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In this work, we report on the electrochemical behavior of nitrided spaced TiO$_2$ nanotubes conformally coated with a nanocrystalline Nb$_2$O$_5$ layer and find for these hierarchical structures an excellent supercapacitor performance.…

Applied Physics · Physics 2020-05-05 Selda Ozkan , Nhat Truong Nguyen , Imgon Hwang , Anca Mazare , Patrik Schmuki

In the present work we grow self-organized TiO2 nanotube arrays with a defined and controlled regular spacing between individual nanotubes. These defined intertube gaps allow to build up hierarchical 1D-branched structures, conformally…

Materials Science · Physics 2016-10-27 Nhat Truong Nguyen , Selda Ozkan , Imgon Hwang , Anca Mazare , Patrik Schmuki

In this work we describe the synthesis and electrochemical properties of nitridated hierarchical TiO$_2$ nanotubes as an electrode for supercapacitors. The hierarchical TiO$_2$ nanostructures are formed by a controlled layer-by-layer TiO2…

Chemical Physics · Physics 2020-04-28 Nhat Truong Nguyen , Selda Ozkan , Imgon Hwang , Xuemei Zhou , Patrik Schmuki

We report on how to grow and control self-organized TiO2 nanotube arrays that show defined and regular gaps between individual nanotubes. For this we use electrochemical anodization of titanium in fluoride containing di-ethylene glycol…

Materials Science · Physics 2016-10-14 Selda Ozkan , Nhat Truong Nguyen , Anca Mazare , Patrik Schmuki

In the present work we grow anodic TiO$_2$ nanotube layer with tube diameter ~ 500 nm and an open tube mouth. We use this morphology in dye-sensitized solar cells (DSSCs) and show that these tubes allow the construction of hybrid…

Applied Physics · Physics 2020-05-05 Abdelhamid Elzarka , Ning Liu , Imgon Hwang , Mustafa Kamal , Patrik Schmuki

Au nanoparticles at the TiO$_2$ surface can enhance the photocatalytic H$_2$ generation performances owing to their electron transfer co-catalytic ability. Key to maximize the co-catalytic effect is a fine control over Au nanoparticle size…

Applied Physics · Physics 2020-06-05 Seyedsina Hejazi , Marco Altomare , Shiva Mohajernia , Patrik Schmuki

In this work, we design a TiO2 nanomembrane (TiNM) that can be used as a nanofilter platform for a selective enrichment of specific proteins. After use the photocatalytic properties of TiO2 allow to decompose unwanted remnant on the…

Materials Science · Physics 2016-10-21 Jingwen Xu , Lingling Yang , Yuyao Han , Yongmei Wang , Xuemei Zhou , Zhida Gao , Yan-Yan Song , Patrik Schmuki

Low-dose nitrogen implantation induces in TiO2 nanotubes a co-catalytic activity for photocatalytic H2-evolution. The use of an ion implantation process leads to a N-implanted zone only at the top part of the tubes. The coupling of this top…

In the present work we compare TiO2 nanotube lift-off strategies for the construction of front-side illuminated dye-sensitized solar cells (DSSCs). Anodic nanotube layers were detached from the metallic back contact by using different…

Due to their characteristic geometry, TiO$_2$ nanotubes (TNTs), suitably doped by metal-substitution to enhance their photocatalytic properties, have a high potential for applications such as clean fuel production. In this context, we…

Materials Science · Physics 2020-09-17 Mohamed M. Fadlallah , Ulrich Eckern

Au and Pt do not form homogeneous bulk alloys as they are thermodynamically not miscible. However, we show that anodic TiO$_2$ nanotubes (NTs) can in-situ be uniformly decorated with homogeneous AuPt alloy nanoparticles (NPs) during their…

In the present work we investigate the photocatalytic hydrogen production (water splitting) activity of different Pt loaded TiO2 nanotube layers. Therefore, we fabricate free standing membranes and fix them in four different configurations:…

Materials Science · Physics 2016-10-14 Gihoon Cha , Kiyoung Lee , JeongEun Yoo , Manuela S. Killian , Patrik Schmuki

Self-standing TiO$_2$ nanotube layers in the form of membranes are fabricated by self-organizing anodization of Ti metal and a potential shock technique. The membranes were then decorated by sputtering different Pt amounts i) only at the…

Applied Physics · Physics 2020-06-02 Gihoon Cha , Marco Altomare , Nhat Truong Nguyen , Nicola Taccardi , Kiyoung Lee , Patrik Schmuki

Current supercapacitors present several distinct limitations that severely inhibit the efficiency, power, and electrical capacitance of energy storage devices. Supercapacitors present an exciting prospect that has countless applications in…

Materials Science · Physics 2016-06-03 Sydney Marler

In the present work, extended Argon ion bombardment was used to modify anatase TiO2 nanotube (NTs) layers. In situ X-ray photoelectron spectroscopy revealed a high content of sub-oxide formed (Ti3+, Ti2+ states) in the nanotube layers.…

Materials Science · Physics 2016-10-14 Xuemei Zhou , Ning Liu , Patrik Schmuki

Photocatalytic $H_2$ evolution reactions on pristine TiO$_2$ is characterized by low efficiencies due to trapping and recombination of charge carriers, and due to a sluggish kinetics of electron transfer. Noble metal (mainly Pt, Pd, Au)…

The present work reports on the enhancement of TiO2 nanotubes photoelectrochemical water splitting rate by decorating the nanostructure with an amine layer in a hydrothermal process using diethylenetriamine (DETA). The aminate coated TiO2…

Materials Science · Physics 2016-10-14 Seyedsina Hejazi , Nhat Truong Nguyen , Anca Mazare , Patrik Schmuki

We address one of the main challenges to TiO2-photocatalysis, namely band gap narrowing, by combining nanostructural changes with doping. With this aim we compare TiO2's electronic properties for small 0D clusters, 1D nanorods and…

Materials Science · Physics 2010-01-18 D. J. Mowbray , J. I. Martinez , J. M. García-Lastra , K. S. Thygesen , K. W. Jacobsen

We report the exfoliation of layered Na2Ti3O7, a promising anode material for Na-ion batteries, and restacking using HNO3 and NaOH to form H-Ti3O7 and Na(x)-Ti3O7 compositions, respectively. The materials were characterised by a range of…

In the present work we report significant enhancement of the photoelectrochemical properties of self-organized TiO2 nanotubes by a combined de-coring of classic nanotubes followed by an appropiate TiCl4-treatment. We show that, except for…

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