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We survey the landscape of binary hydrides across the entire periodic table from 10 to 500 GPa using a crystal structure prediction method. Building a critical temperature ($T_c$) model, with inputs arising from density of states…

Superconductivity · Physics 2021-08-11 Alice M. Shipley , Michael J. Hutcheon , Richard J. Needs , Chris J. Pickard

We perform a large scale study of conventional superconducting materials using a machine-learning accelerated high-throughput workflow. We start by creating a comprehensive dataset of around 7000 electron-phonon calculations performed with…

Superconductivity · Physics 2023-07-21 Tiago F. T. Cerqueira , Antonio Sanna , Miguel A. L. Marques

Inspired by recent predictions of superconductivity in B-C framework clathrates, we employ density functional theory to explore potential superconductors among hexagonal hydride-substituted compounds with compositions XB$_8$C, XB$_7$C$_2$,…

Superconductivity · Physics 2025-03-11 Bin Li , Yuxiang Fan , Chuanhui Yin , Junjie Zhai , Cong Zhu , Zhisi Cao , Jie Cheng , Shengli Liu

Boron carbon compounds have been shown to have feasible superconductivity. In our earlier paper [Zheng et al., Phys. Rev. B 107, 014508 (2023)], we identified a new conventional superconductor of LiB3C at 100 GPa. Here, we aim to extend the…

Inspired by the first boron-carbon (B-C) clathrate SrB$_3$C$_3$ and the ternary borohydride KB$_2$H$_8$ [Miao et al., Phys. Rev. B 104 L100504 (2021)], we have performed first-principles density functional theory calculations of the…

Superconductivity · Physics 2024-05-24 Bin Li , Yulan Cheng , Cong Zhu , Jie Cheng , Shengli Liu

A high-throughput screening using density functional calculations is performed to search for stable boride superconductors from the existing materials database. The workflow employs the fast frozen phonon method as the descriptor to…

Materials Science · Physics 2024-04-30 Shiya Chen , Zepeng Wu , Zhen Zhang , Shunqing Wu , Kai-Ming Ho , Vladimir Antropov , Yang Sun

A multitude of observed boron-based materials have outstanding superconducting, mechanical, and refractory properties. Yet, the structure, the composition, and the very existence of some reported metal boride (M-B) compounds have been a…

Materials Science · Physics 2014-10-03 A. G. Van Der Geest , A. N. Kolmogorov

Metal borides have been considered as potential high-temperature superconductors since the discovery of record-holding 39 K superconductivity in bulk MgB2. In this work, we identified a superconducting yet thermodynamically stable F43m…

Superconductivity · Physics 2023-10-24 Xin Yang , Wenbo Zhao , Liang Ma , Wencheng Lu , Xin Zhong , Yu Xie , Hanyu Liu , Yanming Ma

We identify a new family of boron-rich compounds consisting of interconnected B$_{12}$ icosahedra, and electropositive guest atoms ($X$) in interstitial sites. These structures were found through first-principles crystal structure…

Superconductivity · Physics 2026-05-15 Simone Di Cataldo , Antonio Sanna , Lilia Boeri

Crystal structure searching and ab initio calculations have been used here to explore low-energy structures of boron carbides under high pressure. Under pressures of 85-110 GPa, a metastable B6C with R-3m symmetry is found to be…

Materials Science · Physics 2018-01-01 Kang Xia , Mengdong Ma , Cong Liu , Hao Gao , Qun Chen , Julong He , Jian Sun , Hui-Tian Wang , Yongjun Tian , Dingyu Xing

Hydrogen-rich compounds have been extensively studied both theoretically and experimentally in the quest for novel high-temperature superconductors. Reports on sulfur-hydride attaining metallicity under pressure and exhibiting…

We investigate the superconductivity of carbon compounds with a sodalite structure, which are similar to hydrogen compounds showing the high-temperature superconductivity. A systematic analysis by first-principles calculations is carried…

Superconductivity · Physics 2022-04-28 Kazuhiro Sano , Yoshimi Masuda , Hiroki Ito

We present a workflow that iteratively combines \textit{ab-initio} calculations with a machine-learning (ML) guided search for superconducting compounds with both dynamical stability and instability from imaginary phonon modes, the latter…

Superconductivity · Physics 2026-03-09 Niraj K. Nepal , Lin-Lin Wang

Motivated by advances in hydrogen-rich superconductors in the past decades, we conducted variable-composition structural searches in Mo-H binary system at high pressure. A new composition-pressure phase diagram of thermodynamically stable…

Superconductivity · Physics 2024-01-31 Aiqin Yang , Xiangru Tao , Yundi Quan , Peng Zhang

The search for room-temperature superconductors is a major challenge in modern physics. The discovery of copper-oxide superconductors in 1986 brought hope but also revealed complex mechanisms that are difficult to analyze and compute. In…

Materials Science · Physics 2024-09-26 Shiya Chen , Feng Zheng , Zhen Zhang , Shunqing Wu , Kai-Ming Ho , Vladimir Antropov , Yang Sun

Two-dimensional boron structures, due to the diversity of properties, attract great attention because of their potential applications in nanoelectronic devices. A series of \ce{TiB_x} ($4\leq x \leq 11$) monolayers are efficiently…

Chemical Physics · Physics 2020-08-26 Jason Yu , Jihai Liao , Yujun Zhao , Yinchang Zhao , Xiaobao Yang

Recent research on compressed binary hydrides have unveiled the potential for achieving superconductivity at near-room-temperature. Nevertheless, the available decision-making procedures standing behind the selection of constituent elements…

Superconductivity · Physics 2024-09-25 Izabela A. Wrona , Pawel Niegodajew , Artur P. Durajski

High-temperature superconductivity occurs in strongly correlated materials such as copper oxides and iron-based superconductors. Numerous experimental and theoretical works have been done to identify the key parameters that induce…

Superconductivity · Physics 2023-05-02 Kota Ido , Yuichi Motoyama , Kazuyoshi Yoshimi , Takahiro Misawa

We report a high-throughput ab-initio study of the thermodynamic and superconducting proper- ties of the recently synthesized XB$_3$C$_3$ clathrates. These compounds, in which boron and carbon form a sponge-like network of interconnected…

Superconductivity · Physics 2022-03-14 Simone Di Cataldo , Shadi Qulaghasi , Giovanni B. Bachelet , Lilia Boeri

Searching for superconducting hydrides has so far largely focused on finding materials exhibiting the highest possible critical temperatures ($T_c$). This has led to a bias towards materials stabilised at very high pressures, which…

Superconductivity · Physics 2020-04-29 Michael J. Hutcheon , Alice M. Shipley , Richard J. Needs
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