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In this work, we address the efficient computation of parameterized systems of linear equations, with possible nonlinear parameter dependence. When the matrix is highly sensitive to the parameters, mean-based preconditioning might not be…

Numerical Analysis · Mathematics 2026-05-29 Wouter Gerrit van Harten , Laura Scarabosio

The Hartree-Fock exchange potential is fundamental for capturing quantum mechanical exchange effects but faces critical challenges in large-scale applications due to its nonlocal and computationally intensive nature. This study introduces a…

Chemical Physics · Physics 2025-09-03 Fei Xu

We consider the uniform approximation of the smallest eigenvalue of a large parameter-dependent Hermitian matrix by that of a smaller counterpart obtained through projections. The projection subspaces are constructed iteratively by means of…

Numerical Analysis · Mathematics 2026-01-16 Mattia Manucci , Emre Mengi , Nicola Guglielmi

We propose a general method for optimally approximating an arbitrary matrix $\mathbf{M}$ by a structured matrix $\mathbf{T}$ (circulant, Toeplitz/Hankel, etc.) and examine its use for estimating the spectra of genomic linkage disequilibrium…

Applications · Statistics 2024-09-10 Chris Salahub , Jeffrey Uhlmann

The problem of completing high-dimensional matrices from a limited set of observations arises in many big data applications, especially, recommender systems. Existing matrix completion models generally follow either a memory- or a…

Machine Learning · Computer Science 2019-09-30 Duc Minh Nguyen , Robert Calderbank , Nikos Deligiannis

We present an efficient implementation of periodic Gaussian density fitting (GDF) using the Coulomb metric. The three-center integrals are divided into two parts by range-separating the Coulomb kernel, with the short-range part evaluated in…

Chemical Physics · Physics 2021-04-08 Hong-Zhou Ye , Timothy C. Berkelbach

Gaussian mixture filters for nonlinear systems usually rely on severe approximations when calculating mixtures in the prediction and filtering step. Thus, offline approximations of noise densities by Gaussian mixture densities to reduce the…

Systems and Control · Electrical Eng. & Systems 2025-06-02 Ondŕej Straka , Uwe D. Hanebeck

We present Dirac-Brueckner-Hartree-Fock calculations for isospin asymmetric nuclear matter which are based on improved approximations schemes. The potential matrix elements have been adapted for isospin asymmetric nuclear matter in order to…

Nuclear Theory · Physics 2009-11-11 E. N. E. van Dalen , C. Fuchs , Amand Faessler

Given dense image feature correspondences of a non-rigidly moving object across multiple frames, this paper proposes an algorithm to estimate its 3D shape for each frame. To solve this problem accurately, the recent state-of-the-art…

Computer Vision and Pattern Recognition · Computer Science 2019-04-30 Suryansh Kumar

We describe recent progress in developing practical ab initio methods for which the computer effort is proportional to the number of atoms: linear scaling or O(N) methods. It is shown that the locality property of the density matrix gives a…

Condensed Matter · Physics 2007-05-23 D. R. Bowler , I. J. Bush , M. J. Gillan

We develop a statistical method to learn a molecular Hamiltonian matrix from a time-series of electron density matrices. We extend our previous method to larger molecular systems by incorporating physical properties to reduce…

Chemical Physics · Physics 2021-08-03 Prachi Gupta , Harish S. Bhat , Karnamohit Ranka , Christine M. Isborn

A linear-scaling algorithm is presented for computing the Hartree-Fock (HF) exchange matrix using concentric atomic density fitting. The algorithm utilizes the stronger distance dependence of the three-center electron repulsion integrals…

Chemical Physics · Physics 2014-10-21 David S. Hollman , Henry F. Schaefer , Edward F. Valeev

This article is concerned with the numerical solution of subspace optimization problems, consisting of minimizing a smooth functional over the set of orthogonal projectors of fixed rank. Such problems are encountered in particular in…

Numerical Analysis · Mathematics 2022-10-17 Eric Cancès , Gaspard Kemlin , Antoine Levitt

Nonlinear manifold learning algorithms, such as diffusion maps, have been fruitfully applied in recent years to the analysis of large and complex data sets. However, such algorithms still encounter challenges when faced with real data. One…

Mathematical Physics · Physics 2015-05-25 Carmeline J. Dsilva , Ronen Talmon , Ronald R. Coifman , Ioannis G. Kevrekidis

Probabilistic programming systems generally compute with probability density functions, leaving the base measure of each such function implicit. This mostly works, but creates problems when densities with respect to different base measures…

Programming Languages · Computer Science 2020-12-14 Alexey Radul , Boris Alexeev

We present a new adaptive method for electronic structure calculations based on novel fast algorithms for reduction of multivariate mixtures. In our calculations, spatial orbitals are maintained as Gaussian mixtures whose terms are selected…

Numerical Analysis · Mathematics 2019-06-19 Gregory Beylkin , Lucas Monzon , Xinshuo Yang

Gaussian Mixture Models (GMMs) are one of the most potent parametric density models used extensively in many applications. Flexibly-tied factorization of the covariance matrices in GMMs is a powerful approach for coping with the challenges…

Machine Learning · Computer Science 2023-11-14 Mohammad Pasande , Reshad Hosseini , Babak Nadjar Araabi

Automatic differentiation has become an important tool for optimization problems in computational science, and it has been applied to the Hartree-Fock method. Although the reverse-mode automatic differentiation is more efficient than the…

Chemical Physics · Physics 2022-11-28 Naruki Yoshikawa , Masato Sumita

Estimating the eigenvalues of non-normal matrices is a foundational problem with far-reaching implications, from modeling non-Hermitian quantum systems to analyzing complex fluid dynamics. Yet, this task remains beyond the reach of standard…

Quantum Physics · Physics 2025-10-23 Yukun Zhang , Yusen Wu , Xiao Yuan

We consider the problem of recovering a $d-$dimensional manifold $\mathcal{M} \subset \mathbb{R}^n$ when provided with noiseless samples from $\mathcal{M}$. There are many algorithms (e.g., Isomap) that are used in practice to fit manifolds…

Statistics Theory · Mathematics 2017-09-13 Kitty Mohammed , Hariharan Narayanan