Related papers: Redefining the Phase Space for Ideal Gas Systems R…
The conventional approach to study glasses either requires considering the rapid drop in the excess entropy {\Delta}S_ex or the free volume V_f. As the two quantities are not directly related to each other, the viscosity in the two…
In statistical mechanics Gibbs' paradox is avoided if the particles of a gas are assumed to be indistinguishable. The resulting entropy then agrees with the empirically tested thermodynamic entropy up to a term proportional to the logarithm…
Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…
Liquid-gas phase transition in statistical mechanics is a long-standing dilemma not yet well explained. In this paper we propose a novel approach to this dilemma, by: 1). Putting forth a new space homogeneity assumption. 2). Giving a new…
In this paper, using of the rigorous statement and rigorous proof the Maxwell distribution as an example, we establish estimates of the distribution depending on the parameter $N$, the number of particles. Further, we consider the problem…
The entropy of Boltzmann-Gibbs, as proved by Shannon and Khinchin, is based on four axioms, where the fourth one concerns additivity. The group theoretic entropies make use of formal group theory to replace this axiom with a more general…
Based on a reconsideration of the Gibbs paradox, we show that a residual, non-extensive term in entropy turns up upon mixing identical particles, whether they are indistinguishable or not. The positive contribution from this residual…
We study an ideal Bose gas of N atoms contained in a box formed by two identical planar and parallel surfaces S, enclosed by a mantle of height a perpendicular to them. Calling r0 the mean atomic distance, we assume S >> r0^2 while a may be…
Identical classical particles are distinguishable. This distinguishability affects the number of ways W a macrostate can be realized on the micro-level, and from the relation S = k ln W leads to a non-extensive expression for the entropy.…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…
We study the behaviour of an ideal non-relativistic Bose gas in a three-dimensional space where one of the dimensions is compactified to form a circle. In this case there is no phase transition like that for the case of an infinite volume,…
Approach to the thermodynamic limit of a non-relativistic ideal gas in a periodic box is investigated. The single particle wave function obeys twisted boundary condition, $\psi(L)=e^{i\theta}\psi(0)$ for which the free particle spectrum is…
The ideal gas laws are derived from the democritian concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion aside from the law of energy conservation. A single…
In this work, we demonstrate the inappropriateness of the Boltzmann-Gibbs log-formulation of the physical Clausius entropy $S$ in connecting thermodynamics and phase space statistics. To achieve our goal, we study thermodynamically the…
The probability distribution of the velocity of gas molecules in a closed container is described by the kinetic theory of gases. When molecules collide or impact the walls of a container, they exchange energy and momentum in accordance with…
The spontaneous symmetry breaking in a vibro-fluidized low-density granular gas in three connected compartments is investigated. When the total number of particles in the system becomes large enough, particles distribute themselves…
The virial expansion of a gas is a correction to the ideal gas law that is usually discussed in advanced courses in statistical mechanics. In this note we outline this derivation in a manner suitable for advanced undergraduate and…
We prove Archimedes' principle for a macroscopic ball in ideal gas consisting of point particles with non-zero mass. The main result is an asymptotic theorem, as the number of point particles goes to infinity and their total mass remains…
Several alternative approaches to quantum gravity problem suggest the modification of the {\it fundamental volume $\omega_{0}$} of the accessible phase space for representative points. This modified fundamental volume has a novel momentum…
Exchange symmetry in acceleration partitions the configuration space of an N particle, one-dimensional, gravitational system into N! equivalent cells. We take advantage of the resulting small angular extent of each cell to construct a…