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We investigate the prospects of creating broad rotational wave packets by means of molecular interaction with long sequences of intense femtosecond pulses. Using state-resolved rotational Raman spectroscopy of oxygen, subject to a sequence…

Quantum Physics · Physics 2016-01-27 M. Bitter , V. Milner

A quantum simulation of vibrational strong coupling (VSC) in the collective regime via thermostatted ring-polymer molecular dynamics (TRPMD) is reported. For a collection of liquid-phase water molecules resonantly coupled to a single…

Chemical Physics · Physics 2022-03-08 Tao E. Li , Abraham Nitzan , Sharon Hammes-Schiffer , Joseph E. Subotnik

We present a rigorous study of vibrational relaxation in p-H2 + p-H2 collisions at cold and ultracold temperatures and identify an efficient mechanism of ro-vibrational energy transfer. If the colliding molecules are in different rotational…

Quantum Physics · Physics 2008-04-02 Goulven Quéméner , Naduvalath Balakrishnan , Roman V. Krems

We show that the excitation probability of a state within a manifold of levels undergoes Rabi oscillations with frequency determined by the energy difference between the states and not by the pulse area for sufficiently strong pulses. The…

Quantum Physics · Physics 2018-04-04 B. Y. Chang , I. R. Sola , Vladimir S. Malinovsky

We report the binding energy of $^{87}$Rb$^{133}$Cs molecules in their rovibrational ground state measured using an offset-free optical frequency comb based on difference frequency generation technology. We create molecules in the absolute…

A method for gaining information about the phonon-number moments and the generalized nonlinear and linear quadratures in the motion of trapped ions (in particular, position and momentum) is proposed, valid inside and outside the Lamb-Dicke…

Quantum Physics · Physics 2009-11-11 T. Bastin , J. von Zanthier , E. Solano

Precision measurements are performed on highly excited vibrational quantum states of molecular hydrogen. The $v=12, J=0-3$ rovibrational levels of H$_2$ ($X^1\Sigma_g^+$), lying only $2000$ cm$^{-1}$ below the first dissociation limit, were…

Atomic Physics · Physics 2015-09-30 M. L. Niu , E. J. Salumbides , W. Ubachs

We demonstrate theoretically that it is possible to use Rabi oscillations to coherently control the electron tunneling in an asymmetric double quantum dot system, a quantum dot molecule. By applying an optical pump pulse we can excite an…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 J. M. Villas-Boas , A. O. Govorov , Sergio E. Ulloa

Using a mid-infrared quantum cascade laser and wavelength modulation absorption spectroscopy, we measure the frequencies of ro-vibrational transitions of N$_2$O in the 17 $\mu$m region with uncertainties below 5 MHz. These lines,…

Atomic Physics · Physics 2025-12-10 Y. Wang , J. Rodewald , O. Lopez , M. Manceau , B. Darquié , B. E. Sauer , M. R. Tarbutt

We demonstrate coherent one-color photoassociation of a Bose-Einstein condensate, which results in Rabi oscillations between atomic and molecular condensates. We attain atom-molecule Rabi frequencies that are comparable to decoherence rates…

Atomic Physics · Physics 2013-10-11 Mi Yan , B. J. DeSalvo , Ying Huang , P. Naidon , T. C. Killian

Optical trapping techniques are an efficient way to probe limited quantities of rare isotopes. In order to achieve the highest possible measurement precision, it is critical to optimize the optical trapping efficiency. This work presents…

Wave modes induced by cross-phase reshaping of a probe photon in the guiding structure of a periodic train of temporal pulses are investigated theoretically with emphasis on exact solutions to the wave equation for the probe. The study has…

Pattern Formation and Solitons · Physics 2021-09-16 Alain M. Dikande

We review the recent developments which had taken place in the domain of quasi one dimensional BECs from the viewpoint of integrability. To start with, we consider the dynamics of scalar BECs in a time independent harmonic trap and observe…

Quantum Gases · Physics 2015-01-21 R. Radha , P. S. Vinayagam

It is predicted that nuclear spin conversion in molecules can be efficiently controlled by strong laser radiation resonant to rovibrational molecular transition. The phenomenon can be used for substantial enrichment of spin isomers, or for…

Chemical Physics · Physics 2009-11-06 P. L. Chapovsky

Magnetically induced (MI) transitions (F${}_{g}$ = 1 $\rightarrow$ F${}_{e}$= 3) of ${}^{87}$Rb D${}_{2}$ line are among the most promising atomic transitions for applications in laser physics. They reach their maximum intensity in the…

Atomic Physics · Physics 2023-05-10 Ara Tonoyan , Armen Sargsyan , Rodolphe Momier , Claude Leroy , David Sarkisyan

This article covers few selected aspects of quantum theory of molecular rotations and vibrations. Triatomic molecules are the simplest systems, which show qualitative characteristics of larger polyatomic molecules. On the minimal example of…

Chemical Physics · Physics 2022-03-18 Emil J. Zak

Quantum computation of vibrational properties of molecules is a promising platform to obtain computational advantages for computational chemistry. However, fault-tolerant quantum computations of vibrational properties remain a relatively…

Understanding collisions between ultracold molecules is crucial for making stable molecular quantum gases and harnessing their rich internal degrees of freedom for quantum engineering. Transient complexes can strongly influence collisional…

The average Raman signal power obtained in a modulated optical trap is dependent on the Brownian motion - therefore hydrodynamic properties of the trapped particle. Hence, in addition to the molecular properties obtained from the Raman…

Optics · Physics 2023-11-27 Rohin Sharma , Anusa Thapa , Rijan Maharjan , Ashim Dhakal

Motivated by recent interest in their applications, we report a systematic study of Cs atomic properties calculated by a high-precision relativistic all-order method. Excitation energies, reduced matrix elements, transition rates, and…

Atomic Physics · Physics 2016-07-13 M. S. Safronova , U. I. Safronova , Charles W. Clark