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Lamellar structures of transition metal phosphorus trisulfides possess strong intralayer bonding, albeit adjacent layers are held by weak van der Waals interactions. Those compounds received enormous interest due to their unique combination…

At the few-atom-thick limit, transition metal dichalcogenides (TMDs) exhibit a host of attractive electronic optical, and structural properties. The possibility to pattern these properties has a great impact on applied and fundamental…

We present measurements of the optical spectra on single crystals of spinel-type compound \cis. This material undergoes a sharp metal-insulator transition at 230 K. Upon entering the insulating state, the optical conductivity shows an…

Strongly Correlated Electrons · Physics 2009-11-10 N. L. Wang , G. H. Cao , P. Zheng , G. Li , Z. Fang , T. Xiang , H. Kitazawa , T. Matsumoto

We investigate exemplary the longitudinal optical (LO) mode order in compounds with a plasmon or plasmon-like phonon mode and additional phonon modes. When the oscillator strength of the plasmon or plasmon-like mode is gradually increased,…

Materials Science · Physics 2020-06-24 Thomas G. Mayerhöfer , Jürgen Popp

The integration of transition metal dichalcogenides (TMDs) with ferroelectric substrates is a powerful strategy to modulate their electronic and optical properties. However, the use of relaxor ferroelectrics for this purpose remains…

Materials Science · Physics 2025-05-06 D. Hernández-Pinilla , D. Cachago , Y. A. Xia , G. López-Polín , M. O Ramírez , L. E. Bausá

By analyzing the temperature ($T$) and density ($n$) dependence of the measured conductivity ($\sigma$) of 2D electrons in the low density ($\sim10^{11}$cm$^{-2}$) and temperature (0.02 - 10 K) regime of high-mobility (1.0 and 1.5 $\times…

Mesoscale and Nanoscale Physics · Physics 2009-07-21 L. A. Tracy , E. H. Hwang , K. Eng , G. A. Ten Eyck , E. P. Nordberg , K. Childs , M. S. Carroll , M. P. Lilly , S. Das Sarma

Two-dimensional materials (2DM) have attracted much interest due to their distinct optical, electronic, and catalytic properties. These properties can be by tuned a range of methods including substitutional doping or, as recently…

We present in-depth measurements of the electronic band structure of the transition-metal dichalcogenides (TMDs) MoS2 and WS2 using angle-resolved photoemission spectroscopy, with focus on the energy splittings in their valence bands at the…

In monolayer MoS2 optical transitions across the direct bandgap are governed by chiral selection rules, allowing optical valley initialization. In time resolved photoluminescence (PL) experiments we find that both the polarization and…

Mesoscale and Nanoscale Physics · Physics 2014-02-04 D. Lagarde , L. Bouet , X. Marie , C. R. Zhu , B. L. Liu , T. Amand , P. H. Tan , B. Urbaszek

Recently emerging large-area single-layer MoS2 grown by chemical vapor deposition has triggered great interest due to its exciting potential for applications in advanced electronic and optoelectronic devices. Unlike gapless graphene, MoS2…

Van der Waals materials such as thin films of transition-metal dichalcogenides (TMDCs) manifest strongly bound exciton states in the visible spectrum at ambient conditions that provide an ideal platform for exciton-photon couplings.…

Optics · Physics 2025-07-15 Fatemeh Davoodi , Nahid Talebi

Transition metal oxides such as vanadium dioxide (VO$_2$), niobium dioxide (NbO$_2$), and titanium sesquioxide (Ti$_2$O$_3$) are known to undergo a temperature-dependent metal-insulator transition (MIT) in conjunction with a structural…

Interface chemistry and defect formation in MoS2 thin films grown on single crystal substrates critically determine the electronic structure of MoS2 and thus can strongly modify material functionality relevant for many applications,…

We use momentum-dependent electron energy-loss spectroscopy in transmission to study collective charge excitations in the layer metal Sr$_2$RuO$_4$. This metal has a transition from a perfect Fermi liquid below $T\approx30\,$K into a…

Strongly Correlated Electrons · Physics 2025-07-23 J. Schultz , A. Lubk , F. Jerzembeck , N. Kikugawa , M. Knupfer , D. Wolf , B. Büchner , J. Fink

We study conductance fluctuations in a two-dimensional electron gas as a function of chemical potential (or gate voltage) from the strongly insulating to the metallic regime. Power spectra of the fluctuations decay with two distinct…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 Dragana Popović , S. Washburn

Intrinsic electron- and hole-phonon interactions are investigated in monolayer transition metal dichalcogenides MX$_2$ (M=Mo,W; X=S,Se) based on a density functional theory formalism. Due to their structural similarities, all four materials…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Zhenghe Jin , Xiaodong Li , Jeffrey Thomas Mullen , Ki Wook Kim

We present a first-principles study of the effect of 3$d$ transition metal intercalation on the magnetic properties of the 2H-NbS$_2$ system, using spin-resolved density functional theory calculations to investigate the electronic structure…

Materials Science · Physics 2023-05-16 Z. Hawkhead , T. J. Hicken , N. P. Bentley , B. M. Huddart , S. J. Clark , T. Lancaster

We theoretically investigate the possibility of achieving a superconducting state in transition-metal dichalcogenide bilayers through intercalation, a process previously and widely used to achieve metallization and superconducting states in…

Superconductivity · Physics 2017-09-20 R. Szczesniak , A. P. Durajski , M. W. Jarosik

Research on black phosphorus (BP) has been experiencing a renaissance over the last few years, after the demonstration that few-layer BP exhibits high carrier mobility and a thickness-dependent band gap. For a long time, bulk BP is also…

Materials Science · Physics 2017-05-02 Renyan Zhang , John Waters , Andre K. Geim , Irina V. Grigorieva

This study explores the potential of MoS$_2$ polymorphs, specifically the semiconducting 2H phase and the metallic 1T$^\prime$ phase, as anchoring materials to enhance the electrochemical performance of lithium-sulfur (Li--S) batteries.…

Materials Science · Physics 2025-12-16 J. W. González , E. Flórez , R. A. Gallardo , J. D. Correa