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A variant of coupled-cluster theory is described here, wherein the degrees of freedom are fluctuations of fragments between internally correlated states. The effects of intra-fragment correlation on the inter-fragment interaction are…

Chemical Physics · Physics 2019-05-24 Yuhong Liu , Anthony D. Dutoi

Finding the ground state of a Hamiltonian system is of great significance in many-body quantum physics and quantum chemistry. We propose an improved iterative quantum algorithm to prepare the ground state of a Hamiltonian. The crucial point…

Quantum Physics · Physics 2022-10-25 Jin-Min Liang , Qiao-Qiao Lv , Shu-Qian Shen , Ming Li , Zhi-Xi Wang , Shao-Ming Fei

Utilizing quantum computer to investigate quantum chemistry is an important research field nowadays. In addition to the ground-state problems that have been widely studied, the determination of excited-states plays a crucial role in the…

We present a formulation and implementation of second-order quasidegenerate N-electron valence perturbation theory (QDNEVPT2) that provides a balanced and accurate description of spin-orbit coupling and dynamic correlation effects in…

Chemical Physics · Physics 2024-06-19 Rajat Majumder , Alexander Yu. Sokolov

Efficient simulation of quantum dynamics with time-dependent Hamiltonians is important not only for time-varying systems but also for time-independent Hamiltonians in the interaction picture. Such simulations are more challenging than their…

Quantum Physics · Physics 2025-09-09 Di Fang , Diyi Liu , Shuchen Zhu

Recent advances in analog and digital quantum-simulation platforms have enabled exploration of the spectrum of entanglement Hamiltonians via variational algorithms. In this work we analyze the convergence properties of the variationally…

Quantum Physics · Physics 2025-05-16 Yanick S. Kind , Benedikt Fauseweh

The perturbation method is an approximation scheme with a solvable leading order. The standard way is to choose a non-interacting sector for the leading order. The adaptive perturbation method improves the solvable part by using all…

High Energy Physics - Theory · Physics 2022-10-17 Chen-Te Ma

If a quantum system interacts with the environment, then the Hamiltonian acquires a correction known as the Lamb-shift term. There are two other corrections to the Hamiltonian, related to the stationary state. Namely, the stationary state…

Quantum Physics · Physics 2025-01-28 Marcin Łobejko , Marek Winczewski , Gerardo Suárez , Robert Alicki , Michał Horodecki

A matrix model of an asymptotically free theory with a bound state is solved using a perturbative similarity renormalization group for hamiltonians. An effective hamiltonian with a small width, calculated including the first three terms in…

High Energy Physics - Theory · Physics 2007-05-23 Stanislaw D. Glazek

We study the time evolution of the expectation value of the anharmonic oscillator coordinate in a coherent state as a toy model for understanding the semiclassical solutions in quantum field theory. By using the deformation quantization…

High Energy Physics - Theory · Physics 2015-06-26 N. C. Dias , A. Mikovic , J. N. Prata

An alternative perturbative expansion in quantum mechanics which allows a full expression of the scaling arbitrariness is introduced. This expansion is examined in the case of the anharmonic oscillator and is conveniently resummed using a…

High Energy Physics - Theory · Physics 2015-06-26 J. M. Prats

It is widely believed that mean-field theory is exact for a wide-range of classical long-range interacting systems. Is this also true once quantum fluctuations have been accounted for? As a test case we study the Hamiltonian Mean Field…

Quantum Gases · Physics 2020-02-05 Ryan Plestid , James Lambert

Calculating the action and the interaction Hamiltonian at higher orders in cosmological perturbation theory is a cumbersome task. We employ the formalism of EFT of inflation in the decoupling limit for single-field ultra slow-roll (USR)…

Cosmology and Nongalactic Astrophysics · Physics 2026-05-15 Hassan Firouzjahi , Bahar Nikbakht

Quantum computation is one of the most promising new paradigms for the simulation of physical systems composed of electrons and atomic nuclei, with applications in chemistry, solid-state physics, materials science, and molecular biology.…

Quantum Physics · Physics 2024-11-05 Jakob Günther , Alberto Baiardi , Markus Reiher , Matthias Christandl

We demonstrate the importance of symmetries in Variational Quantum Eigensolver (VQE) algorithms to prepare the ground or specific low-lying states of quantum Hamiltonians. We examine two spin problems, one with random all-to-all couplings…

Quantum Physics · Physics 2025-10-09 Ivana Miháliková , Joseph Carlson , Duff Neill , Ionel Stetcu

The sub-volume scaling of the entanglement entropy with the system's size, $n$, has been a subject of vigorous study in the last decade [1]. The area law provably holds for gapped one dimensional systems [2] and it was believed to be…

Quantum Physics · Physics 2017-01-17 Ramis Movassagh , Peter W. Shor

We consider two perturbative schemes to calculate excitation energies, each employing the Kohn-Sham Hamiltonian as the unperturbed system. Using accurate exchange-correlation potentials generated from essentially exact densities and their…

Condensed Matter · Physics 2009-10-30 Claudia Filippi , C. J. Umrigar , X. Gonze

We study the dynamical properties of the canonical ordered phase of the Hamiltonian mean-field (HMF) model, in which $N$ particles, globally-coupled via pairwise attractive interactions, form a rotating cluster. Using a combination of…

We calculate the action and the interaction Hamiltonians to all orders in perturbation theory in the model of single field inflation with a transient ultra slow-roll phase. Employing the formalism of EFT of inflation, we obtain a compact…

Cosmology and Nongalactic Astrophysics · Physics 2026-05-15 Hassan Firouzjahi , Bahar Nikbakht

For lambda phi^4 models, the introduction of a large field cutoff improves significantly the accuracy that can be reached with perturbative series but the calculation of the modified coefficients remains a challenging problem. We show that…

High Energy Physics - Theory · Physics 2009-11-11 L. Li amd Y. Meurice