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We propose a general multiscale approach for the mechanical behavior of three-dimensional networks of macromolecules undergoing strain-induced unfolding. Starting from a (statistically based) energetic analysis of the macromolecule…

Soft Condensed Matter · Physics 2015-06-22 Domenico De Tommasi , Giuseppe Puglisi , Giuseppe Saccomandi

Stochastic simulations are used to characterize the knotting distributions of random ring polymers confined in spheres of various radii. The approach is based on the use of multiple Markov chains and reweighting techniques, combined with…

Soft Condensed Matter · Physics 2009-11-11 C. Micheletti , D. Marenduzzo , E. Orlandini , D. W. Sumners

We investigate the typical cycle lengths, the total number of cycles, and the number of finite cycles in random permutations whose probability involves cycle weights. Typical cycle lengths and total number of cycles depend strongly on the…

Probability · Mathematics 2013-11-28 Nicholas M. Ercolani , Daniel Ueltschi

Based upon kinetic Monte Carlo simulations of crystallization in a simple polymer model we present a new picture of the mechanism by which the thickness of lamellar polymer crystals is constrained to a value close to the minimum…

Condensed Matter · Physics 2007-05-23 Jonathan Doye , Daan Frenkel

Many problems in materials science and biology involve particles interacting with strong, short-ranged bonds, that can break and form on experimental timescales. Treating such bonds as constraints can significantly speed up sampling their…

Numerical Analysis · Mathematics 2020-12-02 Miranda Holmes-Cerfon

Molecular dynamics simulations are used to study structure formation in simple model polymer chains that are subject to excluded volume and torsional interactions. The changing conformations exhibited by chains of different lengths under…

Soft Condensed Matter · Physics 2009-11-07 D. C. Rapaport

We have analyzed the equilibrium response of chain molecules to stretching. For a homogeneous sequence of monomers, the induced transition from compact globule to extended coil below the $\theta$-temperature is predicted to be sharp. For…

Soft Condensed Matter · Physics 2009-11-07 Phillip L. Geissler , Eugene I. Shakhnovich

Multiple loop formation in polymer macromolecules is an important feature of the chromatin organization and DNA compactification in the nuclei. We analyze the size and shape characteristics of complex polymer structures, containing in…

Soft Condensed Matter · Physics 2015-04-20 Viktoria Blavatska , Ralf Metzler

In a cellular medium, the plasmic membrane is a place of interactions between the cell and its direct external environment. A classic model describes it as a fluid mosaic. The fluid phase of the membrane allows a lateral degree of freedom…

Probability · Mathematics 2013-09-24 Aimé Lachal

We propose a new toy model of a heteropolymer chain capable of forming planar secondary structures typical for RNA molecules. In this model the sequential intervals between neighboring monomers along a chain are considered as quenched…

Soft Condensed Matter · Physics 2014-01-07 S. K. Nechaev , A. N. Sobolevski , O. V. Valba

We present a new simulation technique to study systems of polymers functionalized by reactive sites that bind/unbind forming reversible linkages. Functionalized polymers feature self-assembly and responsive properties that are unmatched by…

Soft Condensed Matter · Physics 2018-04-18 Bernardo Oyarzún , Bortolo Matteo Mognetti

The state space of a polymer molecule is analysed. We show how the size of the state space can be reduced on the basis of symmetry. In the reduced state space, the probability of a new state (termed below as class) is equal to the number of…

Computational Physics · Physics 2012-03-30 Malgorzata J. Krawczyk

Polymers with both soluble and insoluble blocks typically self-assemble into micelles, aggregates of a finite number of polymers where the soluble blocks shield the insoluble ones from contact with the solvent. Upon increasing…

Soft Condensed Matter · Physics 2009-11-13 J. A. Anderson , C. D. Lorenz , A. Travesset

We explore the critical behaviour of two and three dimensional lattice models of polymers in dilute solution where the monomers carry a magnetic moment which interacts ferromagnetically with near-neighbour monomers. Specifically, the model…

Statistical Mechanics · Physics 2021-08-25 Damien Paul Foster , Debjyoti Majumdar

We define a new class of random walk processes which maximize entropy. This maximal entropy random walk is equivalent to generic random walk if it takes place on a regular lattice, but it is not if the underlying lattice is irregular. In…

Disordered Systems and Neural Networks · Physics 2013-05-29 Z. Burda , J. Duda , J. M. Luck , B. Waclaw

We analyze the motion of individual beads of a polymer chain using a discrete version of De Gennes' reptation model that describes the motion of a polymer through an ordered lattice of obstacles. The motion within the tube can be evaluated…

Soft Condensed Matter · Physics 2016-08-15 U. Ebert , L. Schäfer , A. Baumgärtner

Several cycle lexicographical orders are found to describe the relative likelihood of elements of the random walks on the symmetric group generated by the conjugacy classes of transpositions, 3-cycles, and n-cycles. Spectral analysis finds…

Combinatorics · Mathematics 2014-11-14 Megan Bernstein

This work addresses the question of whether it is possible to define simple pair-wise interaction terms to approximate free energies of proteins or polymers. Rather than ask how reliable a potential of mean force is, one can ask how…

Soft Condensed Matter · Physics 2009-10-31 Dirk Reith , Thomas Huber , Florian Mueller-Plathe , Andrew E. Torda

We consider the persistent exclusion process in which a set of persistent random walkers interact via hard-core exclusion on a hypercubic lattice in $d$ dimensions. We work within the ballistic regime whereby particles continue to hop in…

Statistical Mechanics · Physics 2020-11-23 Matthew J. Metson , Martin R. Evans , Richard A. Blythe

We consider an infinite system of particles in one dimension, each particle performs independant Sinai's random walk in random environment. Considering an instant $t$, large enough, we prove a result in probability showing that the…

Probability · Mathematics 2009-11-13 Pierre Andreoletti