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We consider an inextensible, semiflexible polymer or worm-like chain which is confined in the transverse direction by a parabolic potential and subject to a longitudinal force at the ends, so that the polymer is stretched out and…

Soft Condensed Matter · Physics 2015-05-28 Theodore W. Burkhardt

We develop an analytical method for studying the properties of a non-interacting Wormlike Chain (WLC) in confined geometries. The mean field-like theory replaces the rigid constraints of confinement with average constraints, thus allowing…

Soft Condensed Matter · Physics 2009-11-13 Greg Morrison , D. Thirumalai

In this paper, we construct an effective model for the dynamics of an excluded-volume chain under confinement, by extending the formalism of Rouse modes. We make specific predictions about the behavior of the modes for a single polymer…

Soft Condensed Matter · Physics 2009-09-29 Joshua Kalb , Bulbul Chakraborty

We investigate the chain conformation of ring polymers confined to a cylindrical nanochannel using both theoretical analysis and three dimensional Langevin dynamics simulations. We predict that the longitudinal size of a ring polymer scales…

Soft Condensed Matter · Physics 2012-12-06 Junfang Sheng , Kaifu Luo

We present a solution for the Green's function for the general case of a helical wormlike chain with twist-bend coupling, and demonstrate the applicability of our solution for evaluating general structural and mechanical chain properties.…

Soft Condensed Matter · Physics 2024-08-20 Ashesh Ghosh , Kranthi K. Mandadapu , David T. Limmer

We revisit the classical problem of a polymer confined in a slit in both of its static and dynamic aspects. We confirm a number of well known scaling predictions and analyse their range of validity by means of comprehensive Molecular…

Polymer models play the special role of elucidating the elementary features describing the physics of long molecules and become essential to interpret the measurements of their magnitudes. In this work the end-to-end distance of an…

Soft Condensed Matter · Physics 2023-02-23 Alessandro Fiasconaro , Fernando Falo

We present Monte Carlo computer simulations for melts of semiflexible randomly knotted and randomly concatenated ring polymers on the fcc lattice and in slit confinement. Through systematic variation of the slit width at fixed melt density,…

Soft Condensed Matter · Physics 2023-07-06 Mattia Alberto Ubertini , Angelo Rosa

The present paper investigates the extension behavior of a wormlike chain with varied persistence length under the confinement of a cylindrical tube. Based on Odijk theory of a confined polymer chain, we have developed a theory which can…

Biological Physics · Physics 2019-11-05 Ming Li , Jizeng Wang

We present and analyze correlation functions of a main-chain polymer nematic in a continuum worm-like chain description for two types of constraints formalized by the tensorial and vectorial conservation laws, both originating in the…

Soft Condensed Matter · Physics 2017-05-11 Daniel Svensek , Rudolf Podgornik

The endpoint distribution and dynamics of semiflexible fibers is studied by numerical simulation. A brief overview is given over the analytical theory of flexible and semiflexible polymers. In particular, a closed expression is given for…

Soft Condensed Matter · Physics 2013-06-13 Robert D. Groot

The complete knowledge of a theory is encoded in its correlation functions. Thus non-perturbative effects, like confinement in QCD, is necessarily contained in these correlation functions. As a consequence, a number of confinement scenarios…

High Energy Physics - Lattice · Physics 2013-10-31 Tajdar Mufti , Axel Maas

Nanoscale and microscale confinement of biopolymers naturally occurs in cells and has been recently achieved in artificial structures designed for nanotechnological applications. Here, we present an extensive theoretical investigation of…

Soft Condensed Matter · Physics 2007-06-13 Frederik Wagner , Gianluca Lattanzi , Erwin Frey

We propose new polymer models for Monte Carlo simulation and apply them to a polymer chain confined in a relatively thin box which has both curved and flat sides, and show that either an ideal or an excluded-volume chain spends more time in…

Soft Condensed Matter · Physics 2007-05-23 Y. Y. Suzuki , T. Dotera , M. Hirabayashi

We derive the stochastic equations of motion for a tracer that is tightly attached to a semiflexible polymer and confined or agitated by an externally controlled potential. The generalised Langevin equation, the power spectrum, and the…

Soft Condensed Matter · Physics 2011-11-22 Jakob Tómas Bullerjahn , Sebastian Sturm , Lars Wolff , Klaus Kroy

We introduce an efficient, scalable Monte Carlo algorithm to simulate cross-linked architectures of freely-jointed and discrete worm-like chains. Bond movement is based on the discrete tractrix construction, which effects conformational…

Soft Condensed Matter · Physics 2010-12-27 Henry E. Amuasi , Cornelis Storm

We demonstrate that a semiflexible bundle of wormlike chains exhibits a state-dependent bending stiffness that alters fundamentally its scaling behavior with respect to the standard wormlike chain. We explore the equilibrium conformational…

Statistical Mechanics · Physics 2007-07-26 Claus Heussinger , Mark Bathe , Erwin Frey

In this paper, we present a theory to efficiently deal with mechanical properties of heterogeneous polymer chain in free space and the central problem is to evaluate the diffusion equation and orientation-orientation correlation function,…

Biological Physics · Physics 2019-11-05 Ming Li , Jizeng Wang

Motivated by recent nanofluidics experiments, we use Brownian dynamics and Monte Carlo simulations to study the conformation, organization and dynamics of two polymer chains confined to a single box-like cavity. The polymers are modeled as…

Soft Condensed Matter · Physics 2021-05-19 James M. Polson , Desiree A. Rehel

We consider an inextensible, semiflexible polymer or worm-like chain, with persistence length $P$ and contour length $L$, fluctuating in a cylindrical channel of diameter $D$. In the regime $D\ll P\ll L$, corresponding to a long, tightly…

Soft Condensed Matter · Physics 2015-05-19 Theodore W. Burkhardt , Yingzi Yang , Gerhard Gompper
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