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In 1961, R\'enyi discovered a rich family of non-classical Lyapunov functions for kinetics of the Markov chains, or, what is the same, for the linear kinetic equations. This family was parameterised by convex functions on the positive…

Chemical Physics · Physics 2019-07-24 A. N. Gorban

We present a framework to transform the problem of finding a Lyapunov function of a Chemical Reaction Network (CRN) in concentration coordinates with arbitrary monotone kinetics into finding a common Lyapunov function for a linear parameter…

Optimization and Control · Mathematics 2017-10-31 M. Ali Al-Radhawi , David Angeli

Generalized entropies are studied as Lyapunov functions for the Master equation (Markov chains). Three basic properties of these Lyapunov functions are taken into consideration: universality (independence of the kinetic coefficients),…

Statistical Mechanics · Physics 2007-05-23 Pavel Gorban

Complex systems that are characterized by strong correlations and fat-tailed distribution functions have been argued to be incompatible within the framework of Boltzmann-Gibbs entropy. As an alternative, so-called generalized entropies were…

Statistical Mechanics · Physics 2022-08-15 Rudolf Hanel , Stefan Thurner

We consider the relationship between stationary distributions for stochastic models of reaction systems and Lyapunov functions for their deterministic counterparts. Specifically, we derive the well known Lyapunov function of reaction…

Probability · Mathematics 2015-06-11 David F. Anderson , Gheorghe Craciun , Manoj Gopalkrishnan , Carsten Wiuf

We develop the framework of classical Observational entropy, which is a mathematically rigorous and precise framework for non-equilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen…

Statistical Mechanics · Physics 2020-09-09 Dominik Šafránek , Anthony Aguirre , J. M. Deutsch

Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…

Statistical Mechanics · Physics 2009-11-13 Stefan Thurner , Rudolf Hanel

We discuss the dynamics and thermodynamics of systems with weak long-range interactions. Generically, these systems experience a violent collisionless relaxation in the Vlasov regime leading to a (usually) non-Boltzmannian quasi stationary…

Statistical Mechanics · Physics 2009-11-13 Pierre-Henri Chavanis

Piecewise-Linear in Rates (PWLR) Lyapunov functions are introduced for a class of Chemical Reaction Networks (CRNs). In addition to their simple structure, these functions are robust with respect to arbitrary monotone reaction rates, of…

Optimization and Control · Mathematics 2016-09-09 M. Ali Al-Radhawi , David Angeli

Quadratic Lyapunov functions are prevalent in stability analysis of linear consensus systems. In this paper we show that weighted sums of convex functions of the different coordinates are Lyapunov functions for irreducible consensus…

Optimization and Control · Mathematics 2015-01-08 Herbert Mangesius , Jean-Charles Delvenne

A class of chemical reaction networks is described with the property that each positive equilibrium is locally asymptotically stable relative to its stoichiometry class, an invariant subspace on which it lies. The reaction systems treated…

Dynamical Systems · Mathematics 2013-04-11 Pete Donnell , Murad Banaji

The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…

Statistical Mechanics · Physics 2020-07-01 Sheldon Goldstein , Joel L. Lebowitz , Roderich Tumulka , Nino Zanghi

In an earlier paper, we proved the validity of large deviations theory for the particle approximation of quite general chemical reaction networks (CRNs). In this paper, we extend its scope and present a more geometric insight into the…

Dynamical Systems · Mathematics 2018-08-01 Andrea Agazzi , Amir Dembo , Jean-Pierre Eckmann

Starting with the additivity condition for Lyapunov functions of master equation, we derive a one-parametric family of entropy functions which may be appropriate for a description of certain effects of finiteness of statistical systems, in…

Statistical Mechanics · Physics 2009-11-07 Alexander N. Gorban , Iliya V. Karlin

This paper is concerned with the problem of finding a quadratic common Lyapunov function for a family of stable linear systems. We present gradient iteration algorithms which give deterministic convergence for finite system families and…

Optimization and Control · Mathematics 2007-05-23 Daniel Liberzon , Roberto Tempo

We investigate a broad family of chemical reaction networks (CRNs) assigned with mass action kinetics, called complex-balanced-produced-CRNs (CBP-CRNs), which are generated by any given complex balanced mass action system (MAS) and whose…

Dynamical Systems · Mathematics 2019-11-12 Shan Wu , Yafei Lu , Chuanhou Gao

G\'acs' coarse-grained algorithmic entropy leverages universal computation to quantify the information content of any given physical state. Unlike the Boltzmann and Gibbs-Shannon entropies, it requires no prior commitment to macrovariables…

Statistical Mechanics · Physics 2024-12-03 Aram Ebtekar , Marcus Hutter

The notion of entropy is ubiquitous both in natural and social sciences. In the last two decades, a considerable effort has been devoted to the study of new entropic forms, which generalize the standard Boltzmann-Gibbs (BG) entropy and are…

Mathematical Physics · Physics 2015-10-15 Piergiulio Tempesta

There exists only one generalization of the classical Boltzmann-Gibbs-Shannon entropy functional to a one-parametric family of additive entropy functionals. We find analytical solution to the corresponding extension of the classical…

Statistical Mechanics · Physics 2009-11-07 Alexander N. Gorban , Iliya V. Karlin , Hans Christian Ottinger

This paper studies the relationship between the Lyapunov function of a macrosystem whose dynamics is governed by the laws of stochastic chemical kinetics and the invariant measure of this macrosystem arising at large times. A necessary and…

Probability · Mathematics 2018-05-29 Alexander Gasnikov , Evgenia Gasnikova
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