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In this chapter we focus first on the theoretical methods and relevant computational approaches to calculate the electronic structure of atoms, molecules, and clusters containing heavy elements for which relativistic effects become…

Chemical Physics · Physics 2021-10-05 Simone Taioli , Stefano Simonucci

We present a time-dependent formulation of coupled cluster theory. This theory allows for direct computation of the free energy of quantum systems at finite temperature by imaginary time integration and is closely related to the thermal…

Chemical Physics · Physics 2019-03-21 Alec F. White , Garnet Chan

The unitary coupled cluster (UCC) approximation is one of the more promising wave-function ans\"atze for electronic structure calculations on quantum computers via the variational quantum eigensolver algorithm. However, for large systems…

Quantum Physics · Physics 2021-09-30 Jia Chen , Hai-Ping Cheng , James K. Freericks

Deconfined quantum criticality (DQC) arises from fractionalization of quasi-particles and leads to fascinating behaviors beyond the Landau-Ginzburg-Wilson description of phase transitions. Here, we study the critical dynamics when driving a…

Strongly Correlated Electrons · Physics 2025-04-15 Yu-Rong Shu , Shao-Kai Jian , Anders W. Sandvik , Shuai Yin

Simulating molecules using the Variational Quantum Eigensolver method is one of the promising applications for NISQ-era quantum computers. Designing an efficient ansatz to represent the electronic wave function is crucial in such…

Chemical Physics · Physics 2022-05-09 Dmitry A. Fedorov , Yuri Alexeev , Stephen K. Gray , Matthew Otten

The coupled cluster iteration scheme for determining the cluster amplitudes involves a set of nonlinearly coupled difference equations. In the space spanned by the amplitudes, the set of equations are analysed as a multivariate…

A novel parallel hybrid quantum-classical algorithm for the solution of the quantum-chemical ground-state energy problem on gate-based quantum computers is presented. This approach is based on the reduced density-matrix functional theory…

In this work we investigate the ground state and the dissipative quantum dynamics of interacting charged particles in an external potential at finite temperature. The recently devised time-dependent quantum Monte Carlo (TDQMC) method allows…

Quantum Physics · Physics 2025-01-29 Ivan P. Christov

We propose a relativistic unitary coupled cluster (UCC) expectation value approach for computing first-order properties of heavy-element systems. Both perturbative (UCC3) and non-perturbative (qUCC) commutator-based formulations are applied…

Chemical Physics · Physics 2026-02-03 Kamal Majee , Somesh Chamoli , Malaya K. Nayak , Achintya Kumar Dutta

We study a formal extension of the Dirac equation in the framework of a non-commutative two-sheeted space-time. It is shown that this approach naturally extends the classical Dirac theory by doubling the number of fermionic states, which…

High Energy Physics - Theory · Physics 2009-11-10 Fabrice Petit , Michael Sarrazin

We derive coupled-cluster equations for three-body Hamiltonians. The equations for the one- and two-body cluster amplitudes are presented in a factorized form that leads to an efficient numerical implementation. We employ low-momentum two-…

Nuclear Theory · Physics 2008-11-26 G. Hagen , T. Papenbrock , D. J. Dean , A. Schwenk , A. Nogga , M. Wloch , P. Piecuch

In fault-tolerant quantum computing, the cost of calculating Hamiltonian eigenvalues using the quantum phase estimation algorithm is proportional to the constant scaling the Hamiltonian matrix block-encoded in a unitary circuit. We present…

Quantum Physics · Physics 2024-12-03 Konrad Deka , Emil Zak

We develop a linked cluster method to calculate the spectral weights of many-particle excitations at zero temperature. The dynamical structure factor is expressed as a sum of exclusive structure factors, each representing contributions from…

Strongly Correlated Electrons · Physics 2009-11-10 Chris J. Hamer , Weihong Zheng , Rajiv R. P. Singh

Efficiently calculating the low-lying eigenvalues of Hamiltonians, written as sums of Pauli operators, is a fundamental challenge in quantum computing. While various methods have been proposed to reduce the complexity of quantum circuits…

Quantum Physics · Physics 2025-08-08 Abhinav Anand , Kenneth R. Brown

The dynamical cluster approximation (DCA) is a quantum cluster extension to the single-site dynamical mean-field theory that incorporates spatially nonlocal dynamic correlations systematically and nonperturbatively. The DCA$^+$ algorithm…

Strongly Correlated Electrons · Physics 2020-05-26 Urs R. Hähner , Thomas A. Maier , Thomas C. Schulthess

Quantum dynamics of the Bose-Hubbard Model is investigated through a semiclassical hamiltonian picture provided by the Time-Dependent Variational Principle method. The system is studied within a factorized slow/fast dynamics. The…

Superconductivity · Physics 2009-10-31 L. Amico , V. Penna

The Hamiltonian eigenvalue problem for bound states of a quantum field theory is formulated in terms of Dirac's light-front coordinates and then approximated by the exponential-operator technique of the standard coupled-cluster method. This…

High Energy Physics - Phenomenology · Physics 2012-06-27 J. R. Hiller

We propose a new formulation of time-dependent coupled cluster with adaptive basis functions and division of the one-particle space into active and secondary subspaces. The formalism is fully bivariational in the sense of a real-valued…

Chemical Physics · Physics 2024-02-20 Mads Greisen Højlund , Ove Christiansen

Quantum systems with a non-conserved probability can be described by means of non-Hermitian Hamiltonians and non-unitary dynamics. In this paper, the case in which the degrees of freedom can be partitioned in two subsets with light and…

Quantum Physics · Physics 2016-10-21 Alessandro Sergi

A non-${\cal{PT}}$-symmetric Hamiltonian system of a Duffing oscillator coupled to an anti-damped oscillator with a variable angular frequency is shown to admit periodic solutions. The result implies that ${\cal{PT}}$-symmetry of a…

Chaotic Dynamics · Physics 2020-11-11 Pijush K. Ghosh , Puspendu Roy