Related papers: Hydrogenated Fullerenes (Fulleranes) in Space
The quasi-hexagonal phase of the two-dimensional fullerene network (qHPC$_{60}$), recently synthesized, has emerged as a stable carbon-based material with distinct structural and electronic features. In this work, we employed density…
Although they are only minor constituents of the interstellar medium, halogen-containing molecules are of special interest because of their unique thermochemistry. Here, we present a theoretical study of the chemistry of interstellar…
In the last three decades, zero-dimensional, one-dimensional, and two-dimensional carbon nanomaterials (i.e., fullerenes, carbon nanotubes, and graphene, respectively) have attracted significant attention from the scientific community due…
The {\em DIOGENESS} X-ray crystal spectrometer on the {\em CORONAS-F} spacecraft operated for a single month (25~August to 17~September) in 2001 but in its short lifetime obtained one hundred and forty high-resolution spectra from some…
The laboratory gas phase spectrum recently published by Campbell et al. has reinvigorated attempts to confirm the presence of the C$_{60}^+$ cation in the interstellar medium, thorough an analysis of the spectra of hot, reddened stars. This…
This study presents the largest mid-infrared spectral catalog of Herbig Ae/Be stars to date, containing the Spitzer Infrared Spectrograph spectra of 126 stars. Based on the catalog analysis, two prominent infrared vibrational modes of…
Context. The circumstellar environment of evolved stars is generally rich in molecular gas and dust. Typically, the entire environment is either oxygen-rich or carbon-rich, depending on the evolution of the central star. Aims. In this paper…
Formed at an early stage of gas-phase ion-molecule chemistry, hydrides -- molecules containing a heavy element covalently bonded to one or more hydrogen atoms -- play an important role in interstellar chemistry as they are the progenitors…
Large-scale practical applications of fullerene (C60) in nanodevices could be significantly facilitated if the commercially-available micrometer-scale raw C60 powder were further processed into a one-dimensional (1D) nanowire-related…
Dust particles play a major role in the formation, evolution and chemistry of interstellar clouds, stars and planetary systems. Commonly identified forms include amorphous and crystalline carbon-rich particles and silicates. Also present in…
Sequential ionization of fullerene cluster ions (C$_{60}$)$_{n}^{+}$ within multiply-charged helium nanodroplets leads to the intriguing phenomenon of forming and stabilizing doubly- and triply-charged fullerene oligomers. Surprisingly, we…
Intense X-ray photo-absorption from short and intense pulses by a molecule triggers complicated electron and subsequently ion dynamics leading to photo-electron spectra which are difficult to interpret. Illuminating fullerenes offers a way…
A pseudopotential of $C_{60}^-$ has been constructed from ab-initio quantum-mechanical calculations. Since the obtained pseudopotential can be easily fitted by rather simple analytical approximation it can be effectively used both in…
It is well known that collective electronic excitations in fullerene C$_{60}$ are manifested as Mie plasmons, and in graphene (the limiting case of an infinitely large fullerene) collective excitations are of plasmon-polariton type. How the…
The chemical abundance patterns of the oldest stars in the Galaxy are expected to contain residual signatures of the first stars in the early universe. Numerous studies attempt to explain the intrinsic abundance scatter observed in some…
There exists a number of astronomical spectral phenomena that have remained unidentified after decades of extensive observations. The diffuse interstellar bands, the 220 nm feature, unidentified infrared emission bands, extended red…
As building blocks of dust, rocky planets, and even complex life, the chemical elements heavier than hydrogen (H) and helium (He) - called "metals" in astronomy - play an essential role in our Universe and its evolution. Up to Fe and Ni,…
Magnetism of fullerene C60 was studied by three methods of the density functional theory (DFT) calculation, laboratory experiment and astronomical observation. DFT revealed that the most stable spin state was non-magnetic one of Sz=0/2.…
Methods for creating endofullerenes have been steadily improving since their discovery, allowing for new types of endofullerenes to be created in larger numbers. When a molecule is trapped in a fullerene, the fullerene creates a harmonic…
We study C70 fullerene matter waves in a Talbot-Lau interferometer as a function of their temperature. While the ideal fringe visibility is observed at moderate molecular temperatures, we find a gradual degradation of the interference…