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The first-principles simulation of the electronic structure of organic semiconductors in solution poses a number of challenges that are not trivial to address simultaneously. In this work, we investigate the effects and the mutual interplay…

Materials Science · Physics 2021-03-08 Jannis Krumland , Ana M. Valencia , Caterina Cocchi

We report on the design and demonstration of ${\beta}-(Al_{0.18}Ga_{0.82})_2O_3/Ga_2O_3$ modulation doped heterostructures to achieve high sheet charge density. The use of a thin spacer layer between the Si delta-doping and heterojunction…

Fuel cells recombine water from H2 and O2 thereby powering e.g. cars or houses with no direct carbon emission. In anion-exchange membrane fuel cells (AEMFCs), to reach high power densities, operating at high pH is an alternative to using…

Lewis acids like tris(pentafluorophenyl)borane (BCF) offer promising routes for efficient $p$-doping of organic semiconductors. The intriguing experimental results achieved so far call for a deeper understanding of the underlying doping…

Materials Science · Physics 2020-07-07 Richard Schier , Ana M. Valencia , Caterina Cocchi

The structural, electronic, lattice dynamics, electron-phonon coupling, and superconducting properties of the alkali-metal hydride RbH, metalized through electron-doping by the construction of the solid-solution Rb$_{1-x}$Sr$_x$H, are…

Superconductivity · Physics 2022-10-19 S. Villa-Cortés , M. A. Olea-Amezcua , O. De la Peña-Seaman

Contact resistances often contribute significantly to the overall device resistance in organic field-effect transistors (OFETs). Understanding charge injection at the metal-organic interface is critical to optimizing OFET device…

Materials Science · Physics 2009-11-11 D. Natelson , B. H. Hamadani , J. W. Ciszek , D. A. Corley , J. M. Tour

The control over material properties attainable through molecular doping is essential to many technological applications of organic semiconductors, such as OLED or thermoelectrics. These excitonic semiconductors typically reach the…

Materials Science · Physics 2021-07-14 Massimiliano Comin , Simone Fratini , Xavier Blase , Gabriele D'Avino

We show the possibility of inducing a superconductive phase transition in tetrahedrally coordinated semiconductors via field-effect (FET) doping by taking as an example the hydrogenated (111) silicon surface. We perform density functional…

Superconductivity · Physics 2020-10-12 Davide Romanin

A modulation-doping approach to control the carrier density of the high-density electron gas at a prototype polar/non-polar oxide interface is presented. It is shown that the carrier density of the electron gas at a GdTiO3/SrTiO3 interface…

Materials Science · Physics 2015-06-11 Tyler A. Cain , Pouya Moetakef , Clayton A. Jackson , Susanne Stemmer

Chemical doping of topological materials may provide a possible route for realizing topological superconductivity. However, all such cases known so far are based on chalcogenides. Here we report the discovery of superconductivity induced by…

Superconductivity · Physics 2020-11-02 Jifeng Wu , Chenqiang Hua , Bin Liu , Yanwei Cui , Qinqing Zhu , Guorui Xiao , Siqi Wu , Guanghan Cao , Yunhao Lu , Zhi Ren

Using a new two-step synthesis method - ultrasound treatment and low temperature annealing, we explore superconductivity in potassium-doped triphenylbismuth, which is composed of one bismuth atom and three phenyl rings. The combination of…

Superconductivity · Physics 2018-02-12 Ren-Shu Wang , Jia Cheng , Xiao-Lin Wu , Hui Yang , Xiao-Jia Chen , Yun Gao , Zhong-Bing Huang

The interplay between inter- and intra-chain charge transport in bulk polythiophene in the hopping regime has been clarified by studying the conductivity as a function of frequency (up to 3 THz), temperature and doping level. We present a…

Soft Condensed Matter · Physics 2009-10-31 J. A. Reedijk , H. C. F. Martens , H. B. Brom , M. A. J. Michels

"Secondary doping" in poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) is quite effective and a frequently used method for the conductivity enhancement. This simple approach, the addition of co-solvents to the PEDOT:PSS…

Materials Science · Physics 2019-09-23 K. Itoh , Y. Kato , Y. Honma , H. Masunaga , A. Fujiwara , S. Iguchi , T. Sasaki

Polarisation doping of Al$_x$Ga$_{1-x}$N, through grading of $x$, has realised major improvements in $p$-type conductivity in ultraviolet (UV) light-emitting diodes (LEDs) compared to conventional impurity doping. However, the exact balance…

The thermoelectric efficiency of semiconductors is usually considered in the ohmic electronic transport regime, which is achieved through high doping. Here we consider the opposite regime of low doping where the current-voltage…

Materials Science · Physics 2012-10-01 François Léonard

Chemical doping has recently become a very important strategy to induce superconductivity especially in complex compounds. Distinguished examples include Ba-doped La$_2$CuO$_4$ (the first high temperature superconductor), K-doped BaBiO$_3$,…

Superconductivity · Physics 2009-02-22 Guanghan Cao , Cao Wang , Zengwei Zhu , Shuai Jiang , Yongkang Luo , Shun Chi Zhi Ren , Qian Tao , Yuetao Wang , Zhu'an Xu

The search for conventional superconductors with high transition temperatures ($T_c$) has largely focused on intrinsically metallic compounds. In this work, we explore the potential of intrinsically non-metallic compounds to exhibit…

Superconductivity · Physics 2025-07-29 Haowei Xu , Olivia Schneble , Rafael Jaramillo , Marek Polański , Ju Li

We analyze fulleride superconductivity at experimental doping levels, treating the electron-electron and electron-phonon interactions on an equal footing, and establish the existence of novel physics which helps explain the unusually high…

Strongly Correlated Electrons · Physics 2007-05-23 J. E. Han , O. Gunnarsson , V. H. Crespi

We report the doping high concentration of tetravalent Ge4+ ions (5 mol % for x = 0.05 to 30 mol % for x = 0.30) at the Fe3+ sites of Fe2-xGexO3 system by chemical coprecipitation route. The charge state of Fe and Ge ions has been modified…

Materials Science · Physics 2023-09-08 Divya Sherin G T , R. N Bhowmik

Hybrid field effect transistors based on the organic polymer poly(3-hexylthiophene) (P3HT) and inorganic zinc oxide were investigated. In this report we present one of the first studies on hybrid transistors employing one polymeric…

Materials Science · Physics 2010-07-27 Maria S. Hammer , Carsten Deibel , Jens Pflaum , Vladimir Dyakonov