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We studied the crystal and magnetic structure of the La$_{1-x}$Ca$_{x}$MnO$_{3}$ compound for $(0.11\leq x\leq 0.175)$ using stoichiometric samples. For $x<0.13$ the system's ground state is insulating canted antiferromagnetic. For $0.13\le…

Strongly Correlated Electrons · Physics 2009-11-11 M. Pissas , I. Margiolaki , G. Papavassiliou , D. Stamopoulos , D. Argyriou

Structural modulation is a key ingredient behind the extraordinary (magneto)elastic response of Ni-Mn-Ga martensite, yet its link to fine twinned microstructure and twin-boundary supermobility remains unresolved. Here we analyse martensitic…

MnSb$_{2}$O$_{6}$ is based on the structural chiral $P$321 space group #150 where the magnetic Mn$^{2+}$ moments ($S=5/2$, $L\approx 0$) order antiferromagnetically at $T_\mathrm{N}=12$ K. Unlike the related iron based langasite…

We discuss relative roles played by the magnetic inversion symmetry breaking and the ferroelectric (FE) atomic displacements in the multiferroic state of YMnO3. For these purposes we derive a realistic low-energy model, using results of…

Materials Science · Physics 2012-10-12 I. V. Solovyev , M. V. Valentyuk , V. V. Mazurenko

The recent discovery of superconductivity in infinite layer thin films and bulk Ruddlesden-Popper nickelates has stimulated the investigation of other predicted properties of these materials. Among them, the existence of magnetism-driven…

Based on the relativistic spin-polarized density functional theory calculations we investigate the crystal structure, electronic and magnetic properties of a family MnPn2Ch4 compounds, where pnictogen metal atoms (Pn) are Sb and Bi;…

Materials Science · Physics 2018-09-28 S. V. Eremeev , M. M. Otrokov , E. V. Chulkov

Three solid solutions of [CH$_3$NH$_3$]Co$_x$Ni$_{1-x}$(HCOO)$_3$, with $x$ = 0.25 (1), 0.50 (2) and 0.75 (3), were synthesized and their nuclear structures and magnetic properties were characterized using single crystal neutron diffraction…

Strongly Correlated Electrons · Physics 2024-08-06 Madeleine Geers , Oscar Fabelo , Matthew J. Cliffe , Laura Cañadillas-Delgado

The magnetic properties of the two isostructural molecule-based magnets, Ni(NCS)$_{2}$(thiourea)$_{2}$, $S$ = 1, [thiourea = SC(NH$_2$)$_2$] and Co(NCS)$_{2}$(thiourea)$_{2}$, $S$ = 3/2, are characterised using several techniques in order…

We measure the full elastic tensors of Mn$_3$Ge and Mn$_3$Sn as a function of temperature through their respective antiferromagnetic phase transitions. Large discontinuities in the bulk moduli at the N\'eel transitions indicate strong…

Strongly Correlated Electrons · Physics 2024-10-11 Florian Theuss , Sayak Ghosh , Taishi Chen , Oleg Tchernyshyov , Satoru Nakatsuji , B. J. Ramshaw

The short-range organization around Ni atoms in orthorhombic $R$NiO$_{3}$ ($R$=Pr,Nd,Eu) perovskites has been studied over a wide temperature range by Ni K-edge x-ray absorption spectroscopy. Our results demonstrate that two different Ni…

Cooperative Jahn-Teller ordering is well-known to drive the cubic $Fd\overline{3}m$ to tetragonal $I$4$_1$/$amd$ structural distortion in Mn$_3$O$_4$ at 1170 $^{\circ}$C. Further structural distortion occurs in Mn$_3$O$_4$ upon magnetic…

Materials Science · Physics 2014-08-26 Moureen C. Kemei , Jaye K. Harada , Ram Seshadri , Matthew R. Suchomel

We use spherical neutron polarimetry to determine the ground state magnetic structure of Mn3Sn. We find that Mn3Sn adopts an inverse triangular structure with spins parallel to <100> (Type III) rather than spins parallel to <110> (Type IV).…

We report the influence of Ce$^{3+}$ substitution on the magnetic structures and phonon dynamics in SmCrO$_3$ perovskites. Magnetic landscapes are spanned by long-range canted anti-ferromagnetism, AFM with Neel temperatures $\sim$196 K…

Materials Science · Physics 2025-12-30 Shaona Das , Ravi Kiran Dokala , Subhash Thota

KCrF3 represents another prototypical orbital-ordered perovskite, where Cr2+ possesses the same electronic configuration of 3d4 as that of strongly Jahn-Teller distorted Mn3+ in many CMR manganites. The crystal and magnetic structures of…

Strongly Correlated Electrons · Physics 2013-09-30 Y. Xiao , Y. Su , H. -F. Li , C. M. N. Kumar , R. Mittal , J. Persson , A. Senyshyn , K. Gross , Th. Brueckel

The electronic valence state of Mn in Pb(Zr0.2Ti0.8)O3/La0.8Sr0.2MnO3 multiferroic heterostructures is probed by near edge x-ray absorption spectroscopy as a function of the ferroelectric polarization. We observe a temperature independent…

Materials Science · Physics 2010-04-13 C. A. F. Vaz , J. Hoffman , Y. Segal , J. W. Reiner , R. D. Grober , Z. Zhang , C. H. Ahn , F. J. Walker

Antiferromagnetic antiperovskites, of the form Mn$_3B$N ($B$ = Ni, Cu, Zn, Sn, Ir, and Pt), have shown an outstanding behavior in which, giant negative thermal expansion and chiral magnetic structures are intertwined. As such, aiming to…

Materials Science · Physics 2022-09-07 L. Florez-Gomez , W. Ibarra-Hernandez , A. C. Garcia-Castro

Magnetically-driven ferroelectric atomic displacements of the order of 10$^{-3} Angstrom have been observed in orthorhombic (perovskite like) YMnO$_3$ by a single-crystal synchrotron x-ray diffraction. The refined polar structure shows the…

Strongly Correlated Electrons · Physics 2011-08-12 D. Okuyama , S. Ishiwata , Y. Takahashi , K. Yamauchi , S. Picozzi , K. Sugimoto , H. Sakai , M. Takata , R. Shimano , Y. Taguchi , T. Arima , Y. Tokura

We have studied the influence of antiferromagnetic ordering on the local dielectric moments of the MnO_5 and LuO_7 polyhedra by measuring neutron powder diffraction patterns of LuMnO_3 at temperatures near T_N. We show that the coupling is…

Strongly Correlated Electrons · Physics 2009-11-10 Bas B. Van Aken , Thomas T. M. Palstra

A temperature-dependent EXAFS investigation of La{1-x}Ca{x}MnO3 is presented for the concentration range that spans the ferromagnetic-insulator (FMI) to ferromagnetic-metal (FMM) transition region, x = 0.16-0.22. The samples are insulating…

Strongly Correlated Electrons · Physics 2009-11-13 Y. Jiang , F. Bridges , L. Downward , J. J. Neumeier

Here we investigate the temperature evolution of the structural parameters of a potential magnetoelectric material, MnTiO$_{3}$. The experimental results reveal interesting temperature dependence of the $c/a$ ratio and the Mn-O bonds which…

Strongly Correlated Electrons · Physics 2015-05-20 R. K. Maurya , Navneet Singh , S. K. Pandey , R. Bindu
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