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A general nonequilibrium thermodynamic theory is developed for time-dependent Langevin dynamics, starting from the common definition of nonequilibrium Gibbs entropy. It is shown that the notations appearing in the First and the Second Law…

Statistical Mechanics · Physics 2009-04-15 Hao Ge

Events in mesoscopic systems often take place at first-passage times, as is for instance the case for a colloidal particle that escapes a metastable state. An interesting question is how much work an external agent has done on a particle…

Statistical Mechanics · Physics 2020-02-05 Izaak Neri

We provide a proof of the necessary and sufficient condition on the profile of the temperature, chemical potential, and angular velocity for a charged perfect fluid in dynamic equilibrium to be in thermodynamic equilibrium not only in fixed…

General Relativity and Quantum Cosmology · Physics 2022-03-30 Kai Shi , Yu Tian , Xiaoning Wu , Hongbao Zhang , Chuanjia Zhu

Free energy and entropy are examined in detail from the standpoint of classical thermodynamics. The approach is logically based on the fact that thermodynamic work is mediated by thermal energy through the tendency for nonthermal energy to…

Physics Education · Physics 2015-06-26 Clinton D. Stoner

Motivated by the notion that the mathematics of gravity can be reproduced from a statistical requirement of maximal entropy, we study the consequence of introducing an entropic source term in the Einstein-Hilbert action. For a spatially…

General Relativity and Quantum Cosmology · Physics 2024-03-20 Soumya Chakrabarti

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

We present a conjugate analysis of two different dark energy models investigating both their agreement with recent data and their thermodynamical properties. The successful match with the data allows to both constrain the model parameters…

Cosmology and Nongalactic Astrophysics · Physics 2017-10-11 Vincenzo F. Cardone , Ninfa Radicella , Antonio Troisi

Entanglement is central both to the foundations of quantum theory and, as a novel resource, to quantum information science. The theory of entanglement establishes basic laws, such as the non-increase of entanglement under local operations,…

Quantum Physics · Physics 2008-11-04 Fernando G. S. L. Brandao , Martin B. Plenio

This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…

Quantum Physics · Physics 2015-03-30 David M. Rogers

A general thermodynamic framework is presented for open quantum systems in fixed contact with a thermal reservoir. The first and second law are obtained for arbitrary system-reservoir coupling strengths, and including both factorized and…

Quantum Physics · Physics 2020-04-23 Ángel Rivas

Equilibrium thermodynamics is combined with Jarzynski's irreversible work theorem to quantify the excess entropy produced by irreversible processes. The resulting rectified form of the second law parallels the first law, in the sense that…

Statistical Mechanics · Physics 2007-05-23 Dor Ben-Amotz , J. M. Honig

The connection between gravity and thermodynamics is explored. Examining a perfect fluid in gravitational equilibrium we find that the entropy is extremal only if Einstein's equations are satisfied. Conversely, one can derive part of…

General Relativity and Quantum Cosmology · Physics 2007-05-23 J. Oppenheim

We derive a formulation of the First Law of nonequilibrium thermodynamics for biological information-processing systems by partitioning entropy in the Second Law into microscopic and mesoscopic components and by assuming that natural…

Statistical Mechanics · Physics 2025-11-03 Roger D. Jones , Achille Giacometti , Alan M. Jones

The second law of thermodynamics constitutes a fundamental principle of physics, precluding the existence of perpetual motion machines and providing a natural definition of the arrow of time. Its scope extends across virtually all areas of…

General Relativity and Quantum Cosmology · Physics 2025-10-21 Alejandro Corichi , Omar Gallegos

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

The modern theory of elasticity and the first law of thermodynamics are cornerstones of engineering science that share the concept of reversibility. Engineering researchers have known for four decades that the modern theory violates the…

Soft Condensed Matter · Physics 2019-11-21 Christopher M. Szalwinski

We study two small quantum systems coupled to the same reservoir which is in thermal equilibrium. By studying the particle density and the energy density in the two systems before and after they contact each other, we find that the two…

Statistical Mechanics · Physics 2012-10-12 Pei Wang

We argue that statistical mechanics of systems with relaxation implies breaking the energy function of systems into two having different transformation rules. With this duality the energy approach incorporates the generalized vortex forces.…

General Physics · Physics 2013-05-23 V. E. Shapiro

Thermodynamics is a science concerning the state of a system, whether it is stable, metastable, or unstable. The combined law of thermodynamics derived by Gibbs about 150 years ago laid the foundation of thermodynamics. In Gibbs combined…

Statistical Mechanics · Physics 2023-08-03 Zi-Kui Liu

The thermodynamic equilibrium states of a static thin ring shell in a (2+1)-dimensional flat spacetime is analyzed. Inside the ring the spacetime is flat, whereas outside it is conical flat. The first law of thermodynamics applied to the…

General Relativity and Quantum Cosmology · Physics 2015-06-17 José P. S. Lemos , Gonçalo M. Quinta