Related papers: Long-range Rydberg molecule Rb$_2$: Two-electron \…
The large electric dipole moments associated with highly excited Rydberg states of atoms and molecules make gas-phase samples in these states very well suited to deceleration and trapping using inhomogeneous electric fields. The methods of…
Matter-wave interferometry has been performed with helium atoms in high Rydberg states. In the experiments the atoms were prepared in coherent superpositions of Rydberg states with different electric dipole moments. Upon the application of…
Optically trapped Rydberg atoms are a suitable platform to explore quantum many-body physics mediated by long-range atom--atom interactions that can be engineered through externally applied light fields. However, this approach is limited to…
A ground state atom immersed in the wave function of the valence electron of a Rydberg atom can generate a long-range Rydberg molecule (LRRM). In this work, using the multipole expansion of the electrostatic interaction in prolate…
We calculated the electronic interaction associated with the exchange of an electron between an atom of calcium excited to a Rydberg state ($n\sim 10-15$) and another, neighbouring calcium atom in its ground state. In this range the Rydberg…
We present an accurate theoretical determination of rovibrational energy levels of the hydrogen molecule and its isotopologues in its electronic ground state. We consider all significant corrections to the Born-Oppenheimer approximation,…
Rydberg atoms in dc electric fields acquire static dipole moments. When the atoms are close to a surface producing an inhomogeneous electric field, such as by the adsorbates on an atom chip, depending on the sign of the dipole moment of the…
The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly…
We report the observation of cold Cs Rydberg atom molecules bound at internuclear separations of R~3-9 um. The bound states result from avoided crossings between Rydberg atom pair interaction potentials in an applied electric field. The…
Combining the measured binding energies of four of the most weakly bound rovibrational levels of the $^{87}$Rb$_2$ molecule with the results of two other recent high-precision rubidium experiments, we obtain exceptionally strong constraints…
Rydberg atom arrays operated by a quantum adiabatic principle are among the most promising quantum simulating platforms due to their scalability and long coherence time. From the perspective of combinatorial optimization, they offer an…
In an atomic ensemble, quantum information is typically carried as single collective excitations. It is very advantageous if the creation of single excitations is efficient and robust. Rydberg blockade enables deterministic creation of…
We demonstrate Rydberg blockade due to the charge-dipole interaction between a single Rb atom and a single RbCs molecule confined in optical tweezers. The molecule is formed by magnetoassociation of a Rb+Cs atom pair and subsequently…
Adiabatic potential energy curves of the 3sSigma+, 3tSigma+, 2sPi and 2tPi states correlating for large internuclear distance with the K(4s) + Li(2p) atomic asymptote were calculated. Very good agreement between the calculated and the…
Motivated by a recent experiment on a square-lattice Rydberg atom array realizing a long-range dipolar XY model [Chen et al., Nature (2023)], we numerically study the model's equilibrium properties. We obtain the phase diagram, critical…
We derive a quantum master equation for an atom coupled to a heat bath represented by a charged particle many-body environment. In Born-Markov approximation, the influence of the plasma environment on the reduced system is described by the…
We report the observation of spin-singlet ultra-long range Rydberg butterfly molecules consisting of a ground-state atom bound to a Rydberg atom by $P$-wave scattering of $^{87}$Rb Rydberg electrons from $^{87}$Rb(5s) atoms. A three-photon…
Obtaining full control over the internal and external quantum states of molecules is the central goal of ultracold chemistry and allows for the study of coherent molecular dynamics, collisions and tests of fundamental laws of physics. When…
We propose a method for the determination of the interaction potential of Rydberg atoms. Specifically, we consider a laser-driven Rydberg gas confined in a one-dimensional lattice and demonstrate that the Rydberg atom number after a laser…
We theoretically investigate Rydberg atom pair potentials of Rb atoms in front of a perfectly conducting plate. The pair potentials are perturbed by both the Casimir--Polder potential acting on a single atom and the scattering contribution…