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Atomistic effective Hamiltonian simulations are used to investigate electrocaloric (EC) effects in the lead-free Ba(Zr$_{0.5}$Ti$_{0.5}$)O$_{3}$ (BZT) relaxor ferroelectric. We find that the EC coefficient varies non-monotonically with the…

Materials Science · Physics 2017-07-25 Zhijun Jiang , Sergei Prokhorenko , Sergey Prosandeev , Y. Nahas , D. Wang , J. Íñiguez , E. Defay , L. Bellaiche

Solid-state cooling is an environmentally friendly and highly scalable technology that may solve most of the problems associated with current refrigerant methods. Solid-state cooling consists of applying external fields on caloric…

Materials Science · Physics 2019-06-07 Claudio Cazorla

In acceptor doped ferroelectrics and in ferroelectric films and nanocomposites, defect dipoles, strain gradients, and the electric boundary conditions at interfaces and surfaces often impose internal bias fields. In this work we delicately…

Materials Science · Physics 2018-09-05 Yang-Bin Ma , Bai-Xiang Xu , Karsten Albe , Anna Grünebohm

The electrocaloric effect (ECE) in normal and relaxor ferroelectrics is investigated in the framework of a thermodynamic approach based on the Maxwell relation and a Landau-type free energy model. The static dielectric response of relaxors…

Disordered Systems and Neural Networks · Physics 2015-05-20 R. Pirc , Z. Kutnjak , R. Blinc , Q. M. Zhang

There is growing interest in heat pumps based on materials that show thermal changes when phase transitions are driven by changes of electric, magnetic or stress field. Importantly, regeneration permits sinks and loads to be thermally…

Materials Science · Physics 2019-10-09 S. Crossley , B. Nair , R. W. Whatmore , X. Moya , N. D. Mathur

The electrocaloric effect (ECE) in BaTiO3 is simulated using two different first-principles based effective Hamiltonian molecular dynamics methods. The calculations are performed for a wide range of temperatures (30--900 K) and external…

Materials Science · Physics 2013-11-12 Takeshi Nishimatsu , Jordan A. Barr , Scott P. Beckman

A new simulation approach of field evaporation is presented. The model combines classical electrostatics with molecular dynamics (MD) simulations. Unlike previous atomic-level simulation approaches, our method does not rely on an…

Materials Science · Physics 2022-10-17 Jiayuwen Qi , Christian Oberdorfer , Emmanuelle A. Marquis , Wolfgang Windl

Electron microscopy is a powerful tool for studying the properties of materials down to their atomic structure. In many cases, the quantitative interpretation of images requires simulations based on atomistic structure models. These…

The electrocaloric effect (ECE), i.e., the reversible temperature change due to the adiabatic variation of the electric field, is of great interest due to its potential technological applications. Based on entropy arguments, we present a…

Materials Science · Physics 2023-04-28 Lucas Squillante , Isys F. Mello , A. C. Seridonio , Mariano de Souza

We discuss the theory of cooling electrons in solid-state devices via ``evaporative emission.'' Our model is based on filtering electron subbands in a quantum-wire device. When incident electrons in a higher-energy subband scatter out of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Thushari Jayasekera , Kieran Mullen , Michael A. Morrison

In this study, we report on a direct measurement method for the electrocaloric effect, the heating/cooling upon application/removal of an electric field in dielectric materials, based on a lock-in thermography technique. By use of…

Materials Science · Physics 2023-03-08 Ryo Iguchi , Daisuke Fukuda , Jun Kano , Takashi Teranishi , Ken-ichi Uchida

An atomistic effective Hamiltonian is used to investigate electrocaloric (EC) effects of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) relaxor ferroelectrics in its ergodic regime, and subject to electric fields applied along the pseudocubic [111]…

Materials Science · Physics 2018-04-03 Zhijun Jiang , Y. Nahas , S. Prokhorenko , S. Prosandeev , D. Wang , Jorge Íñiguez , L. Bellaiche

Cooling systems based on the caloric effects of ferroic materials show high potential for various cooling and heat-pumping applications due to their potentially high efficiencies and the lack of any environmentally hazardous refrigerants.…

Applied Physics · Physics 2021-08-30 Jan Kalizan , Jaka Tušek

A semiclassical approach that incorporates quantum mechanical behavior of heat capacity in direct caloric effect simulations is proposed. Application of this methodology to study electrocaloric effect in prototypical ferroelectrics ${ \rm…

Computational Physics · Physics 2017-12-27 P. Jouzdani , S. Cuozzo , S. Lisenkov , I. Ponomareva

Refrigeration systems based on compression of greenhouse gases are environmentally threatening and cannot be scaled down to on-chip dimensions. In the vicinity of a phase transition caloric materials present large thermal responses to…

Materials Science · Physics 2018-12-19 Claudio Cazorla , Jorge Iniguez

Electrocaloric (EC) materials show promise in eco-friendly solid-state refrigeration and integrable on-chip thermal management. While direct measurement of EC thin-films still remains challenging, a generic theoretical framework for…

Materials Science · Physics 2021-04-21 Yuping Shi , Limin Huang , Ai Kah Soh , George J. Weng , Shuangyi Liu , Simon A. T. Redfern

The ab-initio theory of low-field electronic transport properties such as carrier mobility in semiconductors is well-established. However, an equivalent treatment of electronic fluctuations about a non-equilibrium steady state, which are…

Materials Science · Physics 2021-04-14 Alexander Y. Choi , Peishi Cheng , Benjamin Hatanpaa , Austin J. Minnich

Electrical and electromagnetic (EM) methods can be diagnostic geophysical imaging tools for monitoring applications, such as carbon capture and storage or hydraulic fracturing. In these settings, it is common that steel-cased wells and…

Geophysics · Physics 2022-03-29 Lindsey J. Heagy , Douglas W. Oldenburg

Thermoelectric effects, measured by the Seebeck coefficients, refer to the phenomena in which a temperature difference or gradient imposed across a thermoelectric material induces an electrical potential difference or gradient, and vice…

Materials Science · Physics 2018-12-05 Yi Wang , Yong-Jie Hu , Shun-Li Shang , Bi-Cheng Zhou , Zi-Kui Liu , Long-Qing Chen

The multicaloric effect is defined as the adiabatic temperature change in multiferroic materials induced by the application of an external electric or magnetic field, and it was first proposed in 2012. The multicaloric effects in…

Materials Science · Physics 2022-01-14 Melvin M. Vopson , Yuri K. Fetisov , Ian Hepburn