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Many astrochemical models today explicitly consider the species that comprise the bulk of interstellar dust grain ice-mantles separately from those in the top few monolayers. Bombardment of these ices by ionizing radiation - whether in the…

Astrophysics of Galaxies · Physics 2019-05-29 Christopher N. Shingledecker , Anton Vasyunin , Eric Herbst , Paola Caselli

Interactions between cold ions and atoms have been proposed for use in implementing quantum gates\cite{Idziaszek2007}, probing quantum gases\cite{Sherkunov2009}, observing novel charge-transport dynamics\cite{Cote2000}, and sympathetically…

Carbon ($^3$P) atom is a reactive species that, according to laboratory experiments and theoretical calculations, condensates with interstellar ice components. This fact is of uttermost importance for the chemistry in the interstellar…

Astrophysics of Galaxies · Physics 2023-07-19 Stefano Ferrero , Cecilia Ceccarelli , Piero Ugliengo , Mariona Sodupe , Albert Rimola

The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the…

Astrophysics of Galaxies · Physics 2025-12-16 Ryota Ichimura , Hideko Nomura , Kenji Furuya , Tetsuya Hama , T. J. Millar

The reactivity of interstellar carbon atoms (C) on the water-dominated ices is one of the possible ways to form interstellar complex organic molecules (iCOMs). In this work, we report a quantum chemical study of the coupling reaction of C…

Astrophysics of Galaxies · Physics 2023-10-24 Stefano Ferrero , Cecilia Ceccarelli , Piero Ugliengo , Mariona Sodupe , Albert Rimola

Ice is ubiquitous in the interstellar medium. We model the formation of the main constituents of interstellar ices, including H2O, CO2 , CO, and CH3 OH. We strive to understand what physical or chemical parameters influence the final…

Astrophysics of Galaxies · Physics 2023-07-26 A. Clément , A. Taillard , V. Wakelam , P. Gratier , J. -C. Loison , E. Dartois , F. Dulieu , J. A. Noble , M. Chabot

Methane is one of the simplest stable molecules that is both abundant and widely distributed across space. It is thought to have partial origin from interstellar molecular clouds, which are near the beginning of the star formation cycle.…

Solar and Stellar Astrophysics · Physics 2020-04-16 D. Qasim , G. Fedoseev , K. -J. Chuang , J. He , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

We present two methods for studying reactive collisions between two atomic or molecular species: a collinear merged-beam method, in which two gas pulses from a single supersonic beam source are coalesced, and an intrabeam-scattering…

Atomic Physics · Physics 2021-07-15 Katrin Dulitz , Marco van den Beld-Serrano , Frank Stienkemeier

We study conditions under which carbon clusters of different sizes form and stabilize. {We describe an approach to equilibrium by simulating tenuous carbon gas dynamics to long times.} First, we use reactive molecular dynamics simulations…

Astrophysics of Galaxies · Physics 2015-06-18 N. Patra , P. Kral , H. R. Sadeghpour

This review paper summarizes the state-of-the-art in laboratory based interstellar ice chemistry. The focus is on atom addition reactions, illustrating how water, carbon dioxide and methanol can form in the solid state at astronomically…

Astrophysics of Galaxies · Physics 2015-07-13 Harold Linnartz , Sergio Ioppolo , Gleb Fedoseev

We introduce a method for shaping a cold atom cloud using a vortex laser beam with a polarization singularity at its center, which creates a point of vanishing intensity. Exploiting this feature we experimentally demonstrate two different…

{It is necessary to understand the dynamics of the atomic gas to use complex modeling and to carry out detailed comparisons between theoretical models and observations.}{In a companion paper, we present high resolution bidimensional…

Astrophysics · Physics 2007-05-23 P. Hennebelle , E. Audit , M. -A Miville-Deschenes

We present a method for modelling star-forming clouds that combines two different models of the thermal evolution of the interstellar medium (ISM). In the combined model, where the densities are low enough that at least some part of the…

Solar and Stellar Astrophysics · Physics 2015-03-19 Matthew R. Bate , Eric R. Keto

We have designed an improved algorithm that enables us to simulate the chemistry of cold dense interstellar clouds with a full gas-grain reaction network. The chemistry is treated by a unified microscopic-macroscopic Monte Carlo approach…

Earth and Planetary Astrophysics · Physics 2015-06-19 Qiang Chang , Eric herbst

The formation of double and triple C-C bonds from the processing of pure c-C6H12 (cyclohexane) and mixed H2O:NH3:c-C6H12 (1:0.3:0.7) ices by highly-charged, and energetic ions (219 MeV O^{7+} and 632 MeV Ni^{24+}) is studied. The…

Astrophysics of Galaxies · Physics 2015-06-04 S. Pilling , D. P. P. Andrade , E. F. da Silveira , H. Rothard , A. Domaracka , P. Boduch

Photon-mediated interaction can be used for simulating complex many-body phenomena with ultracold atoms coupled to electromagnetic modes of an optical resonator. We theoretically study a method of producing controllable interatomic…

Quantum Gases · Physics 2024-07-16 Ivor Krešić

Observations of the circumgalactic medium (CGM) often display coincident absorption from species with widely varying ionization states, providing direct evidence for complex, multiphase interactions. Motivated by these measurements, we…

Astrophysics of Galaxies · Physics 2025-05-23 Lisiyuan Yang , Neal Katz , Evan Scannapieco , Marcus Brüggen

Hydrogenation reactions of CO in inter- and circumstellar ices are regarded as an important starting point in the formation of more complex species. Previous laboratory measurements by two groups on the hydrogenation of CO ices resulted in…

Solar and Stellar Astrophysics · Physics 2009-06-15 G. W. Fuchs , H. M. Cuppen , S. Ioppolo , C. Romanzin , S. E. Bisschop , S. Andersson , E. F. van Dishoeck , H. Linnartz

The interstellar medium is characterized by a rich and diverse chemistry. Many of its complex organic molecules are proposed to form through radical chemistry in icy grain mantles. Radicals form readily when interstellar ices (composed of…

Astrophysics of Galaxies · Physics 2016-09-13 Karin I. Oberg

Context: Hydrogenation reactions are expected to be among the most important surface reactions on interstellar ices. However, solid state astrochemical laboratory data on reactions of H-atoms with common interstellar ice constituents are…

Astrophysics · Physics 2009-11-13 S. E. Bisschop , G. W. Fuchs , E. F. van Dishoeck , H. Linnartz