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Materials that undergo reversible metal-insulator transitions are obvious candidates for new generations of devices. For such potential to be realised, the underlying microscopic mechanisms of such transitions must be fully determined. In…

We use first principles calculations to investigate the lattice properties of group-IV monochalcogenides. These include static dielectric permittivity, elastic and piezoelectric tensors. For the monolayer, it is found that the static…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Lídia C. Gomes , A. Carvalho , A. H. Castro Neto

The objective of this work is to study the effects of charge redistribution, applied layer-normal electric fields, applied strain, and layer engineering on the band alignment of Black Phosphorus (BP)/Molybdenum disulphide (MoS2)…

Materials Science · Physics 2022-12-28 Nupur Navlakha , Priyamvada Jadaun , Leonard F. Register , Sanjay K. Banerjee

The addition of electron donors to the vacant A site of defect-perovskite structure tungsten trioxide causes a series of structural and chemical phase transitions; for instance, in the well-known case of the sodium tungsten bronzes…

Materials Science · Physics 2009-11-10 Andrew D. Walkingshaw , Nicola A. Spaldin , Emilio Artacho

We simulate the electronic and transport properties of metal/two-dimensional material/metal vertical heterostructures, with a focus on graphene, hexagonal boron nitride and two phases of molybdenum diselenide. Using density functional…

Mesoscale and Nanoscale Physics · Physics 2025-02-06 Gaëlle Bigeard , Zineb Kerrami , François Triozon , Alessandro Cresti

The magnetic properties of the two-dimensional $J_{1}-J_{2}$ model with both exchanges $J_{1}$ and $J_{2}$ being antiferromagnetic and a single-ion anisotropy at nonzero temperature are investigated. As $J_{2}/J_{1}<1/2$ ($>1/2$), only the…

Strongly Correlated Electrons · Physics 2019-09-26 Huai-Yu Wang

Monolayer transition metal dichalcogenides are novel, gapped two-dimensional materials. Toward device applications, we consider MoS$_2$ layers on dielectrics, in particular in this work, the effect of vacancies on the electronic structure.…

Mesoscale and Nanoscale Physics · Physics 2016-06-10 Amithraj Valsaraj , Jiwon Chang , Amritesh Rai , Leonard F. Register , Sanjay K. Banerjee

Forcing systems though fast non-equilibrium phase transitions offers the opportunity to study new states of quantum matter that self-assemble in their wake. Here we study the quantum interference effects of correlated electrons confined in…

Atomically thin materials, like semiconducting transition metal dichalcogenides (S-TMDs), are highly sensitive to the environment. This opens up an opportunity to externally control their properties by changing their surroundings. We…

Mesoscale and Nanoscale Physics · Physics 2019-10-23 M. Grzeszczyk , M. R. Molas , K. Nogajewski , M. Bartoš , A. Bogucki , C. Faugeras , P. Kossacki , A. Babiński , M. Potemski

Two-dimensional (2D) Janus Transition Metal Dichalcogenides (TMDs) have attracted much interest due to their exciting quantum properties arising from their unique two-faced structure, broken-mirror symmetry, and consequent colossal…

Two-dimensional transition metal dichalcogenides are among the most promising materials for water-splitting catalysts. While a variety of methods have been applied to promote the hydrogen evolution reaction on the transition metal…

Materials Science · Physics 2023-06-16 Sangjin Lee , Sujin Lee , Chaewon Kim , Young-Kyu Han

How magnetism emerges in low-dimensional materials such as transition metal dichalcogenides at the monolayer limit is still an open question. Herein, we present a comprehensive study of the magnetic properties of single crystal and…

First-principle calculations with different exchange-correlation functionals, including LDA, PBE and vdW-DF functional in form of optB88-vdW, have been performed to investigate the electronic and elastic properties of two dimensional…

Materials Science · Physics 2015-08-31 Fan Zeng , Wei-Bing Zhang , Bi-Yu Tang

The change of bonding status, typically occurring only in chemical processes, could dramatically alter the material properties. Here, we show that a tunable breaking and forming of a diatomic bond can be achieved through physical means,…

Materials Science · Physics 2017-02-23 Yao Wang , Shan-Shan Wang , Yunhao Lu , Jianzhong Jiang , Shengyuan A. Yang

The emergence of ferromagnetism in two-dimensional van der Waals materials has aroused broad interest. However, the ferromagnetic instability has been a problem remained. In this work, by using the first-principles calculations, we…

Strongly Correlated Electrons · Physics 2021-03-18 Wen-ning Ren , Kui-juan Jin , Jie-su Wang , Chen Ge , Er-Jia Guo , Cheng Ma , Can Wang , Xiulai Xu

It is essential to explore two-dimensional (2D) material with magnetic ordering in new generation spintronic devices. Particularly, the seeking of room-temperature 2D ferromagnetic (FM) materials is a hot topic of current research. Here, we…

Mesoscale and Nanoscale Physics · Physics 2018-09-07 Chang-Wei Wu , Jun-Han Huang , Dao-Xin Yao

By using the density functional theory method, we systematically study the influences of the doping of an Al atom on the electronic structures of the Mg(0001) surface and dissociation behaviors of H2 molecules. We find that for the Al-doped…

Chemical Physics · Physics 2015-05-14 Yanfang Li , Yu Yang , Yinghui Wei , Ping Zhang

Using first-principles density functional theory calculations, we investigate the geometries, electronic structures, and thermodynamic stabilities of substitutionally doped phosphorene sheets with group III, IV, V, and VI elements. We find…

Computational Physics · Physics 2016-03-17 Weiyang Yu , Zhili Zhu , Chun-Yao Niu , Chong Li , Jun-Hyung Cho , Yu Jia

The optical response of traditional semiconductors depends on the laser excitation power used in experiments. For two-dimensional (2D) semiconductors, laser excitation effects are anticipated to be vastly different due to complexity added…

Elucidating the polymorphism of transition metal dichalcogenide layers and the interplay between structure and properties is a key challenge for the application of these materials. We identify a novel low energy metastable phase of…

Strongly Correlated Electrons · Physics 2021-09-22 Bing-Hua Lei , David J. Singh
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