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With growing demand for time-domain simulations of correlated many-body systems, the development of efficient and stable integration schemes for the time-dependent Schr\"odinger equation is of keen interest in modern electronic structure…

Chemical Physics · Physics 2023-08-22 David B. Williams-Young , Stephen Yuwono , A. Eugene DePrince , Chao Yang

Strongly interacting quantum many-body systems are fundamentally compelling and ubiquitous in science. However, their complexity generally prevents exact solutions of their dynamics. Precisely engineered ultracold atomic gases are emerging…

Atomic Physics · Physics 2015-06-12 M. J. Martin , M. Bishof , M. D. Swallows , X. Zhang , C. Benko , J. von-Stecher , A. V. Gorshkov , A. M. Rey , Jun Ye

Many-body interactions in effective field theories for disordered interacting electrons are considered. It is shown that three-body and higher interaction terms are generated in perturbation theory, and some of the physical consequences of…

Statistical Mechanics · Physics 2009-11-10 T. R. Kirkpatrick , D. Belitz

We present a robust, ab initio method for addressing atom-light interactions and apply it to photoionization of argon. We use a close-coupling ansatz constructed on a multi-configurational Hartree-Fock description of localized states and…

Atomic Physics · Physics 2015-06-12 T. Carette , J. M. Dahlström , L. Argenti , E. Lindroth

We present the numerical implementation of the time-dependent complete-active-space self-consistent-field (TD-CASSCF) method [Phys. Rev. A, 88, 023402 (2013)] for atoms driven by a strong linearly polarized laser pulse. The present…

The issue of orbital relaxation in computational core-hole spectroscopy, specifically x-ray absorption, has been a major problem for methods such as equation-of-motion coupled cluster with singles and doubles (EOM-CCSD). The…

Chemical Physics · Physics 2025-03-26 Megan Simons , Devin A. Matthews

A formalism for energy-dependent many-body perturbation theory (MBPT), previously indicated in our recent review articles (Lindgren et al., Phys.Rep. 389,161(2004), Can.J.Phys. 83,183(2005)), is developed in more detail. The formalism…

Quantum Physics · Physics 2009-11-13 Ingvar Lindgren , Sten Salomonson , Daniel Hedendahl

It is shown how to adapt the non-perturbative coupled cluster method of many-body theory so that it may be successfully applied to Hamiltonian lattice $SU(N)$ gauge theories. The procedure involves first writing the wavefunctions for the…

High Energy Physics - Lattice · Physics 2009-10-22 C. H. Llewellyn Smith , N. J. Watson

Classical chaotic systems exhibit exponentially diverging trajectories due to small differences in their initial state. The analogous diagnostic in quantum many-body systems is an exponential growth of out-of-time-ordered correlation…

Strongly Correlated Electrons · Physics 2020-03-06 Étienne Lantagne-Hurtubise , Stephan Plugge , Oguzhan Can , Marcel Franz

The performance of correlated optimized effective potential (OEP) functionals based on the spin-resolved second-order correlation energy is analyzed. The relative importance of singly- and doubly- excited contributions as well as the effect…

Chemical Physics · Physics 2014-07-31 I. Grabowski , E. Fabiano , A. Teale , S. Śmiga , A. Buksztel , F. Della Sala

Understanding quantum many-body states of correlated electrons is one main theme in modern condensed matter physics. Given that the Fermi-Hubbard model, the prototype of correlated electrons, has been recently realized in ultracold optical…

Strongly Correlated Electrons · Physics 2021-01-27 Bin-Bin Chen , Chuang Chen , Ziyu Chen , Jian Cui , Yueyang Zhai , Andreas Weichselbaum , Jan von Delft , Zi Yang Meng , Wei Li

We present a computationally efficient approach to solve the time-dependent Kohn-Sham equations in real-time using higher-order finite-element spatial discretization, applicable to both pseudopotential and all-electron calculations. To this…

Computational Physics · Physics 2019-10-02 Bikash Kanungo , Vikram Gavini

In this work we present a coupled-cluster theory for the propagation of multireference electronic systems initiating at general quantum mechanical states. Our formalism is based on the infinitesimal analysis of modified cluster operators,…

Chemical Physics · Physics 2025-05-09 Martín A. Mosquera

The many-body Coulomb repulsive energy of strictly correlated electrons provides direct information of the exact Hohenberg-Kohn exchange-correlation functional in the strong interaction limit. Until now the treatment of strictly correlated…

Chemical Physics · Physics 2013-03-13 Christian B. Mendl , Lin Lin

We present a theoretical description of femtosecond laser induced dynamics of the hydrogen molecule and of singly ionised sodium dimers, based on a real-space, real-time, implementation of time-dependent density functional theory (TDDFT).…

Condensed Matter · Physics 2007-05-23 Alberto Castro , M. A. L. Marques , Julio A. Alonso , George F. Bertsch , Angel Rubio

The present work explores quantitative limits to the Single-Active Electron (SAE) approximation, often used to deal with strong-field ionization and subsequent attosecond dynamics. Using a time-dependent multi\-configuration approach,…

Atomic Physics · Physics 2025-11-04 Jean-Nicolas Vigneau , Tung Nguyen-Dang , Eric Charron , Osman Atabek

We discuss the multispecies time-dependent restricted-active-space self-consistent-field theory, an \textit{ab initio} wavefunction-based theory for mixtures of ultracold atomic and molecular gases. We present the general theory, based on…

Quantum Physics · Physics 2018-08-01 Camille Lévêque , Lars Bojer Madsen

We numerically study models of $\mathrm{H}_2$ and $\mathrm{LiH}$ molecules, aligned collinearly with the linear polarization of the external field, to elucidate the possible role of correlation in the enhanced-ionization phenomena.…

Atomic Physics · Physics 2016-01-06 S. Chattopadhyay , S. Bauch , L. B. Madsen

By propagating the many-body Schr\"odinger equation, we determine the exact time-dependent Kohn-Sham potential for a system of strongly correlated electrons which undergo field-induced tunneling. Numerous features are entirely absent from…

Strongly Correlated Electrons · Physics 2021-01-15 Matthew J. P. Hodgson , James D. Ramsden , Jacob B. J. Chapman , Piers Lillystone , Rex W Godby

The multiconfigurational time-dependent Hartree-Fock method (MCTDHF) is applied for simulations of the two-photon ionization of Helium. We present results for the single- and double ionization from the groundstate for photon energies in the…

Atomic Physics · Physics 2011-12-30 D. Hochstuhl , M. Bonitz