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The second law of ordinary thermodynamics and the second law of steady state thermodynamics, as proposed by Oono and Paniconi, are investigated from the microscopic point of view for the open quantum system. Based on the H-theorem of…

Statistical Mechanics · Physics 2007-05-23 Satoshi Yukawa

Molecular dynamics simulations provide theoretical insight into the microscopic behavior of materials in condensed phase and, as a predictive tool, enable computational design of new compounds. However, because of the large temporal and…

Chemical Physics · Physics 2020-06-18 Wujie Wang , Rafael Gómez-Bombarelli

This article sets up a formalism to describe stochastic thermodynamics for driven out-of-equilibrium open quantum systems. A stochastic Schr\"odinger equation allows to construct quantum trajectories describing the dynamics of the system…

Statistical Mechanics · Physics 2016-10-17 Cyril Elouard , Alexia Auffèves , Maxime Clusel

The stochastic dissipative Schrodinger equation is derived for an open quantum system consisting of a sub-system able to exchange energy with a thermal reservoir. The resultant evolution of the wave function also gives the evolution of the…

Statistical Mechanics · Physics 2014-06-03 Phil Attard

Several approximation procedures, such as the full or partial rotating-wave, time-averaging, and geometric-arithmetic approximations, have been proposed to derive Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) generators from the Born-Markov…

Statistical Mechanics · Physics 2026-05-29 Teruhiro Ikeuchi , Takashi Mori

We derive a coarse-grained description of the dynamics of a nanoparticle immersed in an isothermal simple fluid by performing a systematic coarse graining of the underlying microscopic dynamics. As coarse-grained or relevant variables we…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Pep Español , Aleksandar Donev

We investigate the effect of coarse-graining on the energetics properties of a system, focusing on entropy production. As a case of study, we consider a one-dimensional colloidal particle in contact with a thermal bath, moving in a…

Statistical Mechanics · Physics 2021-09-08 Pierpaolo Bilotto , Lorenzo Caprini , Angelo Vulpiani

The Hamiltonian evolution of an isolated classical system is reversible, yet the second law of thermodynamics states that its entropy can only increase. This has confounded attempts to identify a `Microscopic Dynamical Entropy' (MDE), by…

Statistical Mechanics · Physics 2025-03-17 Mingnan Ding , Michael E. Cates

This article provides non-trivial technical ingredients for the article "The quantitative hydrodynamic limit of the Kawasaki dynamics" by the same authors. In that work a quantitative version of the hydrodynamic limit is deduced using a…

Probability · Mathematics 2018-07-30 Deniz Dizdar , Georg Menz , Felix Otto , Tianqi Wu

A thermodynamically consistent phase-field model is developed to study the non-isothermal grain coalescence during the sintering process, with a potential application to the simulation in unconventional sintering techniques, e.g. spark…

Materials Science · Physics 2018-06-08 Yangyiwei Yang , Min Yi , Bai-Xiang Xu , Long-Qing Chen

We analyze an autonomous micro-engine as a closed quantum mechanical system, including the work it performs and the fuel it consumes. Our model system shows by example that it is possible to transfer energy steadily and spontaneously…

Statistical Mechanics · Physics 2013-04-12 Lukas Gilz , Eike P. Thesing , James R. Anglin

We present the stochastic thermodynamics analysis of an open quantum system weakly coupled to multiple reservoirs and driven by a rapidly oscillating external field. The analysis is built on a modified stochastic master equation in the…

Statistical Mechanics · Physics 2015-05-12 Gregory Bulnes Cuetara , Andreas Engel , Massimiliano Esposito

We show that the dynamics of a driven quantum system weakly coupled to a finite reservoir can be approximated by a sequence of Landau-Zener transitions if the level spacing of the reservoir is large enough. This approximation can be…

Statistical Mechanics · Physics 2019-05-01 Juzar Thingna , Massimiliano Esposito , Felipe Barra

Classical thermodynamics is a theory based on coarse-graining, meaning that the thermodynamic variables arise from discarding information related to the microscopic features of the system at hand. In quantum mechanics, however, where one…

Quantum Physics · Physics 2026-04-13 T. Pernambuco , L. C. Céleri

We develop a perturbation theory of quantum (and classical) master equations with slowly varying parameters, applicable to systems which are externally controlled on a time scale much longer than their characteristic relaxation time. We…

Quantum Physics · Physics 2017-08-09 Vasco Cavina , Andrea Mari , Vittorio Giovannetti

Master equation could be applied to model various kinds of biochemical systems. A general theory for its time-dependent nonequilibrium thermodynamics is rigorously derived. We not only introduce a concept of general internal energy, but…

Statistical Mechanics · Physics 2009-04-16 Hao Ge

The study of open quantum systems often relies on approximate master equations derived under the assumptions of weak coupling to the environment. However when the system is made of several interacting subsystems such a derivation is in many…

Quantum Physics · Physics 2018-11-20 G. De Chiara , G. Landi , A. Hewgill , B. Reid , A. Ferraro , A. J. Roncaglia , M. Antezza

Thermodynamics is based on a coarse-grained approach, from which its fundamental variables emerge, effectively erasing the complicate details of the microscopic dynamics within a macroscopic system. The strength of Thermodynamics lies in…

Quantum Physics · Physics 2025-04-17 Gabriel Fernandez Ferrari , Łukasz Rudnicki , Lucas Chibebe Céleri

Coarse-graining techniques play a central role in reducing the complexity of stochastic models, and are typically characterised by a mapping which projects the full state of the system onto a smaller set of variables which captures the…

Probability · Mathematics 2023-09-28 Bastian Hilder , Upanshu Sharma

We consider a generalisation of thermodynamics that deals with multiple conserved quantities at the level of individual quantum systems. Each conserved quantity, which, importantly, need not commute with the rest, can be extracted and…

Quantum Physics · Physics 2016-07-14 Yelena Guryanova , Sandu Popescu , Anthony J. Short , Ralph Silva , Paul Skrzypczyk
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