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We study the electronic structure and dynamical correlations in antiferromagnetic BiFeO$_3$, a prototypical room-temperature multiferroic, using a variety of static and dynamical first-principles methods. Conventional static Hubbard…

Strongly Correlated Electrons · Physics 2025-12-01 Yihan Wu , Mario Caserta , Tommaso Chiarotti , Nicola Marzari

Using \emph{ab initio} band structure and DFT+dynamical mean-field theory methods we examine the effects of electron-electron interactions on the electronic structure, magnetic state, and structural phase stability of the recently…

Strongly Correlated Electrons · Physics 2026-01-26 I. V. Leonov

X-ray absorption spectroscopy (XAS), optical reflectance spectroscopy, and the Hall effect measurements were used to investigate the electronic structure in La_0.7Ce_0.3MnO_3 thin films (LCeMO). The XAS results are consistent with those…

Strongly Correlated Electrons · Physics 2007-05-23 W. J. Chang , J. Y. Tsai , H. -T. Jeng , J. -Y. Lin , Kenneth Y. -J. Zhang , H. L. Liu , J. M. Lee , J. M. Chen , K. H. Wu , T. M. Uen , Y. S. Gou , J. Y. Juang

In this paper, density functional theory calculations are used to explore the electronic and atomic reconstruction at interfaces between III-III/I-V oxides. In particular, at these interfaces, two dimensional electron gases (2DEGs) with…

Materials Science · Physics 2012-06-06 Valentino R. Cooper

We use x-ray absorption spectroscopy to investigate the local structure and electronic properties of bulk La$_{1-y}$Sr$_{y}$Co$_{1-x}$Nb$_x$O$_3$ ($y=$ 2$x$ as LSCNO and $y=$ 0 as LCNO) samples. The x-ray absorption near-edge spectra…

Materials Science · Physics 2021-04-23 Rishabh Shukla , Ajay Kumar , Ravi Kumar , S. N. Jha , R. S. Dhaka

We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…

La$_3$Ni$_2$O$_7$, a bilayer nickelate with Ruddlesden-Popper structure, undergoes a pressure-induced structural transition from a tilted Amam phase to an untilted Fmmm (or I4/mmm) phase near 10-15 GPa, concomitant with the emergence of…

This study presents an \textit{ab initio} investigation of the XANES spectra at the aluminum K edge for three compounds: Al$_2$O$_3$, AlF$_3$ and AlCl$_3$, where the Al atoms share the same oxidation state~(III) and are coordinated in an…

Materials Science · Physics 2024-11-14 Newman Amoyaw , Abezu Agegnehu , Francesco Sottile , Matteo Gatti , M. Laura Urquiza

The influence of atomic vibrations on x-ray absorption near edge structure (XANES) is calculated by assuming that vibrational energies are small with respect to the instrumental resolution. The resulting expression shows that, at the…

Materials Science · Physics 2010-07-26 Christian Brouder , Delphine Cabaret , Amélie Juhin , Philippe Sainctavit

Transition metal oxides exhibit a wide range of tunable electronic properties arising from the complex interplay of charge, spin, and lattice degrees of freedom, governed by their $d$ orbital configurations, making them particularly…

Recent studies of La$_3$Ni$_2$O$_7$ have identified a bilayer (2222) structure and an unexpected alternating monolayer-trilayer (1313) structure, both of which feature signatures of superconductivity near 80 K under high pressures. Using…

First principles calculations were performed to study the ground state electronic properties of BaFeO3 (BFO) within the density functional theory (DFT). Adopting generalized gradient approximation (GGA) exchange and correlation functional…

Materials Science · Physics 2007-05-23 Hong-Jian Feng , Fa-Min Liu

We report a temperature-composition phase diagram for the chemically disordered and CeO2-LA2O3 high entropy oxides (HEOs), where LA denotes equimolar Y, La, Sm, and Pr, delineating stability regions for bixbyite, disordered fluorite, and…

Taking advantage of the large electron escape depth of soft x-ray angle resolved photoemission spectroscopy we report electronic structure measurements of (111)-oriented [LaNiO3/LaMnO3] superlattices and LaNiO3 epitaxial films. For thin…

On the basis of density functional theory electronic band structure calculations using the augmented spherical wave method, the electronic and magnetic properties of the orthorhombic and tetragonal phases of Ca3Mn2O7 were investigated and…

Materials Science · Physics 2007-08-02 S. F. Matar , V. Eyert , A. Villesuzanne , M. -H. Whangbo

Electronic structures of multiferroic RMnO$_3$ (R=Y, Er) have been investigated by employing photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS). We have found that Mn ions in RMnO$_3$ are in the trivalent high-spin…

Materials Science · Physics 2007-05-23 J. -S. Kang , S. W. Han , J. -G. Park , S. C. Wi , S. S. Lee , G. Kim , H. J. Song , H. J. Shin , W. Jo , B. I. Min

Using the hybrid exchange-correlation functional within the density-functional theory, we have systematically investigated the structural and electronic properties of MO (M = Be, Mg, Ca, Sr, Ba, Zn, Cd) in binary rocksalt (B1), zincblende…

Materials Science · Physics 2019-03-19 Jinying Yu , Mingke Zhang , Zihan Zhang , Shangwei Wang , Yelong Wu

The conducting quasi-two dimensional electron system (q2DES) formed at the interface between LaAlO3 and SrTiO3 band insulators is confronting the condensed matter physics community with new paradigms. While the mechanism for the formation…

Materials Science · Physics 2014-09-11 M. Salluzzo

HfO$_2$-based ferroelectrics have emerged as promising materials for advanced nanoelectronics, with their robust polarization and silicon compatibility making them ideal for high-density, non-volatile memory applications. Oxygen vacancies,…

Materials Science · Physics 2026-01-06 Yudi Yang , Wooil Yang , Young-Woo Son , Shi Liu

Recently, it was established that a two-dimensional electron system can arise at the interface between two oxide insulators LaAlO3 and SrTiO3. This paradigmatic example exhibits metallic behaviour and magnetic properties between…

Strongly Correlated Electrons · Physics 2016-11-28 I. I. Piyanzina , Yu. V. Lysogorskiy , I. I. Varlamova , A. G. Kiiamov , T. Kopp , V. Eyert , O. V. Nedopekin , D. A. Tayurskii
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