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Light and heat drive interfacial chemistry at solid-liquid interfaces, underpinning processes central to sustainable energy conversion, including photoelectrochemical and hydrovoltaic systems. Yet, non-invasive probing of light-induced…

Chemical Physics · Physics 2026-05-04 Tarique Anwar , Diana DallAglio , Milad Sabzehparvar , Giulia Tagliabue

The interface between two different semiconductors is crucial in determining the electronic properties at the heterojunction, therefore novel techniques that can probe these regions are of particular interest. Recently it has been shown…

Mesoscale and Nanoscale Physics · Physics 2021-09-01 Frederico B. Sousa , Lucas Lafeta , Alisson R. Cadore , Prasana K. Sahoo , Leandro M. Malard

An optical Second-Harmonic Generation (SHG) allows to probe various structural and symmetry-related properties of materials, since it is sensitive to the inversion symmetry breaking in the system. Here, we investigate the SHG response from…

Mesoscale and Nanoscale Physics · Physics 2019-05-08 M. Vandelli , M. I. Katsnelson , E. A. Stepanov

Metal-organic interfaces determine critical processes in organic electronic devices. The frontier molecular orbitals (highest occupied and lowest unoccupied molecular orbital, HOMO and LUMO) are crucial in determining charge-injection and…

Materials Science · Physics 2025-04-09 Anubhab Chakraborty , Oliver L. A. Monti

Soft-X-ray ARPES (SX-ARPES) with its enhanced probing depth and chemical specificity allows access to fundamental electronic structure characteristics - momentum-resolved spectral function, band structure, Fermi surface - of systems…

Mesoscale and Nanoscale Physics · Physics 2018-02-06 Vladimir N. Strocov , Claudia Cancellieri , Andrey S. Mishchenko

Charge transfer in oxide heterostructures can be tuned to promote emergent interfacial states, and accordingly, has been the subject of intense study in recent years. However, accessing the physics at these interfaces, which are often…

Strongly Correlated Electrons · Physics 2018-09-12 R. F. Need , P. B. Marshall , E. Weschke , A. J. Grutter , D. A. Gilbert , E. Arenholz , P. Shafer , S. Stemmer , S. D. Wilson

We show that the nonlinear optical response reflects sensitively the electronic structure of transition-metal surfaces and interfaces. $d$ and $s$ electrons may contribute rather differently to the second harmonic generation (SHG) signal.…

Condensed Matter · Physics 2007-05-23 W. H"ubner , K. H. Bennemann , K. Böhmer

It is of fundamental importance but challenging to simultaneously identify atomic and magnetic configurations of two-dimensional van der Waals materials. In this work, we show that the nonreciprocal second-harmonic generation (SHG) can be a…

Materials Science · Physics 2020-07-15 Wenshen Song , Ruixiang Fei , Li Yang

Emergent phenomena at complex-oxide interfaces have become a vibrant field of study in the past two decades due to the rich physics and a wide range of possibilities for creating new states of matter and novel functionalities for potential…

Materials Science · Physics 2024-06-19 C. -T. Kuo , G. Conti , J. E. Rault , C. M. Schneider , S. Nemšák , A. X. Gray

Transition metal (TM) oxide heterostructure superlattices have attracted great attention in research communities because of their emergent interfacial phenomena that do not exist in the bulk form. In order to understand the mechanisms that…

Materials Science · Physics 2024-06-19 Cheng-Tai Kuo , Shih-Chieh Lin , Yi-De Chuang

Built-in electric fields across heterojunctions between semiconducting materials underpin the functionality of modern device technologies. Heterojunctions between semiconductors and epitaxially grown crystalline oxides provide a rich…

The efficient optical second-harmonic generation (SHG) of two-dimensional (2D) crystals, coupled with their atomic thickness that circumvents the phase-match problem, has garnered considerable attention. While various 2D heterostructures…

Materials Science · Physics 2023-10-31 Wontaek Kim , Gyouil Jeong , Juseung Oh , Jihun Kim , Kenji Watanabe , Takashi Taniguchi , Sunmin Ryu

Since the first observation of second harmonic generation (SHG), there have been extensive studies on this nonlinear phenomenon not only to clarify its physical origin but also to realize unconventional functionalities. Nonetheless, a…

Metal-organic molecular adsorbates on metallic surfaces offer the potential to both generate materials for future (spin-)electronics applications as well as a better fundamental understanding of molecule-substrate interaction, provided that…

Materials Science · Physics 2024-09-17 A. Eschenlohr , R. Shi , J. Chen , P. Zhou , U. Bovensiepen , W. Hübner , G. Lefkidis

Interface interactions in 2D vertically stacked heterostructures play an important role in optoe-lectronic applications, photodetectors based on graphene/InSe heterostructures had shown promising performance nowadays. However, nonlinear…

Optics · Physics 2023-05-12 Jialin Li , Lizhen Wang , Yuzhong Chen , Yujie Li , Haiming Zhu , Linjun Li , Limin Tong1

Key technologies in energy conversion and storage, sensing and chemical synthesis rely on a detailed knowledge about charge transfer processes at electrified solid-liquid interfaces. However, these interfaces continuously evolve as a…

Materials Science · Physics 2022-12-12 Reshma R. Rao , Iris C. G. van den Bosch , Christoph Baeumer

The interfacial structure plays a critical role in modern optoelectronics. Currently multilayer electrodes are used to optimize the injection and lifetime properties. The choice of interlayer is not universal, with different effects for the…

Materials Science · Physics 2012-08-02 Ayse Turak , Dan Grozea , Chanjun Huang , Zheng-Hong Lu

Second-order nonlinear spectroscopy has proven to be a powerful tool in elucidating key chemical and structural characteristics at a variety of interfaces. However, the presence of interfacial potentials may lead to complications regarding…

Materials Science · Physics 2017-10-19 Paul E. Ohno , Hong-fei Wang , Franz M. Geiger

Vertical integration of two-dimensional materials has recently emerged as an exciting method for the design of novel electronic and optoelectronic devices. Using density functional theory, we investigatethe structural and electronic…

Materials Science · Physics 2015-06-25 Yongqing Cai , Gang Zhang , Yong-Wei Zhang

The interfacial structure of SrZr$_{x}$Ti$_{1-x}$O$_3$ films grown on semiconducting Ge substrates are investigated by synchrotron X-ray diffraction and first-principles density functional theory. By systematically tuning Zr content x, the…

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