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Static and dynamic critical behavior of Sn$_2$P$_2$S$_6$ type ferroelectrics and (Pb$_y$Sn$_{1-y}$)$_2$P$_2$(Se$_x$S$_{1-x}$)$_6$ mixed crystals with line of tricritical points and line of Lifshitz points on the $T-x-y$ phase diagram, which…

Materials Science · Physics 2020-07-01 V. Liubachko , A. Oleaga , A. Salazar , R. Yevych , A. Kohutych , Yu. Vysochanskii

Basing on the temperature dependences of optical birefringence for Sn2P2S6 and Sn2P2(Se0.28S0.72)6 crystals subjected to hydrostatic pressures, we prove unambiguously that Sn2P2S6 reveals a tricritical point on its (p,T)-phase diagram with…

Materials Science · Physics 2015-06-23 B. Zapeka , M. Kostyrko , I. Martynyuk-Lototska , R. Vlokh

For Sn$_2$P$_2$S$_6$ ferroelectrics the second order phase transitions line is observed until reaching the tricritical point at transition temperature lowering to 250 K by compression. Observed temperature-pressure phase diagram agrees with…

The valence fluctuations which are related to the charge disproportionation of phosphorous ions $P^{4+} + P^{4+}\rightarrow P^{3+} + P^{5+}$ are the origin of ferroelectric and quantum paraelectric states in Sn(Pb)$_2$P$_2$S$_6$…

Materials Science · Physics 2017-09-13 R. Yevych , V. Haborets , M. Medulych , A. Molnar , A. Kohutych , A. Dziaugys , Ju. Banys , Yu. Vysochanskii

Phase transition between ferroelectricity and quantum paraelectricity via non-thermal tuning parameters can lead to quantum critical behavior and associated emergent phenomena. Ferroelectric quantum critical systems are, however, rare…

Mesoscale and Nanoscale Physics · Physics 2022-03-07 Prasanna Venkatesan Ravindran , Asif Islam Khan

Magnetic-field-induced phase transitions are investigated in the frustrated gapped quantum paramagnet Rb$_{2}$Cu$_{2}$Mo$_3$O$_{12}$ through dielectric and calorimetric measurements on single-crystal samples. It is clarified that the…

Strongly Correlated Electrons · Physics 2021-07-19 S. Hayashida , L. Huberich , D. Flavián , Z. Yan , K. Yu. Povarov , S. Gvasaliya , A. Zheludev

Materials tuned to the neighbourhood of a zero temperature phase transition often show the emergence of novel quantum phenomena. Much of the effort to study these new effects, like the breakdown of the conventional Fermi-liquid theory of…

Strongly Correlated Electrons · Physics 2014-05-06 S. E. Rowley , L. J. Spalek , R. P. Smith , M. P. M. Dean , G. G. Lonzarich , J. F. Scott , S. S. Saxena

The dielectric and magnetic polarizations of quantum paraelectrics and paramagnetic materials have in many cases been found to initially increase with increasing thermal disorder and hence exhibit peaks as a function of temperature. A…

Materials Science · Physics 2020-06-04 M J Coak , C R S Haines , C Liu , S E Rowley , G G Lonzarich , S S Saxena

Evidence for a re-entrant quantum paraelectric (QPE) state preceded by a dipole glass (DG) phase with a non-classical exponent in the quantum critical regime of SrFe12O19 is presented. It is shown that the DG transition is accompanied with…

Strongly Correlated Electrons · Physics 2023-12-19 Keshav Kumar , Dhananjai Pandey

For $\rm Sn_2P_2S_6$ ferroelectrics by first-principles calculations an analysis of the $\rm P_2S_6$ cluster electronic structure and their comparison with crystal valence band in paraelectric and ferroelectric phases has been done and the…

Materials Science · Physics 2015-03-19 Konstantin Glukhov , Kristina Fedyo , Yulian Vysochanskii

A variety of compounds, for example doped paraelectrics and polar metals, exhibit both ferroelectricity and correlated electronic phenomena such as low-density superconductivity and anomalous transport. Characterizing such properties is…

Strongly Correlated Electrons · Physics 2023-07-19 Avraham Klein , Vladyslav Kozii , Jonathan Ruhman , Rafael M. Fernandes

Ferroelectric phase transition in the semiconductor Sn2P2S6 single crystal has been studied by means of neutron scattering in the pressure-temperature range adjacent to the anticipated tricritical Lifshitz point (p=0.18GPa, T=296K). The…

We have investigated non-equilibrium properties of proper uniaxial Sn$_2$P$_2$(Se$_x$S$_{1-x}$)$_6$ ferroelectrics with the Type II incommensurate phase above Lifshitz point $x_{\rm LP} \sim 0.28$. We measured dielectric susceptibility with…

Since there is both strong electron-phonon coupling during a ferroelectric/FE transition and superconducting/SC transition, it has been an important topic to explore superconductivity from the FE instability. Sn$_2$P$_2$Se$_6$ arouses broad…

Superconductivity · Physics 2024-02-27 He Zhang , Wei Zhong , Xiaohui Yu , Binbin Yue , Fang Hong

High-temperature electronic materials are in constant demand as the required operational range for various industries increases. Here we design $(A,A^\prime)B_2$O$_6$ perovskite oxides with [111] ``rock salt" $A$-site cation order and…

Materials Science · Physics 2014-06-11 Joshua Young , James M. Rondinelli

We analyze the equilibrium states of quantum lattice model with local multi-well potentials for Sn$_2$P$_2$S$_6$ ferroelectric crystals using the mean and Gaussian curvatures ($H$, $K$), curvedness ($C$) and shape index ($S$). From the…

Materials Science · Physics 2025-12-29 S. Özüm , T. Akkurt , R. Erdem , N. Güçlü

We discuss the nature of pressure induced phase transitions in standard Quantum Paraelectrics near quantum critical point. From a microscopic theory we first show that near the critical point the transition temperature $T_c(p)$ varies as $…

Strongly Correlated Electrons · Physics 2012-07-30 Nabyendu Das , Suresh G. Mishra

In a recent letter [Phys. Rev. Lett. {\bf 75}, 2360 (1996)] we briefly discussed the existence and nature of ferroelectric order in positionally disordered dipolar materials. Here we report further results and give a complete description of…

Disordered Systems and Neural Networks · Physics 2009-10-30 G. Ayton , M. J. P. Gingras , G. N. Patey

In this article mixed CuInP$_2$(S$_x$Se$_{1-x}$)$_6$ crystals were investigated by broadband dielectric spectroscopy (20 Hz - 3 GHz). The complete phase diagram has been obtained from these results. The phase diagram of investigated…

Materials Science · Physics 2015-05-13 J. Macutkevic , J. Banys , R. Grigalaitis , Yu. Vysochanskii

A quantum critical point (QCP) between the antiferromagnetic and the paramagnetic phases was realized by applying a hydrostatic pressure of ~ 7 GPa on single crystals of NiS_{2} pyrite with a low residual resistivity, rho_{0}, of 0.5…

Strongly Correlated Electrons · Physics 2007-05-23 N. Takeshita , S. Takashima , C. Terakura , H. Nishikubo , S. Miyasaka , M. Nohara , Y. Tokura , H. Takagi
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