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When a droplet containing a non-volatile component is dried on a substrate, it leaves a ringlike deposit on the substrate. We propose a theory which predicts the deposit distribution based on a model of fluid flow and contact line motion of…

Soft Condensed Matter · Physics 2016-02-17 Xingkun Man , Masao Doi

We studied the morphology of linear particle deposits obtained by inkjet-printing of silica nanoparticle suspension in drying condition where contact line depinning occurs. We show that this evaporation mode can be obtained by adjusting the…

Soft Condensed Matter · Physics 2020-12-09 N. Bridonneau , G. Mattana , V. Noël , S. Zrig , F. Carn

Deposits from evaporating drops have shown to take a variety of shapes, depending on the physicochemical properties of both solute and solvent. Classically, the evaporation of drops of colloidal suspensions leads to the so-called coffee…

Soft Condensed Matter · Physics 2021-05-04 Marius R. Bittermann , Daniel Bonn , Sander Woutersen , Antoine Deblais

Orientational and positional ordering properties of liquid crystal monolayers are examined by means of Fundamental-Measure Density Functional Theory. Particles forming the monolayer are modeled as hard parallelepipeds of square section of…

Soft Condensed Matter · Physics 2015-06-19 Yuri Martinez-Raton , Szabolcs Varga y Enrique Velasco

We consider a theoretical model for a binary mixture of colloidal particles and spherical emulsion droplets. The hard sphere colloids interact via additional short-ranged attraction and long-ranged repulsion. The droplet-colloid interaction…

Soft Condensed Matter · Physics 2012-01-11 Ingmar Schwarz , Andrea Fortini , Claudia Simone Wagner , Alexander Wittemann , Matthias Schmidt

We propose a theory for the multi-ring pattern of the deposits that are formed when droplets of suspension are dried on a substrate. Assuming a standard model for the stick-slip motion of the contact line, we show that as droplets…

Soft Condensed Matter · Physics 2018-07-26 Mengmeng Wu , Xingkun Man , Masao Doi

This review covers experimental results of evaporative lithography and analyzes existing mathematical models of this method. Evaporating droplets and films are used in different fields, such as cooling of heated surfaces of electronic…

Applied Physics · Physics 2024-04-04 Konstantin Kolegov , Lev Barash

The deposition of particles on a substrate by drying a colloidal suspension droplet is at the core of applications ranging from traditional printing on paper to printable electronics or photovoltaic devices. The self-pinning induced by the…

Fluid Dynamics · Physics 2019-08-21 Qingguang Xie , Jens Harting

Phase transformations can be difficult to characterize at the microscopic level due to the inability to directly observe individual atomic motions. Model colloidal systems, by contrast, permit the direct observation of individual particle…

Soft Condensed Matter · Physics 2015-04-21 Ye Yang , Lin Fu , Catherine Marcoux , Joshua E. S. Socolar , Patrick Charbonneau , Benjamin B. Yellen

We present a framework for calculating the surface density profile of a stain deposited by a drop with a receding contact line. Unlike a pinned drop, a receding drop pushes fluid towards its interior, continuously deposits mass across its…

Soft Condensed Matter · Physics 2014-10-10 Julian Freed-Brown

Charged colloidal particles trapped at an air--water interface are well known to form an ordered crystal, stabilized by a long ranged repulsion, the details of this repulsion remain something of a mystery, but all experiments performed to…

Soft Condensed Matter · Physics 2016-12-22 Duck-Gyu Lee , Pietro Cicuta , Dominic Vella

We study the coupling between the structural dynamics and rheological response of charged colloidal monolayers at water/oil interfaces, driven into steady shear by a microdisk rotating at a controlled angular velocity. The flow causes…

Soft Condensed Matter · Physics 2015-09-14 Ivo Buttinoni , Zachary A. Zell , Todd M. Squires , Lucio Isa

We report observations of the self-assembly of coated droplets into regular clusters at the sudden expansion of a microfluidic channel. A double emulsion consisting of a regular train of coated microdroplets was created upstream of the…

Soft Condensed Matter · Physics 2020-10-19 Kerstin Schirrmann , Gabriel Cáceres-Aravena , Anne Juel

We propose a simple seedless approach to assemble millimeter sized monolayer single colloidal crystals with desired orientations at predetermined locations on an unstructured charged substrate. This approach utilizes the millimeter-ranged…

Soft Condensed Matter · Physics 2018-03-09 Ran Niu , Thomas Palberg

We study the self-assembly of magnetic colloids using the Stockmayer (SM) model characterized by short-range Lennard-Jones interactions and long-range dipole-dipole interactions. Using molecular dynamics simulations, we design cooling…

Soft Condensed Matter · Physics 2025-06-30 Anuj Kumar Singh , Sanjay Puri , Varsha Banerjee

The so-called coffee stain effect has been intensively studied over the past decades, but most of the studies are focused on sessile droplets. In this paper, we analyse the origin of the difference between the deposition of suspended…

Fluid Dynamics · Physics 2023-03-22 Marie Corpart , Frédéric Restagno , François Boulogne

It has been experimentally established in numerous cases that precipitation of monodispersed colloids from homogeneous solutions is a complex process. Specifically, it was found that in many systems nuclei, produced rapidly in a…

Materials Science · Physics 2010-09-22 Vladimir Privman , Dan V. Goia , Jongsoon Park , Egon Matijevic

Thermally or chemically active colloids generate thermodynamic gradients in the solution in which they are immersed and thereby induce hydrodynamic flows that affect their dynamical evolution. Here we study a mean-field model for the…

Soft Condensed Matter · Physics 2020-11-06 Alvaro Domínguez , Mihail N. Popescu

The evaporation of a droplet induces variety of ordered patterns near the contact line between the droplet and a substrate. This pattern formation involves both the behavior of colloidal suspensions and interactions between a droplet and a…

Soft Condensed Matter · Physics 2024-08-05 Yusaku Abe , Yu Matsuda

We study the influence of particle shape on growth processes at the edges of evaporating drops. Aqueous suspensions of colloidal particles evaporate on glass slides, and convective flows during evaporation carry particles from drop center…

Soft Condensed Matter · Physics 2015-06-11 Peter J. Yunker , Matthew A. Lohr , Tim Still , Alexei Borodin , D. J. Durian , A. G. Yodh