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We present a first--principles density functional theory (DFT) study of transition metal (TM = Ti, Cr, Mn, Fe, Co, Ni) functionalized two--dimensional polyaramid (2DPA) to explore their structural, electronic, and magnetic properties.…

Materials Science · Physics 2025-11-03 Ravi Trivedi , Chaithanya Purushottam Bhat , Shakti S. Ray , Debashis Bandyopadhyay

As titanium is a highly utilized metal for structural light-weighting, its phases, transformation pathways (transition states), and structures have scientific and industrial importance. Impurities, pressure, and temperature control the…

Materials Science · Physics 2017-11-28 N. A. Zarkevich , D. D. Johnson

We carried out a comprehensive crystal structure characterization of Ti-doped lithium ruthenate (Li$_2$Ti$_x$Ru$_{1-x}$O$_3$), to investigate the effect of Ti-doping on the structural phase transition. Experimental tools sensitive to the…

By means of first-principles density-functional theory (DFT) calculations, we perform a comparative analysis of the electronic and magnetic properties of transition metal-doped TiO$_2$. The electronic band gaps of Ti$_x$M$_{1-x}$O$_2$,…

Materials Science · Physics 2026-01-26 Vikash Mishra , Shashi Pandey , Swaroop Ganguly , Alok Shukla

A density functional theory study of atomic defects and dopants in ternary Z-phase transition-metal nitrides CrMN with M=V, Nb, or Ta is presented. Various defect formation energies of native point defects and of substitutional atoms of…

Materials Science · Physics 2017-10-09 Daniel F. Urban , Christian Elsässer

We present a density-functional theory (DFT) study of the structural, electronic, and chemical bonding behaviour in germanium (Ge)-doped vanadium dioxide (VO$_2$). Our motivation is to explain the reported increase of the metal-insulator…

Materials Science · Physics 2023-02-03 Peter Mlkvik , Claude Ederer , Nicola A. Spaldin

Titanium-based oxides are abundant, chemically stable, non-toxic, and highly versatile materials, with applications ranging from photovoltaics to catalysis. For rutile and anatase phases of Titanium dioxide (TiO2), the bandgap ranges from…

Materials Science · Physics 2022-01-04 Lynet Allan , George O Amolo , Julius Mwabora , Silas Mureramanzi

We perform density functional theory calculation to investigate the structural and electronic properties of various two-dimensional transition metal dichalcogenides, MX$_2$ (M$=$Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, or W, and X$=$S or Se), and…

Materials Science · Physics 2019-05-21 Seoung-Hun Kang , Young-Kyun Kwon

Successful doping of single-layer transition metal dichalcogenides (TMDs) remains a formidable barrier to their incorporation into a range of technologies. We use density functional theory to study doping of molybdenum and tungsten…

Materials Science · Physics 2017-11-22 Nicolas Onofrio , David Guzman , Alejandro Strachan

Magnetization, susceptibility, specific heat, resistivity, neutron and x-ray diffraction have been used to characterize the properties of single crystalline CaFe2-xNixAs2 as a function of Ni doping for x varying from 0 to 0.1. The combined…

The elastic properties of the $B_1$-structured transition-metal nitrides and their carbide counterparts are studied using the {\it ab initio\} density functional perturbation theory. The linear response results of elastic constants are in…

Materials Science · Physics 2009-11-10 Zhigang Wu , Xiao-Jia Chen , Viktor V. Struzhkin , Ronald E. Cohen

With the intention to reveal the effect of the substitution, Ti-doped InSb alloy, we accomplished a first-principles prediction within the FPLAPW+lo method. We used GGA-PBEsol scheme attached with the improved TB-mBJ approach to predict…

Materials Science · Physics 2021-12-21 S. Amrani , M. Berber , M. Mebrek

In strongly correlated transition metal dichalcogenides, an intricate interplay of polaronic distortions, stacking arrangement, and electronic correlations determines the nature of the insulating state. Here, we study the response of the…

We propose a new method for accurately calculating electrical transport properties of a lightly-doped thermoelectric material from density functional theory (DFT) calculations, based on experimental data and density functional theory…

Materials Science · Physics 2014-01-14 Alireza Faghaninia , Cynthia S. Lo

Amorphous metal oxide thin-film transistors (TFT) are fabricated using InOx-based semiconductors doped with TiO2, WO3 or SiO2. Although density of dopant is low in the film, change in the electrical properties showed strong dependence on…

Materials Science · Physics 2013-10-25 Shinya Aikawa , Toshihide Nabatame , Kazuhito Tsukagoshi

Transformations in bcc-$\beta$, hcp-$\alpha$, and the $\omega$ phases of Ti alloys are studied using Density Functional Theory for pure Ti and Ti alloyed with Al, Si, V, Cr, Fe, Cu, Nb, Mo, and Sn. The $\beta$-stabilization caused by…

Materials Science · Physics 2025-08-12 David Holec , Johann Grillitsch , Jose L. Neves , David Obersteiner , Thomas Klein

Metastable alloys, such as $\beta$-phase titanium (Ti) alloys with a body-centered cubic (BCC) lattice, can exhibit exceptional mechanical properties through the interplay of multiple deformation mechanisms -- diffusionless phase…

Materials Science · Physics 2025-10-16 Ganlin Chen , Deepak V Pillai , Yufeng Zheng , Liang Qi

We present a comprehensive first-principles study of the structural and elastic properties of 2H-MX$_2$ transition metal dichalcogenides (TMDs) (M = W, Mo, Ta, Nb; X = S, Se). Using density functional theory with various van der Waals…

Materials Science · Physics 2025-05-12 S. Azadi , A. Azhar , R. V. Belosludov , T. D. Kühne , M. S. Bahramy

We use combine high resolution neutron diffraction (HRPD) with density functional theory (DFT) to investigate the exchange striction at the Curie temperature (TC) of Fe2P and to examine the effect of boron and carbon doping on the P site.…

Materials Science · Physics 2013-07-26 Z. Gercsi , E. K. Delczeg-Czirjak , L. Vitos , A. S. Wills , A. Daoud-Aladine , K. G. Sandeman

Scanning tunneling spectroscopy measurements on the high temperature superconductor Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$ have reported an enhanced spectral gap in the neighborhood of O dopant atoms. We calculate, within density functional…

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