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We investigate the modeling and simulation of ionic transport and charge conservation in lithium-ion batteries (LIBs) at the microscale. It is a multiphysics problem that involves a wide range of time scales. The associated computational…

Numerical Analysis · Mathematics 2025-10-02 Ali Asad , Romain de Loubens , Laurent François , Marc Massot

A formulation is presented to efficiently model ionic conduction inside, i.e. across and along, grain boundaries. Efficiency and accuracy is achieved by reducing it to a two-dimensional manifold while guaranteeing the conservation of mass…

Chemical Physics · Physics 2024-01-15 Stephan Sinzig , Christoph P. Schmidt , Wolfgang A. Wall

This paper considers one of the most commonly used equivalent circuit models (ECMs) for lithium-ion batteries and investigates the sensitivity of the model output to changes of model parameters using the Morris method. Experiments are…

Systems and Control · Computer Science 2017-02-13 Shi Zhao , David A. Howey

Lithium-ion secondary batteries have been used in a wide variety of purposes, such as for powering mobile devices and electric vehicles, but their performance should be improved. One of the factors that limits their performance is the…

A two-dimensional small bias model has been developed for a patterned metal current collector $|$ mixed oxygen ion and electronic conductor (MIEC) $|$ patterned metal current collector electrochemical cell in a symmetric gas environment.…

Chemical Physics · Physics 2009-03-20 Francesco Ciucci , William C. Chueh , Sossina M. Haile , David G. Goodwin

This manuscript presents an algorithm for individual Lithium-ion (Li-ion) battery cell state of charge (SOC) estimation when multiple cells are connected in parallel, using only terminal voltage and total current measurements. For battery…

Systems and Control · Electrical Eng. & Systems 2020-11-11 Dong Zhang , Luis D. Couto , Sebastien Benjamin , Wente Zeng , Daniel F. Coutinho , Scott J. Moura

We present the implementation and application of a multiphysics simulation technique to carrier dynamics under electromagnetic excitation in supported two-dimensional electronic systems. The technique combines ensemble Monte Carlo (EMC) for…

Mesoscale and Nanoscale Physics · Physics 2014-05-21 N. Sule , K. J. Willis , S. C. Hagness , I. Knezevic

In this work we analyse the local nonlinear electrochemical impedance spectroscopy (NLEIS) response of a lithium-ion battery and estimate model parameters from measured NLEIS data. The analysis assumes a single-particle model including…

Chemical Physics · Physics 2023-04-24 T. L. Kirk , A. Lewis-Douglas , D. A. Howey , C. P. Please , S. J. Chapman

An appropriate description of the lithiation/delithiation dynamics in bi-phasic primary cathode particles of Li-ion batteries requires an accurate treatment of the conditions holding at the interface between the particle and the surrounding…

Materials Science · Physics 2024-11-01 Ahmed Yousfi , Arnaud Demortière , Guillaume Boussinot

Using the specific model of a system of like charged ions confined between two planar like charged surfaces, we compare the predictions for the energy and density profile of four simulation methods available to treat the long range Coulomb…

Statistical Mechanics · Physics 2007-05-23 M. Mazars , J-M. Caillol , J. -J. Weis , D. Levesque

Mobile ions in hybrid perovskite semiconductors introduce a new degree of freedom to electronic devices suggesting applications beyond photovoltaics. An intuitive device model describing the interplay between ionic and electronic charge…

We develop a theory of charge storage in ultra-narrow slit-like pores of nano\-structured electrodes. Our analysis is based on the Blume-Capel model in external field, which we solve analytically on a Bethe lattice. The obtained solutions…

Soft Condensed Matter · Physics 2020-01-08 Maxym Dudka , Svyatoslav Kondrat , Olivier Bénichou , Alexei A. Kornyshev , Gleb Oshanin

Diffusion-driven processes are important phenomena of materials science in the field of energy conversion and transmission. During the conversion from chemical energy to electrical energy, the species diffusion is generally linked to the…

Applied Physics · Physics 2021-02-23 Jay Santoki

All solid state batteries are claimed to be the next-generation battery system, in view of their safety accompanied by high energy densities. A new advanced, multiscale compatible, and fully three dimensional model for solid electrolytes is…

Applied Physics · Physics 2022-03-15 L. Cabras , D. Danilov , W. Subber , V. Oancea , A. Salvadori

Batteries, supercapacitors, and several other electrochemical devices charge by accumulating ions in the pores of electrolyte-immersed porous electrodes. The charging of such devices has long been interpreted using equivalent circuits and…

Soft Condensed Matter · Physics 2023-12-22 Christian Pedersen , Timur Aslyamov , Mathijs Janssen

With the importance of Li-ion and emerging alternative batteries to our electric future, predicting new sustainable materials, electrolytes and complete cells that safely provide high performance, long life, energy dense capability is…

Materials Science · Physics 2022-07-26 Alex Grant , Colm O'Dwyer

In this article we address the theoretical study of a multiscale drift-diffusion (DD) model for the description of photoconversion mechanisms in organic solar cells. The multiscale nature of the formulation is based on the co-presence of…

Applied Physics · Physics 2018-02-14 Maurizio Verri , Matteo Porro , Riccardo Sacco , Sandro Salsa

Capacity degradation of lithium-ion batteries under long-term cyclic aging is modelled via a flexible sigmoidal-type regression set-up, where the regression parameters can be interpreted. Different approaches known from the literature are…

Applications · Statistics 2019-07-31 Marcus Johnen , Simon Pitzen , Udo Kamps , Maria Kateri , Dirk Uwe Sauer

Computational modeling is vital for the fundamental understanding of processes in Li-ion batteries. However, capturing nanoscopic to mesoscopic phase thermodynamics and kinetics in the solid electrode particles embedded in realistic…

A simulation package employing a Particle in Cell (PIC) method is developed to study the high current beam transport and the dynamics of plasmas. This package includes subroutines those are suited for various planned projects at University…

Accelerator Physics · Physics 2016-06-21 N. Joshi
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