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For many real physico-chemical complex systems detailed mechanism includes both reversible and irreversible reactions. Such systems are typical in homogeneous combustion and heterogeneous catalytic oxidation. Most complex enzyme reactions…

Statistical Mechanics · Physics 2013-01-17 A. N. Gorban , E. M. Mirkes , G. S. Yablonsky

We set up a rigorous thermodynamic description of reaction-diffusion systems driven out of equilibrium by time-dependent space-distributed chemostats. Building on the assumption of local equilibrium, nonequilibrium thermodynamic potentials…

Statistical Mechanics · Physics 2018-09-12 Gianmaria Falasco , Riccardo Rao , Massimiliano Esposito

Using infinite compositions, we solve the general equations $P(\lambda w) = p(w)f(P(w))$ for holomorphic functions $p$ and $f$. We describe the situations in which this equation is palpable; and their effectiveness at describing dynamical…

Complex Variables · Mathematics 2021-09-01 James David Nixon

We show that the typical dynamical system sometimes begins to behave like a non-deterministic system with a small classical entropy, and this behavior lasts an extremely long time, until the system starts decreasing entropy. Then again it…

Dynamical Systems · Mathematics 2020-07-28 V. V. Ryzhikov

The long standing contrast between Boltzmann's and Gibbs' approach to statistical thermodynamics has been recently rekindled by Dunkel and Hilbert [1], who criticize the notion of negative absolute temperature (NAT), as a misleading…

Statistical Mechanics · Physics 2015-08-31 Loris Ferrari

Dynamical systems generated by scalar reaction-diffusion equations on an interval enjoy special properties that lead to a very simple structure for the semiflow. Among these properties, the monotone behavior of the number of zeros of the…

Dynamical Systems · Mathematics 2023-12-29 Giorgio Fusco , Carlos Rocha

We present an exact treatment of the thermodynamics of physical systems in the framework of the generalized uncertainty principle (GUP). Our purpose is to study and compare the consequences of two GUPs that one implies a minimal length…

High Energy Physics - Theory · Physics 2016-03-11 M. Abbasiyan-Motlaq , P. Pedram

This paper presents new sufficient conditions for convergence and asymptotic or exponential stability of a stochastic discrete-time system, under which the constructed Lyapunov function always decreases in expectation along the system's…

Systems and Control · Computer Science 2019-06-05 Yuzhen Qin , Ming Cao , Brian D. O. Anderson

In 1892, Lyapunov provided a fundamental contribution to stability theory by introducing so-called Lyapunov functions and Lyapunov equilibria. He subsequently showed that, for linear systems, the two concepts are equivalent. These concepts…

Dynamical Systems · Mathematics 2023-06-02 Sébastien Maurice Mattenet , Raphael Jungers

Fluctuation theorems have a very special place in the study of non equilibrium dynamics of physical systems. The form in which it is used most extensively is the Gallavoti-Cohen Fluctuation Theorem which is in terms of the distribution of…

Classical Physics · Physics 2015-12-01 G. S. Agarwal , Sushanta Dattagupta

For more than 100 years, one of the central concepts in statistical mechanics has been the microcanonical ensemble, which provides a way of calculating the thermodynamic entropy for a specified energy. A controversy has recently emerged…

Statistical Mechanics · Physics 2016-07-04 Michael Matty , Lachlan Lancaster , William Griffin , Robert H. Swendsen

This paper introduces a biparametric family of Lyapunov functions for a non-linear mathematical model based on the FitzHugh-Nagumo equations able to reproduce some main features of the X-ray bursting behaviour exhibited by the microquasar…

High Energy Astrophysical Phenomena · Physics 2017-05-11 A. Ardito , P. Ricciardi , E. Massaro , T. Mineo , F. Massa

Using the recently developed ``Maximum Entropy'' (or ``least biased'') distribution function to truncate the moment hierarchy arising from kinetic theory, we formulate a far-from-equilibrium macroscopic theory that provides the possibility…

High Energy Physics - Phenomenology · Physics 2023-08-03 Chandrodoy Chattopadhyay , Ulrich Heinz , Thomas Schaefer

The stability of the equilibrium state is one of the crucial tests a hydrodynamic theory needs to pass. A widespread technique to study this property consists of searching for a Lyapunov function of the linearised theory, in the form of a…

General Relativity and Quantum Cosmology · Physics 2021-09-30 Lorenzo Gavassino

We consider a thermodynamically correct framework for electro-energy-reaction-diffusion systems, which feature a monotone entropy functional while conserving the total charge and the total energy. For these systems, we construct a relative…

Analysis of PDEs · Mathematics 2025-08-08 Michael Kniely

Every irreducible discrete-time linear switching system possesses an invariant convex Lyapunov function (Barabanov norm), which provides a very refined analysis of trajectories. Until recently that notion remained rather theoretical apart…

Optimization and Control · Mathematics 2021-09-28 Vladimir Yu. Protasov

By decoupling forward and backward stochastic trajectories, we construct a family of martingales and work theorems for both overdamped and underdamped Langevin dynamics. Our results are made possible by an alternative derivation of work…

Statistical Mechanics · Physics 2025-04-17 Xiangting Li , Tom Chou

For general asymptotically sub-additive potentials (resp. asymptotically additive potentials) on general topological dynamical systems, we establish some variational relations between the topological entropy of the level sets of Lyapunov…

Dynamical Systems · Mathematics 2015-05-13 De-Jun Feng , Wen Hunag

Computer assisted procedures of Lyapunov functions defined in given neighborhoods of fixed points for flows and maps are discussed. We provide a systematic methodology for constructing explicit ranges where quadratic Lyapunov functions…

Numerical Analysis · Mathematics 2016-04-21 Kaname Matsue , Tomohiro Hiwaki , Nobito Yamamoto

A Path-Complete Lyapunov Function is an algebraic criterion composed of a finite number of functions, called its pieces, and a directed, labeled graph defining Lyapunov inequalities between these pieces. It provides a stability certificate…

Dynamical Systems · Mathematics 2016-12-14 David Angeli , Matthew Philippe , Nikolaos Athanasopoulos , Raphaël M. Jungers
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