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Evolutionary crystal structure prediction proved to be a powerful approach for studying a wide range of materials. Here, we present a specifically designed algorithm for the prediction of the structure of complex crystals consisting of…

Materials Science · Physics 2012-05-21 Qiang Zhu , Artem R. Oganov , Colin W. Glass , Harold T. Stokes

This work demonstrates that the convex hull of formation energies for solid compounds involving elements from hydrogen to uranium admits a remarkably simple description over the 92-dimensional space of chemical compositions, despite the…

Understanding the high-pressure behavior of C-H system is of great importance due to its key role in organic, bio-, petroleum and planetary chemistry. We have performed a systematic investigation of the pressure-composition phase diagram of…

Materials Science · Physics 2020-01-07 Anastasia S. Naumova , Sergey V. Lepeshkin , Artem R. Oganov

We build random forests models to predict elastic properties and mechanical hardness of a compound, using only its chemical formula as input. The model training uses over 10,000 target compounds and 60 features based on stoichiometric…

Materials Science · Physics 2021-07-22 Wei-Chih Chen , Joanna N. Schmidt , Da Yan , Yogesh K. Vohra , Cheng-Chien Chen

We set up an evolutionary algorithm combined with density functional tight-binding (DFTB) calculations to investigate hydrogen adsorption on flat graphene and graphene monolayers curved over substrate steps. During the evolution, candidates…

Mesoscale and Nanoscale Physics · Physics 2018-08-08 G. Ozbal , J. T. Falkenberg , M. Brandbyge , R. T. Senger , H. Sevincli

Prediction of stable crystal structures at given pressure-temperature conditions, based only on the knowledge of the chemical composition, is a central problem of condensed matter physics. This extremely challenging problem is often termed…

Materials Science · Physics 2015-05-20 A. R. Oganov , Y. Ma , A. O. Lyakhov , M. Valle , C. Gatti

Recently, Grockowiak $\textit{et al.}$ reported "hot superconductivity" in ternary or multinary compounds based on lanthanum hydride [A. D. Grockowiak $\textit{et al.}$, Front. Electron. Mater. $\textbf{2}$, 837651 (2022)]. In this paper,…

Superconductivity · Physics 2023-12-05 Takahiro Ishikawa , Yuta Tanaka , Shinji Tsuneyuki

Using a comprehensive structure search and high-throughput first-principles calculations of 1483 compounds, this study presents the phase diagram of Lu-H-N. The formation energy landscape of Lu-H-N was derived and utilized to assess the…

Superconductivity · Physics 2023-04-11 Fankai Xie , Tenglong Lu , Ze Yu , Yaxian Wang , Zongguo Wang , Sheng Meng , Miao Liu

A novel method for crystal structure prediction, based on metadynamics and evolutionary algorithms, is presented here. This technique can be used to produce efficiently both the ground state and metastable states easily reachable from a…

Materials Science · Physics 2012-06-08 Qiang Zhu , Artem R. Oganov , Andriy O. Lyakhov

Computationally efficient and automated generation of convex hulls is desirable for high throughput materials discovery of thermodynamically stable multi-species crystal structures. A convex hull genetic algorithm is proposed that uses…

Materials Science · Physics 2024-04-23 Scott Donaldson , Robert A. Lawrence , Matt I. J. Probert

The spontaneous genesis of hydrocarbons which comprise natural petroleum have been analyzed by chemical thermodynamic stability theory. The constraints imposed upon chemical evolution by the second law of thermodynamics are briefly…

Chemical Physics · Physics 2009-11-11 J. F. Kenney , Vladimir G. Kutcherov , Nikolai A. Bendeliani , Vladimir A. Alekseev

We present a systematic search for low-energy metastable superhard carbon allotropes by using the recently developed evolutionary metadynamics technique. It is known that cold compression of graphite produces an allotrope at 15-20 GPa. Here…

Materials Science · Physics 2012-05-22 Qiang Zhu , Qingfeng Zeng , Artem R. Oganov

Understanding of recently reported putative close-to-room-temperature superconductivity in C-S-H compounds at 267 GPa demands reproducible synthesis protocol as well as knowledge of its structure and composition. We synthesized C-S-H…

Polymeric nitrogen with single bonds can be created from the molecular form at high pressure and due to large energy difference between triple and single bonds it is interesting as energetic material. Its structure and properties are,…

Materials Science · Physics 2018-11-21 Dominika Melicherová , Oto Kohulák , Dušan Plašienka , Roman Martoňák

We have developed an efficient and reliable methodology for crystal structure prediction, merging ab initio total-energy calculations and a specifically devised evolutionary algorithm. This method allows one to predict the most stable…

Materials Science · Physics 2009-11-18 A. R. Oganov , C. W. Glass

The complex crystal chemistry of elemental boron has led to numerous proposed structures with distinctive motifs as well as contradictory findings. Herein, evolutionary structure searches performed at 100 GPa have uncovered a series of…

Materials Science · Physics 2021-05-19 Katerina P. Hilleke , Eva Zurek , Tadashi Ogitsu , Shuai Zhang

High-throughput computational materials searches generate large databases of locally-stable structures. Conventionally, the needle-in-a-haystack search for the few experimentally-synthesizable compounds is performed using a convex hull…

Materials Science · Physics 2018-10-24 Andrea Anelli , Edgar A. Engel , Chris J. Pickard , Michele Ceriotti

Metal hydrides can be tuned to have a diverse range of properties and find applications in hydrogen storage and superconductivity. Finding methods to control the synthesis of hydrides can open up new pathways to unlock novel hydride…

The recently developed evolutionary algorithm USPEX proved to be a tool that enables accurate and reliable prediction of structures for a given chemical composition. Here we extend this method to predict the crystal structure of polymers by…

Materials Science · Physics 2019-01-03 Qiang Zhu , Vinit Sharma , Artem R Oganov , Rampi Ramprasad

We explore chemically homogeneous evolution (CHE) as a formation channel for massive merging binary black holes (BBHs). We develop methods to include CHE in a rapid binary population synthesis code, Compact Object Mergers: Population…

Solar and Stellar Astrophysics · Physics 2021-05-26 Jeff Riley , Ilya Mandel , Pablo Marchant , Ellen Butler , Kaila Nathaniel , Coenraad Neijssel , Spencer Shortt , Alejandro Vigna-Gomez
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