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Smoluchowski's coagulation equations can be used as elementary mathematical models for the formation of polymers. We review here some recent contributions on a variation of this model in which the number of aggregations for each atom is a…

Probability · Mathematics 2012-02-24 Jean Bertoin

Binary coagulation is an important process in aerosol dynamics by which two particles merge to form a larger one. The distribution of particle sizes over time may be described by the so-called Smoluchowski's coagulation equation. This…

Mathematical Physics · Physics 2021-06-25 Marina A. Ferreira

We investigate the influence of multiscale aggregation and deposition on the colloidal dynamics in a saturated porous medium. At the pore scale, the aggregation of colloids is modeled by the Smoluchowski equation. Essentially, the colloidal…

Analysis of PDEs · Mathematics 2014-04-17 Oleh Krehel , Adrian Muntean , Peter Knabner

Temperature-dependent Smoluchowski equations describe the ballistic agglomeration. In contrast to the standard Smoluchowski equations for the evolution of cluster densities with constant rate coefficients, the temperature-dependent…

Statistical Mechanics · Physics 2022-10-11 A. I. Osinsky , N. V. Brilliantov

We consider two simple models for the formation of polymers where at the initial time, each monomer has a certain number of potential links (called arms in the text) that are consumed when aggregations occur. Loosely speaking, this imposes…

Mathematical Physics · Physics 2015-05-13 Jean Bertoin

We study the dynamics of diffusion-limited irreversible aggregation of monomers, where bonds are mediated by linkers. We combine kinetic Monte Carlo simulations of a lattice model with a mean-field theory to study the dynamics when the…

Soft Condensed Matter · Physics 2019-05-31 G. C. Antunes , C. S. Dias , M. M. Telo da Gama , N. A. M. Araújo

The Smoluchowski equation is a system of partial differential equations modelling the diffusion and binary coagulation of a large collection of tiny particles. The mass parameter may be indexed either by positive integers, or by positive…

Probability · Mathematics 2008-12-01 Mohammad Reza Yaghouti , Fraydoun Rezakhanlou , Alan Hammond

We present a rigorous thermodynamic treatment of irreversible binary aggregation. We construct the Smoluchowski ensemble as the set of discrete finite distributions generated from the same initial state of all monomers upon fixed number…

Statistical Mechanics · Physics 2020-11-16 Themis Matsoukas

Modeling of aggregation processes in space-inhomogeneous systems is extremely numerically challenging since complicated aggregation equations -- Smoluchowski equations are to be solved at each space point along with the computation of…

Computational Physics · Physics 2023-12-11 M. A. Larchenko , R. R. Zagidullin , V. V. Palyulin , N. V. Brilliantov

We consider in this work a model for aggregation, where the coalescing particles initially have a certain number of potential links (called arms) which are used to perform coagulations. There are two types of arms, male and female, and two…

Mathematical Physics · Physics 2009-11-09 Raoul Normand

Similarly-charged polyelectrolytes are known to attract each other and aggregate into bundles when the charge density of the polymers exceeds a critical value that depends on the valency of the counterions. The dynamics of aggregation of…

Soft Condensed Matter · Physics 2016-09-22 Anvy Moly Tom , R. Rajesh , Satyavani Vemparala

We study multicomponent coagulation via the Smoluchowski coagulation equation under non-equilibrium stationary conditions induced by a source of small clusters. The coagulation kernel can be very general, merely satisfying certain power law…

Analysis of PDEs · Mathematics 2021-03-25 Marina A. Ferreira , Jani Lukkarinen , Alessia Nota , Juan J. L. Velázquez

In this article a stochastic particle system approximation to the parametric sensitivity in the Smoluchowski coagulation equation is introduced. The parametric sensitivity is the derivative of the solution to the equation with respect to…

Probability · Mathematics 2016-09-08 I. Bailleul , P. L. W. Man , M. Kraft

Many soft-matter and biophysical systems are composed of monomers which reversibly assemble into rod-like aggregates. The aggregates can then order into liquid-crystal phases if the density is high enough, and liquid-crystal ordering…

Soft Condensed Matter · Physics 2010-07-27 Tatiana Kuriabova , M. D. Betterton , Matthew A. Glaser

The aggregation of interacting Brownian particles in sheared concentrated suspensions is an important issue in colloid and soft matter science per se. Also, it serves as a model to understand biochemical reactions occurring in vivo where…

Soft Condensed Matter · Physics 2010-04-14 Alessio Zaccone , Daniele Gentili , Hua Wu , Massimo Morbidelli

The initial purpose of this work is to provide a probabilistic explanation of a recent result on a version of Smoluchowski's coagulation equations in which the number of aggregations is limited. The latter models the deterministic evolution…

Probability · Mathematics 2009-11-13 Jean Bertoin , Vladas Sidoravicius

We study a Smoluchowski equation describing a simple mean-field model of particles moving in $d$ dimensions and aggregating with conservation of `mass' $s=R^D$ ($R$ is the particle radius). In the scaling regime the scaled mass distribution…

Condensed Matter · Physics 2007-05-23 Stéphane Cueille , Clément Sire

We numerically study a simple fluid composed of particles having a hard-core repulsion, complemented by two short-ranged attractive (sticky) spots at the particle poles, which provides a simple model for equilibrium polymerization of linear…

Soft Condensed Matter · Physics 2009-11-13 F. Sciortino , E. Bianchi , J. F. Douglas , P. Tartaglia

An overview of the author's papers on the new approach to the Brownian coagulation theory and its generalization to the diffusion-limited reaction rate theory is presented. The traditional diffusion approach of the Smoluchowski theory for…

Chemical Physics · Physics 2016-05-24 Mikhail S. Veshchunov

Here we develop a formalism for reversible ionic aggregation kinetics in an example concentrated electrolyte, building on previous equilibrium work of McEldrew and co-workers, and thermoreversible polymers and patchy particle systems. This…

Soft Condensed Matter · Physics 2026-05-04 Zachary A. H. Goodwin
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