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Chemical processes in closed systems are poorly controllable since they always relax to equilibrium. Living systems avoid this fate and give rise to a much richer diversity of phenomena by operating under nonequilibrium conditions. Recent…

Chemical Physics · Physics 2019-09-11 Emanuele Penocchio , Riccardo Rao , Massimiliano Esposito

Unlike crystalline solids or ideal gases, transport properties remain difficult to describe from a microscopic point of view in liquids, whose dynamics result from complex energetic and entropic contributions at the atomic scale. Two…

Soft Condensed Matter · Physics 2022-08-16 Farid Rizk , Simon Gelin , Anne-Laure Biance , Laurent Joly

We investigate by Molecular Dynamics simulation a system of $N$ particles moving on the surface of a two-dimensional sphere and interacting by a Lennard-Jones potential. We detail the way to account for the changes brought by a nonzero…

Statistical Mechanics · Physics 2015-06-18 Julien-Piera Vest , Gilles Tarjus , Pascal Viot

Developing microscopic understanding of the thermal properties of liquids is challenging due to their strong dynamic disorder, which prevents characterization of the atomic degrees of freedom. There have been significant research interests…

Disordered Systems and Neural Networks · Physics 2023-07-19 Jaeyun Moon , Lucas Lindsay , Takeshi Egami

The close-to-equilibrium regularity of solutions to a class of reaction-diffusion systems is investigated. The considered systems typically arise from chemical reaction networks and satisfy a complex balanced condition. Under some…

Analysis of PDEs · Mathematics 2017-11-29 Bao Quoc Tang

Aspects of the modern dynamical systems approach to thermodynamics of stationary states out of equilibrium with attention to the original conceptions which arose at the beginnings of Statistical Mechanics

Statistical Mechanics · Physics 2019-01-28 Giovanni Gallavotti

Nonequilibrium thermodynamics has shown its applicability in a wide variety of different situations pertaining to fields such as physics, chemistry, biology, and engineering. As successful as it is, however, its current formulation…

Condensed Matter · Physics 2009-11-07 J. M. G. Vilar , J. M. Rubi

A novel type of a multiscale approach, called Relative Resolution (RelRes), can correctly retrieve the behavior of various nonpolar liquids, whilst speeding up molecular simulations by almost an order of magnitude. In this approach in a…

Statistical Mechanics · Physics 2024-03-15 Mark Chaimovich , Aviel Chaimovich

The physical behavior of glass-forming liquids presents complex features of both dynamic and thermodynamic nature. Some studies indicate the presence of thermodynamic anomalies and of crossovers in the dynamic properties, but their origin…

Statistical Mechanics · Physics 2018-06-08 Daniele Coslovich , Misaki Ozawa , Walter Kob

The design of small scale non-equilibrium steady states (NESS) is a challenging, open ended question. While similar equilibrium problems are tractable using standard thermodynamics, a generalized description for non-equilibrium systems is…

Statistical Mechanics · Physics 2021-02-10 William D. Piñeros , Tsvi Tlusty

The well-known Wall theorem states a simple and precise relation among temperature, pressure and density of a fluid at contact with a confining hard wall in thermodynamic equilibrium. In this Letter we develop an extension of the Wall…

Statistical Mechanics · Physics 2019-10-23 Ignacio Urrutia , Ivan Paganini , Claudio Pastorino

The accurate determination of transport coefficients in numerical simulations is becoming increasingly important in a wide range of applications. Here we consider the linear response in systems driven away from thermal equilibrium into a…

Statistical Mechanics · Physics 2016-08-24 Thomas Speck

Nonequilibrium dynamics and effective thermalization are studied in a resonant tunneling scenario via multilevel Landau-Zener crossings. Our realistic many-body system, composed of two energy bands, naturally allows a separation of degrees…

Quantum Gases · Physics 2014-05-19 Carlos A. Parra-Murillo , Javier Madroñero , Sandro Wimberger

We propose a computational method to simulate anomalous self-diffusion in a simple liquid. The method is based on a molecular dynamics simulation on which we impose the following two conditions: firstly, the inter-particle interaction is…

Statistical Mechanics · Physics 2010-04-07 Simon Standaert , Jan Ryckebusch , Lesley De Cruz

Recently, we introduced Relative Resolution as a hybrid formalism for fluid mixtures [1]. The essence of this approach is that it switches molecular resolution in terms or relative separation: While nearest neighbors are characterized by a…

Statistical Mechanics · Physics 2019-10-09 Aviel Chaimovich , Kurt Kremer , Christine Peter

We employ the adaptive resolution approach AdResS, in its recently developed Grand Canonical-like version (GC-AdResS) [Wang et al. Phys.Rev.X 3, 011018 (2013)], to calculate the excess chemical potential, $\mu^{ex}$, of various liquids and…

Statistical Mechanics · Physics 2014-11-11 Animesh Agarwal , Han Wang , Christof Schütte , Luigi Delle Site

The thermodynamic properties of systems with long-range interactions is still an ongoing challenge, both from the point of view of theory as well as computer simulation. In this work we study a model system, a Coulomb gas confined inside a…

Statistical Mechanics · Physics 2020-11-04 Sergio Davis , Jalaj Jain , Biswajit Bora

Recent experiments in hybrid-quantum systems facilitate the potential realization of one of the most fundamental interacting Hamiltonian-Reservoir system, namely, the single-site Bose-Hubbard model coupled to two reservoirs at different…

Quantum Physics · Physics 2017-01-02 Archak Purkayastha , Abhishek Dhar , Manas Kulkarni

We derive analytical results for the large-time relaxation of the Sherrington - Kirkpatrick model in the thermodynamic limit, starting from a random configuration. The system never achieves local equilibrium in any fixed sector of…

Condensed Matter · Physics 2009-10-22 L. F. Cugliandolo , J. Kurchan

A quasi-two-dimensional system of hard spheres strongly confined between two parallel plates is considered. The attention is focussed on the macroscopic self-diffusion process observed when the system is looked from above or from below. The…

Statistical Mechanics · Physics 2020-01-09 J. Javier Brey , M. I. García de Soria , P. Maynar