marin Soljačić

Direct optimal control theory for quantum dynamical problems presents itself as an interesting alternative to the traditional indirect optimal control. The method relies on the first discretize and then optimize paradigm, where a…

Chemical Physics · Physics 2022-01-19 A. R. Ramos Ramos , O. Kühn