Related papers: Virial relations for electrons coupled to quantum …
We propose a model of ion-electron plasma (or nucleus-electron plasma) that accounts for the electronic structure around nuclei (i.e. ion structure) as well as for ion-ion correlations. The model equations are obtained through the…
Multi-configurational electronic structure theory delivers the most versatile approximations to many-electron wavefunctions, flexible enough to deal with all sorts of transformations, ranging from electronic excitations, to open-shell…
We propose a novel approach to calculate dynamical processes at ultrafast time scale in molecules in which vibrational and electronic motions are strongly mixed. The relevant electronic orbitals and their interactions are described by a…
Merrifield's Variational Ansatz is extended so as to cover the case of two electronic bands mixed by an Einstein phonon. The Hamiltonian is composed of the local and kinetic (hopping) energies in the absence of vibrations, the vibrational…
Starting from the density-matrix equation of motion, we derive a semiclassical kinetic equation for a general two-band electronic Hamiltonian, systematically including quantum-mechanical corrections up to second order in space-time…
A set of interacting particles are coupled to a phenomenological core described using the generalized coherent state model. Among the particle-core states a finite set which have the property that the angular momenta carried by the proton…
The electric polarizability of mesons, in particular, that of the charged pion, is studied in the framework of a semirelativistic description of hadrons as bound states of valence quarks in terms of a Hamiltonian composed of the…
The virial expansion method is applied within a harmonic approximation to an interacting N-body system of identical fermions. We compute the canonical partition functions for two and three particles to get the two lowest orders in the…
The commutation relations of the composite fields are studied in the 3, 2 and 1 space dimensions. It is shown that the field of an atom consisting of a nucleus and an electron fields satisfies, in the space-like asymptotic limit, the…
In a companion paper, we have developed a phase-space electronic structure theory of molecules in magnetic fields, whereby the electronic energy levels arise from diagonalizing a phase-space Hamiltonian $\hat H_{PS}(\bf{X},\bf{\Pi})$ that…
The effects of a magnetic field on the energy and on the spin of free electrons are computed in the framework of quantum field theory. In the case of a constant moderate field and with relatively slow electrons, the derived formulae are…
Embedding materials in optical cavities has emerged as a strategy for tuning material properties. Accurate simulations of electrons in materials interacting with quantum photon fluctuations of a cavity are crucial for understanding and…
Polar optical phonons are studied in the framework of the dielectric continuum approach for a prototypical quantum-dot/quantum-well (QD/QW) heterostructure, including the derivation of the electron-phonon interaction Hamiltonian and a…
To clarify a key role of orbital degrees of freedom in the response of the many-body electron state of correlated electrons to an external field, we investigate the real-time dynamics in an $e_{\rm g}$-orbital Hubbard model under applied…
The Virial Theorem in the one- and two-dimensional spherical geometry are presented, in both classical and quantum mechanics. Choosing a special class of Hypervirial operators, the quantum Hypervirial relations in the spherical spaces are…
It is shown how the exchange interaction, the dipole-dipole interaction, and the Dzyaloshinsky-Moriya interaction between electronic spin-density fluctuations emerge naturally from a field-theoretic framework that couples electrons to the…
The coupled-wire construction provides a useful way to obtain microscopic Hamiltonians for various two-dimensional topological phases, among which fractional quantum Hall states are paradigmatic examples. Using the recently introduced flux…
Interactions between electrons and phonons play a crucial role in quantum materials. Yet, there is no universal method that would simultaneously accurately account for strong electron-phonon interactions and electronic correlations. By…
Boltzmann relations are widely used in semiconductor physics to express the charge-carrier densities as a function of the Fermi level and temperature. However, these simple exponential relations only apply to sharp band edges of the…
A novel soliton-like solution in quantum electrodynamics is obtained via a self-consistent field method. By writing the Hamiltonian of quantum electrodynamics in the Coulomb gauge, we separate out a classical component in the density…