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Obtaining the expectation value of an observable on a quantum computer is a crucial step in the variational quantum algorithms. For complicated observables such as molecular electronic Hamiltonians, a common strategy is to present the…

Quantum Physics · Physics 2022-04-20 Tzu-Ching Yen , Aadithya Ganeshram , Artur F. Izmaylov

The transformation of a molecular Hamiltonian from the fermionic space to the qubit space results in a series of Pauli strings. Calculating the energy then involves evaluating the expectation values of each of these strings, which presents…

Quantum Physics · Physics 2025-03-25 Harshdeep Singh , Sonjoy Majumder , Sabyashachi Mishra

Variational Hybrid Quantum Classical Algorithms (VHQCAs) are a class of quantum algorithms intended to run on noisy intermediate-scale quantum (NISQ) devices. These algorithms employ a parameterized quantum circuit (ansatz) and a…

Quantum Physics · Physics 2021-06-17 Aidan Pellow-Jarman , Ilya Sinayskiy , Anban Pillay , Francesco Petruccione

In this paper, we propose shot optimization method for QML models at the expense of minimal impact on model performance. We use classification task as a test case for MNIST and FMNIST datasets using a hybrid quantum-classical QML model.…

Quantum Physics · Physics 2023-04-28 Koustubh Phalak , Swaroop Ghosh

Quantum computers offer a promising route to tackling problems that are classically intractable such as in prime-factorization, solving large-scale linear algebra and simulating complex quantum systems, but potentially require…

We introduce an optimisation method for variational quantum algorithms and experimentally demonstrate a 100-fold improvement in efficiency compared to naive implementations. The effectiveness of our approach is shown by obtaining…

Variational quantum eigensolver~(VQE) typically optimizes variational parameters in a quantum circuit to prepare eigenstates for a quantum system. Its applications to many problems may involve a group of Hamiltonians, e.g., Hamiltonian of a…

Quantum Physics · Physics 2021-01-19 Zhan-Hao Yuan , Tao Yin , Dan-Bo Zhang

Measuring the expectation value of the molecular electronic Hamiltonian is one of the challenging parts of the variational quantum eigensolver. A widely used strategy is to express the Hamiltonian as a sum of measurable fragments using…

Quantum Physics · Physics 2023-01-04 Seonghoon Choi , Ignacio Loaiza , Artur F. Izmaylov

We present quantum algorithms, for Hamiltonians of linear combinations of local unitary operators, for Hamiltonian matrix-vector products and for preconditioning with the inverse of shifted reduced Hamiltonian operator that contributes to…

Quantum Physics · Physics 2020-09-09 Zhiyong Zhang

Classical simulation of real-space quantum dynamics is challenging due to the exponential scaling of computational cost with system dimensions. Quantum computer offers the potential to simulate quantum dynamics with polynomial complexity;…

Quantum Physics · Physics 2021-10-13 Chee-Kong Lee , Chang-Yu Hsieh , Shengyu Zhang , Liang Shi

Measuring expectation values of observables is an essential ingredient in variational quantum algorithms. A practical obstacle is the necessity of a large number of measurements for statistical convergence to meet requirements of precision,…

Quantum Physics · Physics 2022-09-07 Masaya Kohda , Ryosuke Imai , Keita Kanno , Kosuke Mitarai , Wataru Mizukami , Yuya O. Nakagawa

Variational quantum algorithms (VQAs) represent a promising approach to utilizing current quantum computing infrastructures. VQAs are based on a parameterized quantum circuit optimized in a closed loop via a classical algorithm. This hybrid…

Quantum Physics · Physics 2024-04-10 David Fitzek , Robert S. Jonsson , Werner Dobrautz , Christian Schäfer

Variational quantum eigensolver (VQE) is demonstrated to be the promising methodology for quantum chemistry based on near-term quantum devices. However, many problems are yet to be investigated for this methodology, such as the influences…

Chemical Physics · Physics 2021-01-18 Xian-Hu Zha , Chao Zhang , Dengdong Fan , Pengxiang Xu , Shiyu Du , Rui-Qin Zhang , Chen Fu

Obtaining precise estimates of quantum observables is a crucial step of variational quantum algorithms. We consider the problem of estimating expectation values of molecular Hamiltonians, obtained on states prepared on a quantum computer.…

Quantum Physics · Physics 2020-06-30 Charles Hadfield , Sergey Bravyi , Rudy Raymond , Antonio Mezzacapo

Simulating quantum many-body systems is crucial for advancing physics but poses substantial challenges for classical computers. Quantum simulations overcome these limitations, with analog simulators offering unique advantages over digital…

Quantum Physics · Physics 2025-01-30 Rui-Cheng Guo , Yanwu Gu , Dong E. Liu

Protein folding -- the problem of predicting the spatial structure of a protein given its sequence of amino-acids -- has attracted considerable research effort in biochemistry in recent decades. In this work, we explore the potential of…

Quantum Physics · Physics 2022-04-06 Sami Boulebnane , Xavier Lucas , Agnes Meyder , Stanislaw Adaszewski , Ashley Montanaro

Variational Quantum Eigensolver (VQE) algorithm is one of few approaches where the hope for near-term quantum advantage concentrates. However, they face challenges connected with measurement stochastic noise, barren plateaus, and…

Quantum Physics · Physics 2025-08-20 Ijaz Ahamed Mohammad , Yury Chernyak , Martin Plesch

Characterizing noisy quantum devices requires methods for learning the underlying quantum Hamiltonian which governs their dynamics. Often, such methods compare measurements to simulations of candidate Hamiltonians, a task which requires…

Quantum Physics · Physics 2021-10-13 Assaf Zubida , Elad Yitzhaki , Netanel H. Lindner , Eyal Bairey

We propose an efficient and almost optimal scheme for measuring molecular Hamiltonians in quantum chemistry on quantum computers, which requires $2N^2$ distinct measurements in the leading order with $N$ being the number of molecular…

Quantum Physics · Physics 2024-04-02 Wataru Inoue , Koki Aoyama , Yusuke Teranishi , Keita Kanno , Yuya O. Nakagawa , Kosuke Mitarai

Highly accurate and robust control of quantum operations is vital for the realization of error-correctible quantum computation. In this paper, we show that the robustness of high-precision controls can be remarkably enhanced through…

Quantum Physics · Physics 2021-07-28 Xiaozhen Ge , Re-Bing Wu
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