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Perovskite-like oxides $AB'_{1/2}B''_{1/2}$O$_3$ may experience different ordering degrees of $B$-cations, that can be varied by suitable synthesis conditions or post-synthesis treatment. In this work the earlier proposed statistical model…

Materials Science · Physics 2020-03-20 N. V. Ter-Oganessian , V. P. Sakhnenko

We formulate an effective model for B-B' site ordering in double perovskite materials A_2BB'O_6. Even within the simple framework of lattice-gas type models, we are able to address several experimentally observed issues including…

Materials Science · Physics 2009-11-13 Prabuddha Sanyal , Sabyasachi Tarat , Pinaki Majumdar

Double perovskite compounds containing 5d transition metal elements have been extensively studied as platforms for multipolar order phenomena stemming from spin-orbit-entangled 5d electrons. In this study, we examine the interplay between…

Strongly Correlated Electrons · Physics 2025-04-02 Koki Shibuya , Daigorou Hirai , Koshi Takenaka

We report the comprehensive experimental results identifying the magnetic spin ordering and the magnetization dynamics of a double perovskite Pr2CoFeO6 by employing the (dc and ac) magnetization, powder neutron diffraction (NPD) and X-ray…

We report on atomic ordering of B-site transition-metals and magnetic properties of epitaxial La2CrFeO6 double-perovskite films grown by pulsed-laser deposition under various conditions. The highest ordered sample exhibited a fraction of…

Materials Science · Physics 2011-08-01 S. Chakraverty , A. Ohtomo , D. Okuyama , M. Saito , M. Okude , R. Kumai , T. Arima , Y. Tokura , S. Tsukimoto , Y. Ikuhara , M. Kawasaki

We have studied the atomic ordering of B-site transition metals and magnetic properties in the pulsed-laser deposited films of La2CrFeO6 (LCFO) and La2VMnO6 (LVMO), whose bulk materials are known to be single perovskites with random…

Materials Science · Physics 2015-06-12 Akira Ohtomo , Suvankar Chakraverty , Hisanori Mashiko , Takayoshi Oshima , Masashi Kawasaki

(Mg, Fe)SiO$_3$ post-perovskite is the highest pressure silicate mineral phase in the Earth's interior. The extreme pressure and temperature conditions inside large extrasolar planets will likely lead to phase transitions beyond pPv. In…

Geophysics · Physics 2023-05-23 Rajkrishna Dutta , Sally. J. Tracy , R. E. Cohen

Pressure-induced ordering close to a $z=1$ quantum critical point is studied in the presence of bond disorder in the quantum spin system (C$_4$H$_{12}$N$_2$)Cu$_2$(Cl$_{1-x}$Br$_{x}$)$_6$ (PHCX) by means of muon-spin rotation and…

Strongly Correlated Electrons · Physics 2017-01-11 A. Mannig , J. S. Möller , M. Thede , D. Hüvonen , T. Lancaster , F. Xiao , R. C. Williams , Z. Guguchia , R. Khasanov , E. Morenzoni , A. Zheludev

Here, the first-principles predictions on the structural stability, magnetic behavior and electronic structure of B-site ordered double perovskite Nd$_{2}$FeCrO$_{6}$ have been reported. Initially, the ground state of the parent single…

Materials Science · Physics 2022-01-10 M. D. I. Bhuyan , Rana Hossain , Ferdous Ara , M. A. Basith

The structural, electronic and magnetic properties of anti-site disordered Sm$ _{2} $NiMnO$ _{6} $ double perovskite has been studied. RE$_{2}$NiMnO$_{6}$ (RE: rare-earth) ordered double perovskite is commonly believed to show two distinct…

Materials Science · Physics 2025-07-28 S. Majumder , M. Tripathi , P. Rajput , S. N. Jha , R. J. Choudhary , D. M. Phase

The influence of pressure on the hydrogen bond ordering in the perovskite metal-organic framework [(CH3)2NH2]Mn(HCOO)3 has been investigated by dielectric, pyroelectric adn magnetic measurements in a piston-cylinder cell. Under ambient…

Materials Science · Physics 2024-03-08 Na Su , Yinina Ma , Shuang Liu , Wei Wu , Jianlin Luo , Young Sun

We report and compare the structural, magnetic, and optical properties of ordered La2NiMnO6 thin films and its disordered LaNi0.5Mn0.5O3 counterpart. An x-ray diffraction study reveals that the B-site Ni/Mn ordering induces additional XRD…

Materials Science · Physics 2015-05-13 M. P. Singh , K. D. Truong , S. Jandl , P. Fournier

Comprehensive muon spin rotation/relaxation (muSR) and neutron powder diffraction (NPD) studies supported via bulk measurements have been performed on the ordered double perovskite Sr2YbRuO6 to investigate the nature of the magnetic ground…

Double-perovskite oxides have attracted recent attention due to their attractive functionalities and application potential. In this paper, we demonstrate the effect of dual controls, i.e., the deposition pressure of oxygen (P$_O2$) and…

Strongly Correlated Electrons · Physics 2023-04-27 Z. T. Zhang , H. Yan , Z. Huang , X. Chi , C. J. Li , Z. S. Lim , S. W. Zeng , K. Han , G. J. Omar , K. X. Jin , A. Ariando

The synthesis and physical properties of the double perovskite (DP) compound Ba2CdReO6 with the 5d1 electronic configuration are reported. Three successive phases originating from a spin-orbit-entangled Jeff = 3/2 state, confirmed by the…

Strongly Correlated Electrons · Physics 2021-04-06 Daigorou Hirai , Zenji Hiroi

Double perovskite-based magnets wherein frustration and competition between emergent degrees of freedom are at play can lead to novel electronic and magnetic phenomena. Herein, we report the electronic structure and magnetic properties of…

Ca2-xLaxFeMoO6 double perovskite with La concentration x = 0 to 0.6 was synthesized using solid state sintering route. The standard techniques of XRD, SEM and EDX were applied to characterize the material. Crystal structure of the samples…

Materials Science · Physics 2009-10-11 I. Panneer Muthuselvam , Asok Poddar , R. N. Bhowmik

Using first-principles methods, we predict the energy landscape and ferroelectric states of double perovskites of the form AA$'$BB$'$O$_6$ in which the atoms on both the A and B sites are arranged in rock-salt order. While we are not aware…

Materials Science · Physics 2011-04-25 Anindya Roy , David Vanderbilt

Here we show that the B-site cation (Fe/Mo) ordering in the double-perovskite magnetoresistor, Sr2FeMoO6, is controlled by either kinetics or thermal equilibrium depending on the temperature range. In order to enhance the ordering, long…

Strongly Correlated Electrons · Physics 2007-05-23 T. Shimada , J. Nakamura , T. Motohashi , H. Yamauchi , M. Karppinen

Double perovskite oxide materials have garnered tremendous interest due to their strong spin-lattice-charge coupling. Interesting in their own right, rare-earth-based DPOs have yet to be subjected to high-pressure studies. In this paper, we…

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