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A model system is proposed to investigate the chemical equilibrium and mechanical stability of biological spherical-like nanoshells in contact with an aqueous solution with added dissociated electrolyte of a given concentration. The ionic…

Soft Condensed Matter · Physics 2020-02-06 Thiago Colla , Amin Bakhshandeh , Yan Levin

Fluid and ionic transport at nanoscale recently highlighted a wealth of exotic behaviours. However, the artificial nanofluidic devices are still far from the advanced functionalities existing in biological systems, such as electrically and…

Mesoscale and Nanoscale Physics · Physics 2020-11-13 Alice Marcotte , Timothée Mouterde , Antoine Niguès , Alessandro Siria , Lydéric Bocquet

Anion exchange membranes are used in alkaline fuel cells and offer a promising alternative to the more expensive proton exchange membrane fuel cells. However, hydroxide ion conductivity in anion exchange membranes is low, and the quest for…

Soft Condensed Matter · Physics 2024-04-16 Mohammed Al Otmi , Ping Lin , William Schertzer , Coray M. Colina , Rampi Ramprasad , Janani Sampath

The interface between a liquid and a solid is the location of plethora of intrincate mechanisms at the nanoscale, at the root of their specific emerging properties in natural processes or technological applications. However, while the…

We study the effects of solute interactions on osmotic transport through pores. By extending single-file, single-species kinetic models to include entrance of solute into membrane pores, we model the statistical mechanics of competitive…

Materials Science · Physics 2009-10-31 Tom Chou

When an ionic liquid adsorbs onto a porous electrode, its ionic arrangement is deeply modified due to a screening of the Coulombic interactions by the metallic surface and by the confinement imposed upon it by the electrode's morphology. In…

Polaritons in strongly anisotropic thin layers have recently captured the attention in nanophotonics because of their directional propagation at the nanoscale, which offers unique possibilities for nanooptical applications. However,…

The transport of polymers with folded configurations across membrane pores is investigated theoretically by analyzing simple discrete stochastic models. The translocation dynamics is viewed as a sequence of two events: motion of the folded…

Statistical Mechanics · Physics 2009-11-13 Stanislav Kotsev , Anatoly B. Kolomeisky

We consider the release and subsequent gravity-driven spreading of a finite volume of fluid in an anisotropic porous medium bounded by an impermeable substrate. When the permeability in the vertical direction is much smaller than the…

Fluid Dynamics · Physics 2023-04-24 GP Benham

We characterize the dynamics of a $z-z$ electrolyte embedded in a varying-section channel. In the linear response regime, by means of suitable approximations, we derive the Onsager matrix associated to externally enforced gradients in…

Soft Condensed Matter · Physics 2019-10-02 Paolo Malgaretti , Mathijs Janssen , Ignacio Pagonabarraga , Miguel J. Rubi

Experimental realization of two-dimensional boron sheets was reported very recently by Feng et. al. using molecular beam epitaxy on silver (111) surface. These boron sheets possess promising electronic and transport properties. We performed…

Mesoscale and Nanoscale Physics · Physics 2018-10-17 Vivekanand Shukla , Anton Grigoriev , Naresh K. Jena , Rajeev Ahuja

Thick Li-ion battery electrodes with high ion transport rates could enable batteries that cost less and that have higher gravimetric and volumetric energy density, because they require fewer inactive cell-components. Finding ways to…

Materials Science · Physics 2015-05-14 V. Pavan Nemani , Stephen J. Harris , Kyle C. Smith

Short nanopores find extensive applications capitalizing on their high throughput and detection resolution. Ionic behaviors through long nanopores are mainly determined by charged inner-pore walls. When pore lengths decrease to sub-200 nm,…

Chemical Physics · Physics 2024-02-19 Long Ma , Zhe Liu , Bowen Ai , Jia Man , Jianyong Li , Kechen Wu , Yinghua Qiu

Hypothesis:Diffusion in confinement is an important fundamental problem with significant implications for applications of supported liquid phases. However, resolving the spatially dependent diffusion coefficient, parallel and perpendicular…

We investigate, based on the tight-binding model and in the linear deformation regime, the strain dependence of the electronic band structure of phosphorene, exposed to a uniaxial strain in one of its principle directions, the normal, the…

Mesoscale and Nanoscale Physics · Physics 2015-12-21 Yawar Mohammadi , Borhan Arghavani Nia

We argue that the kosmotropes remain strongly hydrated in the vicinity of a hydrophobic surface, while the chaotropes lose their hydration shell and can become adsorbed to the interface. The mechanism of adsorption is still a subject of…

Soft Condensed Matter · Physics 2018-02-14 Alexandre P. dos Santos , Yan Levin

We study a membrane tube with unidirectional ion pumps driving an osmotic pressure difference. A pressure driven peristaltic instability is identified, qualitatively distinct from similar tension-driven Rayleigh type instabilities on…

Biological Physics · Physics 2018-04-04 Sami C. Al-Izzi , George Rowlands , Pierre Sens , Matthew S. Turner

Polyamide membranes, such as nanofiltration (NF) and reverse osmosis (RO) membranes, are widely used for water desalination and purification. However, the mechanisms of solute transport and solute rejection due to charge interactions remain…

Soft Condensed Matter · Physics 2025-03-17 Suwei Liu , Zi Hao Foo , John H. Lienhard , Sinan Keten , Richard M. Lueptow

Tuning two dimensional nanomaterial's structural and electronic properties has facilitated the new research paradigm in electronic device applications. In this work, the first principles density functional theory based methods are used to…

Materials Science · Physics 2021-04-30 Rameshwar L. Kumawat , Biswarup Pathak

Solid sheets and fluid membranes exhibit buckling under lateral compression. Here, it is revealed that fluid membranes have anisotropic buckling surface tension contrary to solid sheets. Surprisingly, the surface tension perpendicular to…

Soft Condensed Matter · Physics 2011-07-01 Hiroshi Noguchi
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