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A series of MnO2 unique nanostructures were synthesized by a facile hydrothermal method with microwave-assisted procedures. A novel nanostructure formation mechanism has been proposed, that MnO6 octahedral nuclei and molecular layers can be…

Mesoscale and Nanoscale Physics · Physics 2012-07-16 R. Zeng , J. Q. Wang , G. D. Du , W. X. Li , Z. X. Chen , S. Li , S. X. Dou

Highly crystalline TiO2 nanostructures were prepared through a facile inorganic acid-assisted hydrothermal treatment of hexagonal-structured assemblies of nanocrystalline titiania templated by cetyltrimethylammonium bromide (Hex-ncTiO2/CTAB…

Materials Science · Physics 2012-11-20 Shuxi Dai , Yanqiang Wu , Toshio Sakai , Zuliang Du , Hideki Sakai , Masahiko Abe

Batteries are the most abundant form of electrochemical energy storage. Lithium and sodium ion batteries account for a significant portion of the battery market, but high-performance electrochemically active materials still need to be…

Photocatalytic $H_2$ evolution reactions on pristine TiO$_2$ is characterized by low efficiencies due to trapping and recombination of charge carriers, and due to a sluggish kinetics of electron transfer. Noble metal (mainly Pt, Pd, Au)…

We address one of the main challenges to TiO2-photocatalysis, namely band gap narrowing, by combining nanostructural changes with doping. With this aim we compare TiO2's electronic properties for small 0D clusters, 1D nanorods and…

Materials Science · Physics 2010-01-18 D. J. Mowbray , J. I. Martinez , J. M. García-Lastra , K. S. Thygesen , K. W. Jacobsen

Eutectic NiTiO$_3$-TiO$_2$ samples and their H$_2$ reduced Ni-TiO$_2$ samples, where high aspect ratio TiO$_2$ nanostructures are axially decorated with nodular Ni globules, are thoroughly explored to understand their effect in…

In the present work we report significant enhancement of the photoelectrochemical properties of self-organized TiO2 nanotubes by a combined de-coring of classic nanotubes followed by an appropiate TiCl4-treatment. We show that, except for…

Sub-wavelength laser induced periodic surface structures (LIPSS-Sticks) created by ultrashort pulsed laser irradiation on the surface of titanium are used for the first time to template the electrochemical growth of titanium dioxide…

Applied Physics · Physics 2020-08-04 Rakesh Arul , Junzhe Dong , M. Cather Simpson , Wei Gao

In the present work we demonstrate the self-organized formation of anodic Mo-oxide nanotube arrays grown on a Mo sheet under suitable electrochemical conditions in glycerol/NH4F electrolytes. The resulting amorphous tubes can be…

Materials Science · Physics 2016-10-21 Bowen Jin , Xuemei Zhou , Li Huang , Markus Licklederer , Min Yang , Patrik Schmuki

Here we report the extraordinary electrochemical energy storage capability of NiMoO4@NiMoO4 homogeneous hierarchical nanosheet-on-nanowire-arrays (SOWAs) synthesized on nickel substrate by a two-stage hydrothermal process. Comparatively…

In the present work we introduce a technique to form a photocatalyst, based on Pt nanoparticles suspended over the mouth of TiO2 nanotubes. These structures are obtained by the decoration of the top end of highly ordered TiO2 nanotubes with…

Chemical Physics · Physics 2016-10-18 Nhat Truong Nguyen , JeongEun Yoo , Marco Altomare , Patrik Schmuki

Self-standing TiO$_2$ nanotube layers in the form of membranes are fabricated by self-organizing anodization of Ti metal and a potential shock technique. The membranes were then decorated by sputtering different Pt amounts i) only at the…

Applied Physics · Physics 2020-06-02 Gihoon Cha , Marco Altomare , Nhat Truong Nguyen , Nicola Taccardi , Kiyoung Lee , Patrik Schmuki

Hierarchical C@MoS2@C hollow spheres with the active MoS2 nanosheets being sandwiched by carbon layers have been produced by means of a modified template method. The process applies polydopamine (PDA) layers which inhibit morphology change…

The present review gives an overview of the highlights of more than 10 years of research on synthesis and applications of ordered oxide structures (nanotube layers, hexagonal pore arrangements) that are formed by self-organizing anodization…

Materials Science · Physics 2016-10-13 Xuemei Zhou , Nhat Truong Nguyen , Selda Ozkan , Patrik Schmuki

We apply high-energy proton ion-implantation to modify TiO2 nanotubes selectively at their tops. In the proton-implanted region we observe the creation of intrinsic co-catalytic centers for photocatalytic H2-evolution. We find proton…

The inherent network of nanopores and voids in silicon dioxide (SiO2) is generally undesirable for aspects of film quality, electrical insulation and dielectric performance. However, if we view these pores as natural nano-patterns embedded…

Structural hierarchy is found in myriad biological systems and has improved man-made structures ranging from the Eiffel tower to optical cavities. Hierarchical metamaterials utilize structure at multiple size scales to realize new and…

Silicon is one of the most promising anode materials for Lithium-ion batteries. Silicon endures volume changes upon cycling, which leads to subsequent pulverization and capacity fading. These drawbacks lead to a poor lifespan and hamper the…

Materials Science · Physics 2022-12-23 Mariam Ezzedine , Fatme Jardali , Ileana Florea , Mihai-robert Zamfir , Costel-sorin Cojocaru

Photocatalytic reactions on TiO2 have recently gained an enormous resurgence because of various new strategies and findings that promise to drastically increase efficiency and specificity of such reactions by modifications of the titania…

Applied Physics · Physics 2020-04-13 Xuemei Zhou , Ning Liu , Patrik Schmuki

As renewable energy is becoming a critical energy source to meet the global demand, electrochemical energy storage devices become indispensable for the efficient energy storage and reliable supply. The electrode material is the key factor…