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Following the idea that hydrogen-rich compounds might be high-T$_c$ superconductors at high pressures, and the very recent breakthrough in predicting and synthesizing hydrogen sulfide with record-high T$_c$ = 203 K, ab initio evolutionary…

Superconductivity · Physics 2017-04-19 M. M. Davari Esfahani , A. R. Oganov , H. Niu , J. Zhang

It has been suggested that hydrogen may metallise at lower pressures if it is ``precompressed''. Here we introduce a search strategy for predicting high-pressure structures and apply it to silane using first-principles electronic structure…

Materials Science · Physics 2009-11-11 Chris J. Pickard , R. J. Needs

Through CaH2 chemical reduction of a parent R3+Ni3+O3 perovskite form, superconductivity was recently achieved in Sr-doped NdNiO2 on SrTiO3 substrate. Using density functional theory (DFT) calculations, we find that stoichiometric NdNiO2 is…

Materials Science · Physics 2022-02-02 Oleksandr I. Malyi , Julien Varignon , Alex Zunger

In this article, high composition (>35%) thick (>30 nm) barrier AlGaN/AlN/GaN HEMT structure grown on a sapphire substrate with ultra-low sheet resistivity (<250 \Omega / \Box ) is reported. Optimization of growth conditions, such as…

Many sub-Neptune exoplanets have been believed to be composed of a thick hydrogen-dominated atmosphere and a high-temperature heavier-element-dominant core. From an assumption that there is no chemical reaction between hydrogen and…

Earth and Planetary Astrophysics · Physics 2024-01-08 Taehyun Kim , Xuehui Wei , Stella Chariton , Vitali B. Prakapenka , Young-Jay Ryu , Shize Yang , Sang-Heon Shim

Evolutionary crystal structure prediction searches have been employed to explore the ternary Li-F-H system at 300 GPa. Metastable phases were uncovered within the static lattice approximation, with LiF$_3$H$_2$, LiF$_2$H, Li$_3$F$_4$H,…

Materials Science · Physics 2021-04-07 Tiange Bi , Andrew Shamp , Tyson Terpstra , Russell J. Hemley , Eva Zurek

Lanthanum hydride LaH$_{10}$ with a sodalitelike clathrate structure was experimentally realized to exhibit a room-temperature superconductivity under megabar pressures. Based on first-principles calculations, we reveal that the metal…

Superconductivity · Physics 2021-02-17 Seho Yi , Chongze Wang , Hyunsoo Jeon , Jun-Hyung Cho

Black phosphorus nitrogen (BP-N) is an attractive high-energy-density material. However, high-pressure synthesized BP-N will decompose at low-pressure and cannot be quenched to ambient conditions. Finding a method to stabilize it at 0 GPa…

Materials Science · Physics 2025-01-03 Guo Chen , Chengfeng Zhang , Yuanqin Zhu , Bingqing cao , Jie Zhang , Xianlong Wang

Nitrogen oxides are textbook class of molecular compounds, with extensive industrial applications. Nitrogen and oxygen are also among the most abundant elements in the universe. We explore the N-O system at 0 K and up to 500 GPa though ab…

Materials Science · Physics 2015-06-30 Dongxu Li , Artem R. Oganov , Xiao Dong , Xiang-Feng Zhou , Qiang Zhu , Guangrui Qian , Huafeng Dong

TThe stability of Ngn@B12N12 and Ngn@B16N16 systems is assessed through a density functional study and ab initio simulation. Although they are found to be thermodynamically unstable with respect to the dissociation of individual Ng atoms…

Atomic and Molecular Clusters · Physics 2014-01-10 Munmun Khatua , Sudip Pan , Pratim K. Chattaraj

High entropy materials are often entropy stabilized, meaning that the configurational entropy from multiple elements sharing a single lattice site stabilizes the structure. In this work, we study how high-pressure synthesis conditions can…

Equilibrium constants for Hydrogen and Helium isotopes as a function of density and temperature are measured in the framework of the study made by Qin et al. [Qin L et al 2012 Phys. Rev. Lett. 108 172701]. We review and comment on all…

Hydrogen is an efficient energy carrier that can be produced from renewable sources, enabling the transition towards CO2-free energy. Hydrogen can be stored for a long period in the solid-state, with suitable alloys. Ti-rich TiFe0.90…

Observations of intergalactic neutral hydrogen can provide a wealth of information about structure and galaxy formation, potentially tracing accretion and feedback processes on Mpc scales. Below a column density of NHI ~ 10^19 cm-2, the…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-13 Attila Popping , Romeel Dave , Robert Braun , Benjamin D. Oppenheimer

We study lanthanum mononitride LaN by first-principles calculations. The commonly reported rock-salt structure of $Fm\bar{3}m$ symmetry for rare-earth monopnictides is found dynamically unstable for LaN at zero temperature. Using density…

Materials Science · Physics 2021-08-26 Wei-Chih Chen , Chia-Min Lin , Joseph Maciejko , Cheng-Chien Chen

Volume expansion and elastic softening of Sn anode on lithiation result in mechanical degradation and pulverization of Sn, affecting the overall performance of Li-Sn batteries. It can however be overcome by using exotic high pressure…

Materials Science · Physics 2016-12-21 Raja Sen , Priya Johari

The combination of high pressure techniques with neutron scattering proves to be a powerful tool for studying the phase transitions and physical properties of solids in terms of inter-atomic distances. In our report we are going to review a…

Instrumentation and Detectors · Physics 2010-07-20 R. Done , O. Kirichek , B. E. Evans , Z. A. Bowden

This study investigates hydrogen permeation in titanium aluminium nitride (TiAlN) using ab initio density functional theory (DFT) for cubic and hexagonal crystal structures. Despite the significance of hydrogen barriers, the potential of…

Materials Science · Physics 2024-10-03 Cem Örnek , Rainer Fechte-Heinen

Helium nanodroplets are doped with cesium and molecular hydrogen and subsequently ionized by electrons. Mass spectra reveal H$_x$Cs$^{+}$ ions that contain as many as 130 hydrogen atoms. Two features in the spectra are striking: First, the…

Helium atoms and hydrogen molecules can be strongly bound inside interstitial channels within bundles of carbon nanotubes. An exploration of the low energy and low temperature properties of He-3 atoms is presented here. Recent study of the…

Materials Science · Physics 2009-11-10 S. M. Gatica , F. Ancilotto , M. W. Cole
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