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Related papers: Active Space Pair 2-Electron Reduced Density Matri…

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We present a new hybrid multiconfigurational method based on the concept of range-separation that combines the density matrix renormalization group approach with density functional theory. This new method is designed for the simultaneous…

We present two efficient and intruder-free methods for treating dynamic correlation on top of general multi-configuration reference wave functions---including such as obtained by the density matrix renormalization group (DMRG) with large…

Chemical Physics · Physics 2016-09-13 Sandeep Sharma , Gerald Knizia , Sheng Guo , Ali Alavi

Recent advances in quantum crystallography have shown that, beyond conventional charge density refinement, a one-electron reduced density matrix (1-RDM) satisfying N-representability conditions can be reconstructed using jointly…

Quantum Physics · Physics 2024-03-04 Sizhuo Yu , Jean-Michel Gillet

In this work we explore the performance of approximations to electron correlation in reduced density-matrix functional theory (RDMFT) and of approximations to the observables calculated within this theory. Our analysis focuses on the…

Strongly Correlated Electrons · Physics 2015-02-26 Stefano Di Sabatino , Jan A. Berger , Lucia Reining , Pina Romaniello

Dynamics of strongly interacting Fermi gases, consisting of a 50-50 mixture of two different fermionic species, is investigated. For the equation of state we consider a Pad\'{e} [2/2] approximations, which gives the weak-coupling…

Other Condensed Matter · Physics 2007-05-23 Yeong E. Kim , Alexander L. Zubarev

Using the dynamical mean-field theory (DMFT) as a `booster-rocket', the functional renormalization group (fRG) can be upgraded from a weak-coupling method to a powerful computation tool for strongly interacting fermion systems. The strong…

Strongly Correlated Electrons · Physics 2019-03-13 Demetrio Vilardi , Ciro Taranto , Walter Metzner

Tensor hypercontraction is a method that allows the representation of a high-rank tensor as a product of lower-rank tensors. In this paper, we show how tensor hypercontraction can be applied to both the electron repulsion integral (ERI)…

The O(3) symmetric Anderson model is an example of a system which has a stable low energy marginal Fermi liquid fixed point for a certain choice of parameters. It is also exactly equivalent, in the large U limit, to a localized model which…

Strongly Correlated Electrons · Physics 2009-10-31 S. C. Bradley , R. Bulla , A. C. Hewson , G-M. Zhang

Calculations of the lowest valence {\pi}* as well as the 3s and higher energy 3p{\sigma} Rydberg excited states of the CO2 molecule are carried out using density functionals with variational optimization of the orbitals, an approach…

Chemical Physics · Physics 2026-04-08 Darío Barreiro-Lage , Gianluca Levi , Hannes Jonssón , Thanja Lamberts

Mutual coupling is a dominant systematic effect in dense reflector arrays, imprinting direction-dependent and frequency-dependent structure on embedded element patterns (EEPs) and currently limiting sensitivity in precision radio…

Instrumentation and Methods for Astrophysics · Physics 2026-04-14 Quentin Gueuning , Eloy de Lera Acedo , Anthony Keith Brown , Nicolas Fagnoni

The accuracy of reaction energy profiles calculated with multi-configurational electronic structure methods and corrected by multi-reference perturbation theory depends crucially on consistent active orbital spaces selected along the…

Chemical Physics · Physics 2023-04-14 Moritz Bensberg , Markus Reiher

We recently presented a constructive solution to the N-representability problem of the two-electron reduced density matrix (2-RDM)---a systematic approach to constructing complete conditions to ensure that the 2-RDM represents a realistic…

Chemical Physics · Physics 2012-07-04 David A. Mazziotti

Hubertus J. J. van Dam [Phys. Rev. A 93, 052512, 2016] claims that the one-particle reduced density matrix (1RDM) of an interacting system can be represented by means of a single-determinant wavefunction of fictitious non-interacting…

Chemical Physics · Physics 2017-10-20 Mario Piris , Katarzyna Pernal

The current study illustrates the successful synthesis of Ce$_{1.0}$Mn$_{0.9}$Co$_{0.1}$ nanoparticles, characterized through XRD, EPR, magnetization curves, and TEM/HRTEM/EDX analyses. These nanoparticles were then loaded into the carbon…

Motivated by recent experimental reports, we carry out a Fermi liquid many-body calculation of the interaction induced renormalization of the spin susceptibility and effective mass in realistic two dimensional (2D) electron systems as a…

Strongly Correlated Electrons · Physics 2007-05-23 Ying Zhang , S. Das Sarma

Within the infinite series of ring (or bubble) diagram approximation for the electronic self-energy as appropriate for the long-range Coulomb interaction, we calculate the density-dependent T=0 Fermi liquid quasiparticle effective mass…

Strongly Correlated Electrons · Physics 2007-05-23 Ying Zhang , S. Das Sarma

Reduced density matrices are central to describing observables in many-body quantum systems. In electronic structure theory, the two-particle reduced density matrix (2-RDM) suffices to determine the energy and other key properties. Recent…

The account of electron correlation and its efficient separation into dynamic and nondynamic parts plays a key role in the development of computational methods. In this paper we suggest a physically-sound matrix formulation to split…

Chemical Physics · Physics 2016-08-16 Eloy Ramos-Cordoba , Pedro Salvador , Eduard Matito

The one-particle reduced density matrix functional theory in its natural orbital functional (NOF) version is used to study strongly correlated electrons. We show the ability of the Piris NOF 7 (PNOF7) to describe non-dynamic correlation…

Strongly Correlated Electrons · Physics 2020-02-19 Ion Mitxelena , Mario Piris

The efficient and reliable treatment of both spin-orbit coupling (SOC) and electron correlation is essential for understanding f-element chemistry. We analyze two approaches to the problem, the one-step approach where both effects are…

Chemical Physics · Physics 2022-11-09 Huanchen Zhai , Garnet Kin-Lic Chan
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