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Designing optimal formulations is a major challenge in developing electrolytes for the next generation of rechargeable batteries due to the vast combinatorial design space and complex interplay between multiple constituents. Machine…

Advanced battery management systems rely on mathematical models to guarantee optimal functioning of Lithium-ion batteries. The Pseudo-Two Dimensional (P2D) model is a very detailed electrochemical model suitable for simulations. On the…

Systems and Control · Computer Science 2019-10-01 Andrea Pozzi , Gabriele Ciaramella , Stefan Volkwein , Davide M. Raimondo

Lithium-ion battery packs are usually composed of hundreds of cells arranged in series and parallel connections. The proper functioning of these complex devices requires suitable Battery Management Systems (BMSs). Advanced BMSs rely on…

Systems and Control · Electrical Eng. & Systems 2019-09-30 Andrea Pozzi , Marcello Torchio , Richard D. Braatz , Davide M. Raimondo

Polymer electrolytes (PEs) are promising candidates for use in next-generation high-voltage batteries, as they possess advantageous elastic and electrochemical properties. However, PEs still suffer from low ionic conductivity and need to be…

Accurate estimation of the internal states of lithium-ion batteries is key towards improving their management for safety, efficiency and longevity purposes. Various approaches exist in the literature in this context, among which designing…

Systems and Control · Electrical Eng. & Systems 2023-08-21 Mira Khalil , Romain Postoyan , Stéphane Raël

Lithium-ion (Li-ion) batteries are ubiquitous in modern energy storage systems, highlighting the critical need to comprehend and optimize their performance. Yet, battery models often exhibit poor parameter identifiability which hinders the…

Systems and Control · Electrical Eng. & Systems 2024-06-14 Jorge Espin , Yuichi Kajiura , Dong Zhang

This work presents a comparative study of optimization techniques for parameter identification in equivalent electrical models of lithium-ion batteries. The 2RC model is applied to a set of twelve batteries using four publicly available…

Optimization and Control · Mathematics 2025-12-03 Johan Sebastian Suarez Sepúlveda , Edgar Hernando Sepúlveda-Oviedo , Bruno Jammes , Corinne Alonso

Li-ion rechargeable batteries have enabled the wireless revolution transforming global communication. Future challenges, however, demands distributed energy supply at a level that is not feasible with the current energy-storage technology.…

Electrolytes mediate interactions between the cathode and anode and determine performance characteristics of batteries. Mixtures of multiple solvents are often used in electrolytes to achieve desired properties, such as viscosity,…

Chemical Physics · Physics 2024-10-22 Celia Kelly , Emil Annevelink , Adarsh Dave , Venkatasubramanian Viswanathan

Porous electrode theory (PET) provides essential insights into electrochemical states, but its computational complexity hinders real-time control and obscures scaling relations. To bridge the gap between high-fidelity simulations and…

Systems and Control · Electrical Eng. & Systems 2026-04-21 Shakul Pathak , Martin Z. Bazant

Efficient parameter identification of electrochemical models is crucial for accurate monitoring and control of lithium-ion cells. This process becomes challenging when applied to complex models that rely on a considerable number of…

Systems and Control · Electrical Eng. & Systems 2024-05-20 Jianzong Pi , Samuel Filgueira da Silva , Mehmet Fatih Ozkan , Abhishek Gupta , Marcello Canova

A major challenge in the development of new battery materials is understanding their fundamental mechanisms of operation and degradation. Their microscopically inhomogeneous nature calls for characterization tools that provide operando and…

Li-CO$_2$ batteries are promising energy storage systems due to their high theoretical energy density and CO$_2$ fixation capability, relying on reversible Li$_2$CO$_3$/C formation during discharge/charge cycles. We present a multiscale…

As an anode material for lithium-ion batteries, amorphous silicon offers a significantly higher energy density than the graphite anodes currently used. Alloying reactions of lithium and silicon, however, induce large deformation and lead to…

Numerical Analysis · Mathematics 2024-08-07 Raphael Schoof , Johannes Niermann , Alexander Dyck , Thomas Böhlke , Willy Dörfler

Battery degradation is a major challenge in electric vehicles (EV) and energy storage systems (ESS). However, most degradation investigations focus mainly on estimating the state of charge (SOC), which fails to accurately interpret the…

Machine Learning · Computer Science 2025-04-22 Md Azizul Hoque , Babul Salam , Mohd Khair Hassan , Abdulkabir Aliyu , Abedalmuhdi Almomany , Muhammed Sutcu

As the use of Lithium-ion batteries continues to grow, it becomes increasingly important to be able to predict their remaining useful life. This work aims to compare the relative performance of different machine learning algorithms, both…

Machine Learning · Computer Science 2023-12-12 Hudson Hilal , Pramit Saha

A reinforcement learning-based optimal charging strategy is proposed for Li-ion batteries to extend the battery life and to ensure the end-user convenience. Unlike most previous studies that do not reflect real-world scenario well, in this…

Systems and Control · Electrical Eng. & Systems 2020-05-19 Minho Kim , Jongchan Baek , Soohee Han

We reformulate and extend porous electrode theory for non-ideal active materials, including those capable of phase transformations. Using principles of non-equilibrium thermodynamics, we relate the cell voltage, ionic fluxes, and Faradaic…

Chemical Physics · Physics 2012-08-24 Todd R. Ferguson , Martin Z. Bazant

The entropic coefficient of a lithium-ion battery cell is used to calculate the reversible heat of a battery during operation, which is a non-negligible part for the battery thermal modelling. The contribution of this article is to propose…

Chemical Physics · Physics 2021-11-03 Zeyang Geng , Jens Groot , Torbjörn Thiringer

Battery management systems may rely on mathematical models to provide higher performance than standard charging protocols. Electrochemical models allow us to capture the phenomena occurring inside a lithium-ion cell and therefore, could be…

Computational Engineering, Finance, and Science · Computer Science 2020-05-12 Andrea Pozzi , Xiangzhong Xie , Davide M Raimondo , René Schenkendorf