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We study the phase space structures that control the transport in a classical Hamiltonian model for a chemical reaction. This model has been proposed to study the yield of products in an ultracold exothermic reaction. In the considered…

Chaotic Dynamics · Physics 2021-01-04 Francisco Gonzalez Montoya , Stephen Wiggins

We used for the first time the method of periodic orbit dividing surfaces in a non-integrable Hamiltonian system with three degrees of freedom. We have studied the structure of these four dimensional objects in the five dimensional phase…

Chaotic Dynamics · Physics 2022-05-11 Matthaios Katsanikas , Stephen Wiggins

The periodic-orbit theory based on the improved stationary-phase method within the phase-space path integral approach is presented for the semiclassical description of the nuclear shell structure, concerning the main topics of the fruitful…

Nuclear Theory · Physics 2017-03-08 A. G. Magner , M. V. Koliesnik , K. Arita

We consider an $\varepsilon$-periodic ($\varepsilon\to 0$) tubular structure, modelled as a magnetic Laplacian on a metric graph, which is periodic along a single axis. We show that the corresponding Hamiltonian admits norm-resolvent…

Mathematical Physics · Physics 2024-02-29 Alexander V. Kiselev , Kirill Ryadovkin

Modern materials are often synthesized or operated in complex chemical environments, where there can be numerous elemental species, competing phases, and reaction pathways. When analyzing reactions using the Gibbs free energy, which has a…

Materials Science · Physics 2024-04-10 Jiadong Chen , Matthew J. Powell-Palm , Wenhao Sun

We present an analytical calculation of periodic orbits in the homogeneous quartic oscillator potential. Exploiting the properties of the periodic Lam{\'e} functions that describe the orbits bifurcated from the fundamental linear orbit in…

Chaotic Dynamics · Physics 2009-11-07 M. Brack , S. N. Fedotkin , A. G. Magner , M. Mehta

Background: In the last few decades quantum phase transitions have been of great interest in Nuclear Physics. In this context, two-fluid algebraic models are ideal systems to study how the concept of quantum phase transition evolves when…

Nuclear Theory · Physics 2016-04-06 J. E. García-Ramos , P. Pérez-Fernandez , J. M Arias , E. Freire

We study the structure of the phase diagram for systems consisting of 2- and 3- level particles dipolarly interacting with a 1-mode electromagnetic field, inside a cavity, paying particular attention to the case of a finite number of…

Quantum Physics · Physics 2015-02-04 Eduardo Nahmad-Achar , Sergio Cordero , Octavio Castaños , Ramón López-Peña

We investigate how the phase space structure of a 3D autonomous Hamiltonian system evolves across a series of successive 2D and 3D pitchfork and period-doubling bifurcations, as the transition of the parent families of periodic orbits (POs)…

We investigate the dynamics in the logarithmic galactic potential with an analytical approach. The phase-space structure of the real system is approximated with resonant detuned normal forms constructed with the method based on the Lie…

Astrophysics · Physics 2009-11-13 Cinzia Belmonte , Dino Boccaletti , Giuseppe Pucacco

Nonadiabatic dynamical processes are one of the most important quantum mechanical phenomena in chemical, materials, biological, and environmental molecular systems, where the coupling between different electronic states is either inherent…

Chemical Physics · Physics 2022-05-24 Jian Liu , Xin He , Baihua Wu

We use so-called geometrical approach in description of transition from regular motion to chaotic in Hamiltonian systems with potential energy surface that has several local minima. Distinctive feature of such systems is coexistence of…

Chaotic Dynamics · Physics 2007-05-23 V. P. Berezovoj , Yu. L. Bolotin , G. I. Ivashkevych

The escape mechanism of the four hill potential is explored. A thorough numerical investigation takes place in several types of two-dimensional planes and also in a three-dimensional subspace of the entire four-dimensional phase space in…

Chaotic Dynamics · Physics 2017-09-28 Euaggelos E. Zotos

Nonintegrable dynamical systems have complex structures in their phase space. Motion of a test charged particle in a dipole magnetic field can be reduced to a 2 degree-of-freedom (2 d.o.f.) nonintegrable Hamiltonian system. We carried out a…

Dynamical Systems · Mathematics 2023-02-15 Hanrui Pang , Siming Liu , Rong Liu

This paper studies a class of $1\frac12$-degree-of-freedom Hamiltonian systems with a slowly varying phase that unfolds a Hamiltonian pitchfork bifurcation. The main result of the paper is that there exists an order of…

Dynamical Systems · Mathematics 2015-06-04 Kristian Uldall Kristiansen

Reaction rates of chemical reactions under nonequilibrium conditions can be determined through the construction of the normally hyperbolic invariant manifold (NHIM) [and moving dividing surface (DS)] associated with the transition state…

The transformation of a system from one state to another is often mediated by a bottleneck in the system's phase space. In chemistry these bottlenecks are known as \emph{transition states} through which the system has to pass in order to…

Chaotic Dynamics · Physics 2015-06-15 Ünver Çiftçi , Holger Waalkens

We study the closed Hamiltonian dynamics of a free particle moving on a ring, over one section of which it interacts linearly with a single harmonic oscillator. On the basis of numerical and analytical evidence, we conjecture that at small…

Chaotic Dynamics · Physics 2007-05-23 Stephan De Bievre , Paul E. Parris , Alex A. Silvius

An analytic reversible Hamiltonian system with two degrees of freedom is studied in a neighborhood of its symmetric heteroclinic connection made up of a symmetric saddle-center, a symmetric orientable saddle periodic orbit lying in the same…

Dynamical Systems · Mathematics 2021-02-24 L. M. Lerman , K. N. Trifonov

We present a general review of the bifurcation sequences of periodic orbits in general position of a family of resonant Hamiltonian normal forms with nearly equal unperturbed frequencies, invariant under $Z_2 \times Z_2$ symmetry. The rich…

Dynamical Systems · Mathematics 2016-06-28 Antonella Marchesiello , Giuseppe Pucacco