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We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of…

Statistical Mechanics · Physics 2010-02-10 François Sausset , Gilles Tarjus

We review recent developments in structural-dynamical phase transitions in trajectory space. An open question is how the dynamic facilitation theory of the glass transition may be reconciled with thermodynamic theories that posit a…

Statistical Mechanics · Physics 2020-08-04 C. Patrick Royall , Francesco Turci , Thomas Speck

We study the role of elasticity-induced facilitation on the dynamics of glass-forming liquids by a coarse-grained two-dimensional model in which local relaxation events, taking place by thermal activation, can trigger new relaxations by…

Disordered Systems and Neural Networks · Physics 2023-04-05 Misaki Ozawa , Giulio Biroli

The dynamics of many glassy systems are known to exhibit string-like hopping motions each consisting of a line of particles displacing one and other. By using molecular dynamics simulations of glassy polymers, we show that these motions…

Statistical Mechanics · Physics 2021-06-29 Chi-Hang Lam

The dynamical behavior of a kind of models with hierarchically constrained dynamics is investigated. The models exhibit many properties resembling real structural glasses. In particular, we focus on the study of time-dependent temperature…

Statistical Mechanics · Physics 2009-11-07 A. Prados , J. J. Brey

We assess the relative importance of spatial congestion and lowered temperature in the slowing dynamics of supercooled glycerol near the glass transition. We independently vary both volume, V, and temperature, T, by applying high pressure…

Soft Condensed Matter · Physics 2007-05-23 Kyaw Zin Win , Narayanan Menon

We study the effect of periodic, spatially uniform temperature variation on mechanical properties and structural relaxation of amorphous alloys using molecular dynamics simulations. The disordered material is modeled via a non-additive…

Soft Condensed Matter · Physics 2019-02-04 Qing-Long Liu , Nikolai V. Priezjev

We propose a dynamical theory of low-temperature shear deformation in amorphous solids. Our analysis is based on molecular-dynamics simulations of a two-dimensional, two-component noncrystalline system. These numerical simulations reveal…

Statistical Mechanics · Physics 2009-10-30 M. L. Falk , J. S. Langer

We develop the Elastically Collective Nonlinear Langevin Equation theory to investigate, for the first time, glassy dynamics in capped metallic glass thin films. Finite-size effects on the spatial gradient of structural relaxation time and…

Soft Condensed Matter · Physics 2022-02-02 Anh D. Phan

We analyze the displacements of the particles of a glass-forming molecular liquid perpendicular to a confining solid surface, using extensive molecular dynamics simulations with atomistic models. In the vicinity of an attractive surface,…

Soft Condensed Matter · Physics 2024-10-15 Alireza F. Behbahani , Vagelis Harmandaris

External stress can accelerate molecular mobility of amorphous solids by several orders of magnitude. The changes in mobility are commonly interpreted through the Eyring model, which invokes an empirical activation volume whose origin…

Soft Condensed Matter · Physics 2022-03-14 Entao Yang , Robert A. Riggleman

We compute the rheological properties of inelastic hard spheres in steady shear flow for general shear rates and densities. Starting from the microscopic dynamics we generalise the Integration Through Transients (\textsc{itt}) formalism to…

Soft Condensed Matter · Physics 2020-03-03 W. Till Kranz , Fabian Frahsa , Annette Zippelius , Matthias Fuchs , Matthias Sperl

In a recent publication we established an analogy between the free energy of a hard sphere system and the energy of an elastic network [1]. This result enables one to study the free energy landscape of hard spheres, in particular to define…

Disordered Systems and Neural Networks · Physics 2007-08-08 Carolina Brito , Matthieu Wyart

We use molecular dynamics simulation to study the relationship between structure and dynamics in supercooled binary Lennard--Jones nanoparticles over a range of particle sizes. The glass transition temperature of the nanoparticles is found…

Soft Condensed Matter · Physics 2025-05-15 Weikai Qi , Shreya Tiwary , Richard K. Bowles

We study the dynamics of a glassy model with infinite range interactions externally driven by an oscillatory force. We find a well-defined transition in the (Temperature-Amplitude-Frequency) phase diagram between (i) a `glassy' state…

Statistical Mechanics · Physics 2009-10-31 Ludovic Berthier , Leticia F. Cugliandolo , Jose Luis Iguain

Measuring, characterizing and modelling the slow dynamics of glassy soft matter is a great challenge, with an impact that ranges from industrial applications to fundamental issues in modern statistical physics, such as the glass transition…

Soft Condensed Matter · Physics 2009-11-11 Luca Cipelletti , Laurence Ramos

Molecular dynamics simulations are performed to examine the dynamic response of amorphous solids to oscillatory shear at finite temperatures. The data were collected from a poorly annealed binary glass, which was deformed periodically in…

Soft Condensed Matter · Physics 2017-11-21 Nikolai V. Priezjev

The glass transition, extensively studied in dense fluids, polymers, or colloids, corresponds to a dramatic evolution of equilibrium transport coefficients upon a modest change of control parameter, like temperature or pressure. A similar…

Statistical Mechanics · Physics 2013-05-06 Ludovic Berthier , Jorge Kurchan

Experimental studies of the glassy slowdown in molecular liquids indicate that the high-temperature activation energy $E_{\infty}$ of glass-forming liquids is directly related to their glass transition temperature $T_{\text{g}}$. To further…

Soft Condensed Matter · Physics 2021-03-02 L. Hecht , R. Horstmann , B. Liebchen , M. Vogel

We compute for an archetypical glass-forming system the excess of particle mobility distributions over the corresponding distribution of dynamic propensity, a quantity that measures the tendency of the particles to be mobile and reflects…

Statistical Mechanics · Physics 2014-04-01 Rodriguez Fris J. Ariel , Frechero M. , Appignanesi Gustavo
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