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We report the chemical reaction of single-layer graphene with hydrogen atoms, generated in situ by electron-induced dissociation of hydrogen silsesquioxane (HSQ). Hydrogenation, forming sp3 C-H functionality on the basal plane of graphene,…

Graphene is the first truly two-dimensional (2D) material, possessing a cone-like energy spectrum near the Fermi energy and treated as a gapless semiconductor. Its unique properties trigger researchers to find more applications of it, such…

Mesoscale and Nanoscale Physics · Physics 2022-06-23 Wei-Bang Li , Yu-Ming Wang , Hsien-Ching Chung , Ming-Fa Lin

The electronic structure and structural evolution of hydrogenated graphene are investigated by Raman spectroscopy with multiple excitations. The excitation energy dependent saturation effect on the ratio of integrated intensities of D and G…

Materials Science · Physics 2010-12-06 Zhiqiang Luo , Ting Yu , Zhenhua Ni , Sanhua Lim , Jingzhi Shang , Hailong Hu , Lei Liu , Zexiang Shen , Jianyi Lin

In this paper, we perform large-scale electron-correlated calculations of optoelectronic properties of rectangular graphene-like polycyclic aromatic hydrocarbon molecules. Theoretical methodology employed in this work is based upon…

Materials Science · Physics 2019-05-29 Deepak Kumar Rai , Alok Shukla

An electrodynamic response of graphene to a strong electromagnetic radiation is considered. A hot electron model (HEM) is introduced and a corresponding system of nonlinear equations is formulated. Solutions of this system are found and…

Mesoscale and Nanoscale Physics · Physics 2019-09-18 S. A. Mikhailov

The thermoelectric properties of in plane heterostructures made of Graphene and hexagonal Boron Nitride (BN) have been investigated by means of atomistic simulation. The heterostructures consist in armchair graphene nanoribbons to the sides…

Mesoscale and Nanoscale Physics · Physics 2015-08-19 Van-Truong Tran , Jérôme Saint Martin , Philippe Dollfus

Using the GW approximation, we study the electronic structure of the recently synthesized hydrogenated graphene, named graphane. For both conformations, the minimum band gap is found to be direct at the $\Gamma$ point, and it has a value of…

Materials Science · Physics 2015-05-13 S. Lebegue , M. Klintenberg , O. Eriksson , M. I. Katsnelson

Vertical integration of two-dimensional materials has recently emerged as an exciting method for the design of novel electronic and optoelectronic devices. Using density functional theory, we investigatethe structural and electronic…

Materials Science · Physics 2015-06-25 Yongqing Cai , Gang Zhang , Yong-Wei Zhang

By investigating the optoelectronic properties of prototypical graphene/hexagonal boron nitride (h-BN) heterostructures, we demonstrate how a nanostructured combination of these materials can lead to a dramatic enhancement of light-matter…

We apply hard X-ray photoelectron spectroscopy (HAXPES) to investigate the electronic structures in ~50-nm thick epitaxial GaP layers grown on Si(001) under different conditions. Depth profiles of the local binding energies for the core…

In this paper, we have performed first principles calculations to study optoelectronic, thermodynamic and transport properties of Fe2TiGe using density functional theory (DFT). The semi-classical Boltzmann transport theory is used to…

Materials Science · Physics 2019-05-07 M. Anwar Hossain , M. A. Al Noman , Md. Taslimur Rahman

Using the ab initio pseudopotential density functional method, we investigate the functionalization of halogen molecules into graphene-based nanostructures with zigzag and armchair edges. We find that halogen molecules adsorb through…

Materials Science · Physics 2015-05-19 Hoonkyung Lee , Marvin L. Cohen , Steven G. Louie

Molecular dynamics (MD) simulations have been performed to investigate the mechanical properties of hydrogen functionalized graphene allotropes (GAs) for H-coverage spanning the entire range (0-100%). Four allotropes (graphyne, cyclic…

Materials Science · Physics 2013-08-23 Yinfeng Li , Dibakar Datta , Zhonghua Li , Vivek B. Shenoy

We present first-principles calculations of many-electron effects on the optical response of graphene, bilayer graphene, and graphite employing the GW-Bethe Salpeter equation approach. We find that resonant excitons are formed in these…

Materials Science · Physics 2009-10-31 Li Yang , Jack Deslippe , Cheol-Hwan Park , Marvin L. Cohen , Steven G. Louie

We have developed a method for depositing graphene monolayers and bilayers with minimum lateral dimensions of 2-10 nm by the mechanical exfoliation of graphite onto the Si(100)-2x1:H surface. Room temperature, ultra-high vacuum (UHV)…

Materials Science · Physics 2009-11-13 Kyle A. Ritter , Joseph W. Lyding

We investigate the optical properties of edge-functionalized graphene nanosystems, focusing on the formation of junctions and charge transfer excitons. We consider a class of graphene structures which combine the main electronic features of…

Materials Science · Physics 2011-05-18 Caterina Cocchi , Deborah Prezzi , Alice Ruini , Marilia J. Caldas , Elisa Molinari

We employ the two-band density-matrix equations and time-dependent density functional theory to calculate high-order harmonic generation (HOHG) in graphene under a femtosecond laser irradiation. Our investigation uncovers a striking…

Atomic Physics · Physics 2023-07-25 Fulong Dong , Qinzhi Xia , Jie Liu

We present exemplary results of extensive studies of mechanical, electronic and transport properties of covalent functionalization of graphene monolayers (GML) with -NH2. We report new results of ab initio studies of covalent…

Materials Science · Physics 2014-01-24 Karolina Z. Milowska , Jacek A. Majewski

Heat is a familiar form of energy transported from a hot side to a colder side of an object, but not a notion associated with microscopic measurements of electronic properties. A temperature difference within a material causes charge…

Undoped graphene is semi-metallic and thus not suitable for many electronic and optoelectronic applications requiring gapped semiconductor materials. However, a periodic array of holes (antidot lattice) renders graphene semiconducting with…

Mesoscale and Nanoscale Physics · Physics 2008-06-24 Thomas G. Pedersen , Christian Flindt , Jesper Pedersen , Antti-Pekka Jauho , Niels Asger Mortensen , Kjeld Pedersen