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Next-generation implantable computational devices require long-term stable electronic components capable of operating in, and interacting with, electrolytic surroundings without being damaged. Organic electrochemical transistors (OECTs)…

Materials Science · Physics 2022-11-01 Matteo Cucchi , Daniela Parker , Paschalis Gkoupidenis , Eleni Stavrinidou , Hans Kleemann

We have studied the electrical conductivity of nanoring-based, transparent conductive films, these being promising elements for flexible electronic devices. Both the wire resistance and the junction resistance were taken into account. We…

Statistical Mechanics · Physics 2021-12-23 Yuri Yu. Tarasevich , Andrei V. Eserkepov , Irina V. Vodolazskaya

The motion of the electrolyte, comprising of solute ions and solvent molecules, is a frequently-occurring natural phenomenon. The motion of the electrolyte leads to the flows of ions and solvent molecules, known as electrochemical flows. In…

Fluid Dynamics · Physics 2013-09-12 Chengjun Xu , Chin-Tsau Hsu

We experimentally, numerically and analytically explore the diffusive transport of active colloidal particles with sensory delay, navigating motility landscapes in which the self-propulsion speed depends on space. We show how the transport…

Statistical Mechanics · Physics 2026-04-29 Adrià Garcés , Ueli Töpfer , Lucio Isa , Demian Levis , Ignacio Pagonabarraga

The electric double layer is an important structure that appears at charged liquid interfaces, and it determines the performance of various electrochemical devices such as supercapacitors and electrokinetic energy converters. Here the…

Soft Condensed Matter · Physics 2023-08-15 Haruto Iwasaki , Yasuyuki Kimura , Yuki Uematsu

The structure of polar liquids and electrolytic solutions, such as water and aqueous electrolytes, at interfaces underlies numerous phenomena in physics, chemistry, biology, and engineering. In this work, we develop a continuum theory that…

Soft Condensed Matter · Physics 2022-07-13 J. Pedro de Souza , Alexei A. Kornyshev , Martin Z. Bazant

In this letter we address the question how interactions affect the DC conductance of a one-dimensional electron system not necessarily adequately described by the Luttinger model. Using a Laughlin type argument, we show that gauge…

Mesoscale and Nanoscale Physics · Physics 2008-02-03 Anton Yu. Alekseev , Vadim V. Cheianov , Jurg Froehlich

A number of basic scientific questions relating to ion conduction in homogeneously disordered solids are discussed. The questions deal with how to define the mobile ion density, what can be learned from electrode effects, what is the ion…

Disordered Systems and Neural Networks · Physics 2009-11-13 Jeppe C. Dyre , Philipp Maass , Bernhard Roling , David L. Sidebottom

Density functional theory is used to describe electrolyte solutions in contact with electrodes of planar or spherical shape. For the electrolyte solutions we consider the so-called civilized model, in which all species present are treated…

Soft Condensed Matter · Physics 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

The dominant modes of charge transport in variant polar liquid based nanoparticulate colloidal dispersions (dilute) have been theorized. Theories formulating electrical characteristics of colloids have often been found to over or under…

Soft Condensed Matter · Physics 2015-12-01 Purbarun Dhar , Arvind Pattamatta , Sarit K. Das

We investigate the phenomenon of multilayer formation via layer-by-layer deposition of alternating charge polyelectrolytes. Using mean-field theory, we find that a strong short-range attraction between the two types of polymer chains is…

Soft Condensed Matter · Physics 2012-01-31 Adi Shafir , David Andelman

The solvent quality determines the collapsed or the expanded state of a polymer. For example, a polymer dissolved in a poor solvent collapses, whereas in a good solvent it opens up. While this standard understanding is generally valid,…

Soft Condensed Matter · Physics 2020-07-01 Yani Zhao , Manjesh K. Singh , Kurt Kremer , Robinson Cortes-Huerto , Debashish Mukherji

Solvation effect might have a tremendous influence on chemical reactions. However, precise quantum chemistry calculations are most often done either in vacuum neglecting the role of the solvent or using continuum solvent model ignoring its…

Chemical Physics · Physics 2020-07-14 Guillaume Jeanmairet , Maximilien Levesque , Daniel Borgis

A self-consistent mode-coupling theory is presented for the viscosity of solutions of charged rod-like polymers. The static structure factor used in the theory is obtained from polymer integral equation theory; the Debye-H\"{u}ckel…

Soft Condensed Matter · Physics 2009-11-10 Kunimasa Miyazaki , Biman Bagchi , Arun Yethiraj

Atomic-sized lead (Pb) contacts are deposited and dissolved in an electrochemical environment, and their transport properties are measured. Due to the electrochemical fabrication process, we obtain mechanically unstrained contacts and…

Mesoscale and Nanoscale Physics · Physics 2010-09-21 F. -Q. Xie , F. Hüser , F. Pauly , Ch. Obermair , G. Schön , Th. Schimmel

In this work, we have computed electrical conductivities at ambient conditions of aqueous NaCl and KCl solutions by using the Einstein-Helfand equation. Common force fields (charge q = 1 e) do not reproduce the experimental values of…

Chemical Physics · Physics 2024-01-25 S. Blazquez , J. L. F. Abascal , J. Lagerweij , P. Habibi , P. Dey , T. J. H. Vlugt , O. A. Moultos , C. Vega

Counterion distribution around an isolated flexible polyelectrolyte in the presence of a divalent salt is evaluated using the adsorption model [M. Muthukumar, J. Chem. Phys. {\bf 120}, 9343 (2004)] that considers Bjerrum length, salt…

Soft Condensed Matter · Physics 2008-12-29 Arindam Kundagrami , M. Muthukumar

Finding new ionic conductors that enable significant advancements in the development of energy-storage devices is a challenging goal of current material science. Aside of material classes as ionic liquids or amorphous ion conductors, the…

Materials Science · Physics 2015-09-02 K. Geirhos , P. Lunkenheimer , M. Michl , D. Reuter , A. Loidl

In this work we attempt to elucidate the nature of conductivity in polymers by taking the acid-base doped polyaniline (PAni) polymer. We evaluate the PAni conductance by using realistic ab initio parameters and including decoherent…

Disordered Systems and Neural Networks · Physics 2010-10-06 Carlos J. Cattena , Raúl A. Bustos-Marún , Horacio M. Pastawski

We demonstrate that exciton conductance in organic materials can be enhanced by several orders of magnitude when the molecules are strongly coupled to an electromagnetic mode. Using a 1D model system, we show how the formation of a…

Mesoscale and Nanoscale Physics · Physics 2015-05-26 Johannes Feist , Francisco J. Garcia-Vidal